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公开(公告)号：US3646105A
公开(公告)日：1972-02-29
申请号：US3646105D
申请日：1969-12-18
Applicant: SNAM PROGETTI
Inventor： CESCA SEBASTIANO , ROGGERO ARNALDO , PRIOLA ALDO , CINELLI ERMANNO
CPC classification number: C07C13/68 , C07C1/328 , C07C13/32 , C07C2601/10 , C07C2602/42 , C07C2603/86
Abstract: NEW TERMONOMERS ARE DISCLOSED WHICH ARE REPRESENTED BY THE FORMULA:
A-(CH2)N)-
WHEREIN A IS A RADICAL INCLUDING AT LEAST ONE RING HAVING AN ENDOMETHYLENE GROUP, B IS A CYCLODIENE RADICAL AND N IS 0-5.-
2.发明授权
公开(公告)号：US3896097A
公开(公告)日：1975-07-22
申请号：US35208473
申请日：1973-04-17
Applicant: SNAM PROGETTI
Inventor： PRIOLA ALDO , CESCA SEBASTIANO , FERRARIS GIUSEPPE
Abstract: A method is disclosed for the polymerization of isobutylene and, in particular, the copolymerization of isobutylene and isoprene, by contacting the monomers with a catalyst system constituted by (a) an organoaluminum compound (e.g., Al(C2H5)2Cl) and (b) an oxide or anhydride of an element belonging to Group VI B or VII B of the periodic system (e.g., SO2), in a liquid reaction medium, wherein the molar ratio of compound (b) to compound (a) is less than 1, at a temperature in the range of about -40* to +15*C.
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公开(公告)号：US3872069A
公开(公告)日：1975-03-18
申请号：US33994073
申请日：1973-03-09
Applicant: SNAM PROGETTI
Inventor： PRIOLA ALDO , CESCA SEBASTIANO , FERRARIS GIUSEPPE
Abstract: A process is disclosed whereby butyl rubber of high molecular weight and excellent physical characteristics is readily prepared by copolymerizing isobutylene and isoprene in the presence of a catalyst system consisting of: A. A METALORGANIC COMPOUND (E.G., Al Et2 Cl); and B. AN ORGANIC COMPOUND HAVING FROM 1 TO 24 CARBON ATOMS AND AN ELECTRON AFFINITY VALUE IN THE RANGE FROM 0.3 TO 2 ELECTRON VOLTS (E.G., 1.3.5.-TRINITROBENZENE).
Abstract translation: 公开了一种方法，其中通过在由以下组成的催化剂体系的存在下异丁烯和异戊二烯共聚来容易地制备高分子量和优异物理特性的丁基橡胶：
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