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    Aromatic polyimide composition and articles manufactured therefrom
    2.
    发明授权
    Aromatic polyimide composition and articles manufactured therefrom 有权
    芳族聚酰亚胺组合物及其制造的制品

    公开(公告)号：US08008408B2

    公开(公告)日：2011-08-30

    申请号：US11572815

    申请日：2005-04-26

    申请人： Gregory Warkoski ,  Philip Schild ,  Romano Empaynado ,  Brian A. Stern

    发明人： Gregory Warkoski ,  Philip Schild ,  Romano Empaynado ,  Brian A. Stern

    IPC分类号： C08L79/08 ,  C08L27/12

    CPC分类号： C08G73/14 ,  C08L27/12 ,  C08L27/16 ,  C08L79/08 ,  C09D179/08 ,  C08L2666/04 ,  C08L2666/14

    摘要： Aromatic polyimide composition and articles manufactured therefrom. This invention relates to an aromatic polyimide molding composition, comprising at least one aromatic polyimide (A) chosen from the group consisting of aromatic polyamide-imide, aromatic polyesterimides and aromatic polyimide free of any ester and amide group of specific type and typically from 0.5 to 30% wt of at least one fluoroelastomer (B), with respect to the total weight of (A) and (B), to a method for manufacturing the same, to a molding process of the same, and to the articles manufactured therefrom. Preferably, the component (A) of the composition is at least one aromatic polyamide-imide manufactured by a process including the polycondensation reaction between (i) at least one acid monomer chosen from trimellitic anhydride and trimellitic anhydride monoacid halides and (ii) at least one commoner chosen from the group consisting of 4,4′-diaminodiphenylmethane, 4,4′-diaminodiphenylether, m-phenylenediamine and mixtures therefrom. Advantageously, the aromatic polyimide composition of the invention, owed to its improved flexibility during the molding process, is suitable for the manufacture of articles from mold of complex geometries, such as undercuts, without permanently deforming or cracking upon ejection from the mold.

    摘要翻译： 芳族聚酰亚胺组合物及其制造的制品。 本发明涉及芳族聚酰亚胺模塑组合物，其包含至少一种芳族聚酰亚胺（A），其选自芳族聚酰胺 - 酰亚胺，芳族聚酯酰亚胺和不含特定类型的任何酯和酰胺基团的芳族聚酰亚胺，通常为0.5〜 相对于（A）和（B）的总重量，至少一种含氟弹性体（B）的30重量％，其制造方法，其制造方法和由其制造的制品。 优选地，组合物（A）是至少一种芳族聚酰胺 - 酰亚胺，其通过包括（i）至少一种选自偏苯三酸酐和偏苯三酸酐单酸卤化物的酸单体之间的缩聚反应的方法制备，和（ii）至少 一种选自4,4'-二氨基二苯基甲烷，4,4'-二氨基二苯基醚，间苯二胺及其混合物的共聚物。 有利地，本发明的芳族聚酰亚胺组合物在成型过程中由于其改善的柔性而适用于从复杂几何形状的模具（例如底切）制造制品，而在从模具中弹出时不会永久变形或开裂。

    Aromatic Polyimide Composition and Articles Manufactured Therefrom
    5.
    发明申请
    Aromatic Polyimide Composition and Articles Manufactured Therefrom 有权
    芳香族聚酰亚胺组合物及制品

    公开(公告)号：US20070222108A1

    公开(公告)日：2007-09-27

    申请号：US11572815

    申请日：2005-04-26

    申请人： Gregory Warkoski ,  Philip Schild ,  Romano Empaynado ,  Brian Stern

    发明人： Gregory Warkoski ,  Philip Schild ,  Romano Empaynado ,  Brian Stern

    IPC分类号： C08L79/08 ,  C08L27/12

    CPC分类号： C08G73/14 ,  C08L27/12 ,  C08L27/16 ,  C08L79/08 ,  C09D179/08 ,  C08L2666/04 ,  C08L2666/14

    摘要： Aromatic polyimide composition and articles manufactured therefrom. This invention relates to an aromatic polyimide molding composition, comprising at least one aromatic polyimide (A) chosen from the group consisting of aromatic polyamide-imide, aromatic polyesterimides and aromatic polyimide free of any ester and amide group of specific type and typically from 0.5 to 30% wt of at least one fluoroelastomer (B), with respect to the total weight of (A) and (B), to a method for manufacturing the same, to a molding process of the same, and to the articles manufactured therefrom. Preferably, the component (A) of the composition is at least one aromatic polyamide-imide manufactured by a process including the polycondensation reaction between (i) at least one acid monomer chosen from trimellitic anhydride and trimellitic anhydride monoacid halides and (ii) at least one commoner chosen from the group consisting of 4,4′-diaminodiphenylmethane, 4,4′-diaminodiphenylether, m-phenylenediamine and mixtures therefrom. Advantageously, the aromatic polyimide composition of the invention, owed to its improved flexibility during the mold-deforming process, is suitable for the manufacture of articles from mold of complex geometries, such as undercuts, without permanently deforming or cracking upon ejection from the mold.

    摘要翻译： 芳族聚酰亚胺组合物及其制造的制品。 本发明涉及芳族聚酰亚胺模塑组合物，其包含至少一种芳族聚酰亚胺（A），其选自芳族聚酰胺 - 酰亚胺，芳族聚酯酰亚胺和不含特定类型的任何酯和酰胺基团的芳族聚酰亚胺，通常为0.5〜 相对于（A）和（B）的总重量，至少一种含氟弹性体（B）的30重量％，其制造方法，其制造方法和由其制造的制品。 优选地，组合物（A）是至少一种芳族聚酰胺 - 酰亚胺，其通过包括（i）至少一种选自偏苯三酸酐和偏苯三酸酐单酸卤化物的酸单体之间的缩聚反应的方法制备，和（ii）至少 一种选自4,4'-二氨基二苯基甲烷，4,4'-二氨基二苯基醚，间苯二胺及其混合物的共聚物。 有利地，本发明的芳族聚酰亚胺组合物由于其在模具变形过程中的改进的柔性而适用于从复杂几何形状的模具（例如底切）制造制品，而在从模具弹出时不会永久变形或开裂。

    Multilayer polymer structure
    6.
    发明授权
    Multilayer polymer structure 有权
    多层聚合物结构

    公开(公告)号：US08206834B2

    公开(公告)日：2012-06-26

    申请号：US12296757

    申请日：2007-04-13

    申请人： James K. Doty ,  Alice Weimin Liu ,  Gregory Warkoski ,  Jean De Canniere

    发明人： James K. Doty ,  Alice Weimin Liu ,  Gregory Warkoski ,  Jean De Canniere

    IPC分类号： B32B27/00

    CPC分类号： B32B1/08 ,  B32B1/02 ,  B32B25/14 ,  B32B27/08 ,  B32B27/20 ,  B32B27/32 ,  B32B27/34 ,  B32B2264/108 ,  B32B2270/00 ,  B32B2307/202 ,  B32B2439/00 ,  B32B2597/00 ,  Y10T428/1352 ,  Y10T428/139 ,  Y10T428/1393 ,  Y10T428/27 ,  Y10T428/31725 ,  Y10T428/3175

    摘要： Multilayer structure comprising at least one couple (L1-L2) of adjacent layers (L1) and (L2), wherein: the layer (L1) comprises at least one polymer composition (C1) comprising: (i) at least one semi-aromatic polyamide, and (ii) at least one impact modifier (I1); the layer (L2) comprises at least one polymer composition (C2) comprising: (i) at least one un-functionalized polyolefin (PO2); (ii) at least one functionalized polyolefin (FPO2), the functionalized polyolefin comprising functional groups chosen from carboxylic groups, their esters, their anhydrides and their salts. Process for manufacturing such multilayer structure, which comprises co-extruding or co-blowmolding polymer compositions (C1) and (C2) so as to obtain one couple (L1-L2) of adjacent layers (L1) and (L2).Shaped article comprising such multilayer structure and process for manufacturing the shaped article.

    摘要翻译： 包括相邻层（L1）和（L2）的至少一对（L1-L2）的多层结构，其中：所述层（L1）包含至少一种聚合物组合物（C1），其包含：（i）至少一种半芳族 聚酰胺和（ii）至少一种抗冲改性剂（I1）; 层（L2）包含至少一种聚合物组合物（C2），其包含：（i）至少一种非官能化聚烯烃（PO2）; （ii）至少一种官能化聚烯烃（FPO 2），所述官能化聚烯烃包含选自羧基，其酯，它们的酸酐及其盐的官能团。 制造这种多层结构的方法，其包括共挤出或共吹塑聚合物组合物（C1）和（C2），以获得相邻层（L1）和（L2）的一对（L1-L2）。 包括这种多层结构的成形制品和用于制造成形制品的方法。