公开(公告)号：US09944574B2

公开(公告)日：2018-04-17

申请号：US14409448

申请日：2014-05-23

Applicant: TIANJIN UNIVERSITY

Inventor： Jijun Zou ,  Xiangwen Zhang ,  Li Wang ,  Qingfa Wang

IPC: B01J19/12 ,  B01J35/00 ,  C07C5/22 ,  B01J31/02 ,  B01J31/34 ,  B01J31/36 ,  B01J31/38 ,  B01J31/26

CPC classification number: C07C5/2266 ,  B01J19/123 ,  B01J31/0208 ,  B01J31/0237 ,  B01J31/0239 ,  B01J31/0271 ,  B01J31/26 ,  B01J31/34 ,  B01J31/36 ,  B01J31/38 ,  B01J35/004 ,  C07C5/2213 ,  C07C5/222 ,  C07C2521/06 ,  C07C2523/02 ,  C07C2523/06 ,  C07C2523/20 ,  C07C2523/30 ,  C07C2531/02 ,  C07C2531/26 ,  C07C2531/34 ,  C07C2531/36 ,  C07C2531/38 ,  C07C2603/86 ,  Y02P20/582 ,  C07C13/68

Abstract: The invention discloses a continuous process for producing high-pure quadricyclane, in which “a reaction-rectification integral process” or “a reaction followed by rectification process” may be employed. The two processes both use a novel composite catalyst which is obtained by loading an organic photo-sensitizer on a solid photocatalyst, and the composite catalyst has a high activity and a good stability. In the reaction-rectification integral process, the composite catalyst is used by being blended with rectification fillers or covering the rectification fillers, so as to achieve the integration of the reaction and the rectification. In the reaction followed by rectification process, the composite catalyst and the rectification fillers are placed separately from each other. The two processes achieve a relatively short residence time of reactants, produce highly-pure quadricyclane, and reduce the formation of cokes.

公开(公告)号：US09273166B2

公开(公告)日：2016-03-01

申请号：US14032066

申请日：2013-09-19

Applicant: ExxonMobil Chemical Patents Inc.

Inventor： Ian C. Stewart ,  John R. Hagadorn ,  Mun F. Tse ,  George Rodriguez ,  Patrick Brant

IPC: C08F136/20 ,  C07C13/45 ,  C07C233/10 ,  C07C57/26 ,  C07C255/31 ,  C07C67/343 ,  C07C13/68 ,  C09J123/14 ,  C08G61/08 ,  C09J165/00 ,  C08L65/00

CPC classification number: C08F136/20 ,  C07C13/45 ,  C07C13/68 ,  C07C57/26 ,  C07C67/343 ,  C07C233/10 ,  C07C255/31 ,  C07C2603/91 ,  C08G61/08 ,  C08G2261/1644 ,  C08G2261/3325 ,  C08G2261/418 ,  C08G2261/72 ,  C08L57/02 ,  C08L65/00 ,  C09J123/14 ,  C09J165/00 ,  C07C69/608 ,  C08L23/06 ,  C08L23/14

Abstract: This invention relates to a reaction product obtained by contacting a polymer comprising units derived from dicyclopentadiene with a vinyl terminated macromonomer, a vinyl monomer or a vinylene monomer, in the presence of a metathesis catalyst, where the vinyl monomer or vinylene monomer is represented by the formula: wherein each X is, independently, —CO2R, —CONR1R2, CN, a C1 to a C20 alkyl group; R is a C1 to a C20 alkyl group or an aromatic group; each R1 and R2 is, independently, a hydrogen, a C1 to a C20 alkyl group, or an aromatic group; each R5 is, independently, a hydrogen atom or a C1 to a C40 alkyl group; each Ar is, independently, an aromatic group; and each n is, independently, from 0 to about 40.

Abstract translation: 本发明涉及通过在复分解催化剂存在下将包含衍生自二环戊二烯的单体的聚合物与乙烯基封端的大分子单体，乙烯基单体或亚乙烯基单体接触而获得的反应产物，其中乙烯基单体或亚乙烯基单体由 式：其中每个X独立地是-CO 2 R，-CONR 1 R 2，CN，C 1至C 20烷基; R是C1至C20烷基或芳基; 每个R 1和R 2独立地是氢，C 1至C 20烷基或芳基; 每个R 5独立地为氢原子或C 1至C 40烷基; 每个Ar独立地是芳族基团; 并且每个n独立地为0至约40。

公开(公告)号：US20140077166A1

公开(公告)日：2014-03-20

申请号：US13623698

申请日：2012-09-20

Applicant: Kong Kyeom Kim ,  Sung Kil Hong ,  Hye Young Jang ,  Dong Seob Jeong

Inventor： Kong Kyeom Kim ,  Sung Kil Hong ,  Hye Young Jang ,  Dong Seob Jeong

IPC: C07C13/70 ,  C07D409/04 ,  H01L51/54 ,  C07C211/61

CPC classification number: H01L51/0052 ,  C07C13/68 ,  C07C15/60 ,  C07C15/62 ,  C07C211/61 ,  C07C2603/24 ,  C07C2603/50 ,  C07C2603/66 ,  C07C2603/86 ,  C07D209/08 ,  C07D219/14 ,  C07D221/18 ,  C07D333/08 ,  C09K11/06 ,  C09K2211/1007 ,  C09K2211/1011 ,  C09K2211/1014 ,  C09K2211/1029 ,  C09K2211/1092 ,  H01L51/0058

Abstract: The present invention provides an organic light emitting device comprising a first electrode, at least one organic layer and a second electrode, laminated successively, in which at least one layer of the organic layer has a polycyclic aromatic hydrocarbon as a core and comprises at least one of a derivative in which a substituted or unsubstituted C2-30 cycloalkane, or a substituted or unsubstituted C5-50 polycycloalkane is directly fused to the core or fused to a substituent of the core: and a new organic compound usable in the organic light emitting device. Furthermore, the present invention provides a charge carrier extracting, injecting or transporting material which has a polycyclic aromatic hydrocarbon as a core and comprises a derivative in which a substituted or unsubstituted C2-30 cycloalkane, or a substituted or unsubstituted C5-50 polycycloalkane is directly fused to the core or fused to a substituent of the core.

Abstract translation: 本发明提供了一种有机发光器件，其包括依次层压的第一电极，至少一个有机层和第二电极，其中至少一层有机层具有多环芳族烃作为核心，并且包括至少一个 的衍生物，其中取代或未取代的C 2-30环烷烃或取代或未取代的C 5-50多环烷烃直接与核心稠合或稠合至核心的取代基;以及可用于有机发光器件的新的有机化合物 。 此外，本发明提供一种载体提取，注入或输送具有多环芳烃为核心的材料，其包含其中取代或未取代的C 2-30环烷烃或取代或未取代的C 5-50多环烷烃直接的衍生物 与芯稠合或稠合至核心的取代基。

公开(公告)号：US20120123058A1

公开(公告)日：2012-05-17

申请号：US13386580

申请日：2010-06-25

Applicant: Toshinobu Ohno ,  Yuko Takao ,  Kazuyuki Moriwaki ,  Fukashi Matsumoto ,  Souichi Uchida ,  Satoru Ikeda

Inventor： Toshinobu Ohno ,  Yuko Takao ,  Kazuyuki Moriwaki ,  Fukashi Matsumoto ,  Souichi Uchida ,  Satoru Ikeda

IPC: C08G75/06 ,  C07D333/08 ,  C07C13/62

CPC classification number: H01L51/0047 ,  B82Y10/00 ,  C07C13/68 ,  C07C2604/00 ,  C07D333/08 ,  C07D333/24 ,  H01L51/0036 ,  H01L51/4253 ,  Y02E10/549

Abstract: The present invention provides a novel methanofullerene derivative applicable as an organic semiconductor material in electronics devices such as organic FETs and electroluminescence devices and solar cells, represented by formula (I) wherein the average value of 13C-NMR chemical shift values of carbons C2 and C2′ on FL, bonded to C1 is 80.10 ppm or greater, wherein FL represents fullerenes, X1 and X2 are each an aromatic hydrocarbon, an alkyl group or the like, C2 and C2′ are carbon atoms on FL, bonded to C1, and n is an integer of 1 to 10.

Abstract translation: 本发明提供了一种新型的可用作有机半导体材料的甲基富勒烯衍生物，该电子器件如有机FET和电致发光器件以及由式（I）表示的太阳能电池，其中碳C 2和C 2的13 C-NMR化学位移值的平均值 在FL上键合到C1是80.10ppm或更大，其中FL表示富勒烯，X1和X2各自是芳族烃，烷基等，C2和C2'是FL上的碳原子，与C1结合，n 是1〜10的整数。

公开(公告)号：US06566570B1

公开(公告)日：2003-05-20

申请号：US09601647

申请日：2000-08-04

Applicant: Christer Bergström ,  Arto Mölsä ,  Juhana Ruotoistenmäki

Inventor： Christer Bergström ,  Arto Mölsä ,  Juhana Ruotoistenmäki

IPC: C07C276

CPC classification number: C07C13/68 ,  C07C13/42 ,  C07C2602/42 ,  C07C2603/86 ,  C08F32/08 ,  C08G61/08

Abstract: A process for producing an unsaturated cyclic compound, comprising the steps of hydrochlorinating a terpene to produce a hydrochlorinated terpene, and subjecting the hydrochlorinate terpene to elimination of hydrogen chloride to form an unsaturated cyclic compound. The terpene is preferably &agr;-pinene, &bgr;-pinene, camphene or suitable turpentine fraction. The cyclic compounds can be used as monomers and by means of the invention it is thus possible to produce plastics from renewable raw material sources.

Abstract translation: 一种制备不饱和环状化合物的方法，包括氢化萜烯以产生氢氯化萜烯的步骤，并使氢氯化萜烯消除氯化氢以形成不饱和环状化合物。 萜烯优选为α-蒎烯，β-蒎烯，camp烯或合适的松节油。 环状化合物可以用作单体，通过本发明，可以从可再生原料来源生产塑料。

公开(公告)号：US4169864A

公开(公告)日：1979-10-02

申请号：US888906

申请日：1978-03-22

Applicant: James E. Lyons ,  Abraham Schneider ,  Harry K. Myers, Jr.

Inventor： James E. Lyons ,  Abraham Schneider ,  Harry K. Myers, Jr.

IPC: C07C13/68 ,  C07C13/28 ,  C07C15/12

CPC classification number: C07C13/68 ,  C07C2103/86 ,  C07C2531/14 ,  C07C2531/22 ,  C07C2531/24

Abstract: Novel codimers (I) of norbornadiene and phenylacetylenes and their hydrogenated derivatives (II), having the following structures ##STR1## wherein R is a hydrogen, a phenyl, or a phenyl having alkyl substitutents and R.sub.1 is a phenyl or a phenyl having alkyl substituents and processes for preparing both are disclosed. Codimer (II) can be used as a high energy fuel or a diluent for such a fuel. Process for making codimer (I) involves reacting norbornadiene and phenylacetylene or diphenylacetylene with a catalyst system of cobaltic or cobaltous acetylacetonate, 1,2-bisdiphenylphosphino ethane and an alkyl aluminum chloride.

公开(公告)号：US4110409A

公开(公告)日：1978-08-29

申请号：US842812

申请日：1977-10-17

Applicant: Harry K. Myers, Jr. ,  James E. Lyons ,  Abraham Schneider

Inventor： Harry K. Myers, Jr. ,  James E. Lyons ,  Abraham Schneider

IPC: C07C2/42 ,  C07C5/03 ,  C07C13/68 ,  C07C13/28 ,  C07C15/12

CPC classification number: C07C13/68 ,  C07C2/42 ,  C07C5/03 ,  C07C2103/86 ,  C07C2531/14 ,  C07C2531/22 ,  C07C2531/24

Abstract: Norbornadiene and an alkyne are catalytically codimerized in the presence of a homogeneous catalytic system of cobaltic or cobaltous acetylacetonate, 1,2-bisdiphenylphosphino ethane and an alkyl aluminum chloride. Also, novel codimers of norbornadiene and an alkyne containing at least three carbons are disclosed. After hydrogenation, resulting codimers can be used as high energy fuels or diluents for such fuels.

Abstract translation: 降冰片二烯和炔烃在钴或钴乙酰丙酮化合物，1,2-双二苯基膦基乙烷和烷基氯化铝的均相催化体系存在下进行催化同步化。 此外，公开了降冰片二烯和含有至少三个碳的炔烃的新型共聚物。 氢化后，得到的共混物可用作这种燃料的高能燃料或稀释剂。

公开(公告)号：US3970706A

公开(公告)日：1976-07-20

申请号：US390490

申请日：1973-08-22

Applicant: Marc Julia

Inventor： Marc Julia

IPC: C07C1/32 ,  C07C13/68 ,  C07C33/05 ,  C07C69/145 ,  C07C147/08

CPC classification number: C07C13/68 ,  C07C1/322 ,  C07C2103/86 ,  Y10S585/93

Abstract: The invention relates to a process for the grafting a chain on to the 10-position carbon atom of a tricyclene skeleton, more particularly for producing 10-substituted stereospecific tricyclenes, especially cis-.alpha.-santalene and cis-.alpha.-santalol. The process involves the production of a sulphone of the tricyclene, the reaction of the sulphone with the halogenated derivative of the desired side chain and desulphonating the product.

Abstract translation: 本发明涉及用于将链接枝到三环骨架的10位碳原子上的方法，更具体地说涉及制备10-取代的立体特异性三环，尤其是顺式-α-蒽醌和顺式-α-檀香醇。 该方法涉及三环烯的砜的生成，砜与所需侧链的卤化衍生物的反应并使产物脱磺酸。

公开(公告)号：US3646105A

公开(公告)日：1972-02-29

申请号：US3646105D

申请日：1969-12-18

Applicant: SNAM PROGETTI

Inventor： CESCA SEBASTIANO ,  ROGGERO ARNALDO ,  PRIOLA ALDO ,  CINELLI ERMANNO

IPC: C07C1/32 ,  C07C13/32 ,  C07C13/68 ,  C07C13/28

CPC classification number: C07C13/68 ,  C07C1/328 ,  C07C13/32 ,  C07C2601/10 ,  C07C2602/42 ,  C07C2603/86

Abstract: NEW TERMONOMERS ARE DISCLOSED WHICH ARE REPRESENTED BY THE FORMULA:

A-(CH2)N)-

WHEREIN A IS A RADICAL INCLUDING AT LEAST ONE RING HAVING AN ENDOMETHYLENE GROUP, B IS A CYCLODIENE RADICAL AND N IS 0-5.

公开(公告)号：US3113424A

公开(公告)日：1963-12-10

申请号：US6347260

申请日：1960-10-19

Applicant: MONSANTO RES CORP

Inventor： WINEMAN ROBERT J

IPC: C06B43/00 ,  C07C13/68 ,  C10L1/04

CPC classification number: C07C13/68 ,  C06B43/00 ,  C10L1/04 ,  Y10S149/12