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    Discontinuous process for conducting a heterogeneously catalyzed reaction and installation for heterogeneously catalyzed manufacture of products
    2.
    发明授权
    Discontinuous process for conducting a heterogeneously catalyzed reaction and installation for heterogeneously catalyzed manufacture of products 失效
    用于进行非均相催化反应和非均匀催化产物制造的不连续方法

    公开(公告)号：US06245727B1

    公开(公告)日：2001-06-12

    申请号：US08259362

    申请日：1994-06-14

    Applicant: Bernhard Gutsche ,  Lutz Jeromin ,  Eberhard Peukert ,  Levent Yueksel ,  Kurt Adrian ,  Heinz Bollweg

    Inventor： Bernhard Gutsche ,  Lutz Jeromin ,  Eberhard Peukert ,  Levent Yueksel ,  Kurt Adrian ,  Heinz Bollweg

    IPC: C07C4330

    CPC classification number: B01J19/1881 ,  B01D3/009 ,  B01J8/025 ,  B01J8/0285 ,  B01J2208/00256 ,  B01J2208/00283 ,  B01J2208/00557 ,  B01J2208/00663 ,  B01J2219/00006 ,  C07C67/08 ,  Y02P20/127 ,  Y02P20/582 ,  C07C69/26

    Abstract: The invention relates firstly to a discontinuous process for conducting a heterogeneously catalyzed reaction taking place at elevated temperature, in which heat-sensitive products are formed, a heat transfer unit (4) different from the reactor (1) being used for heating and a fixed-bed catalyst (3) being used as the catalyst and the reaction mixture being continuously circulated in succession through the catalyst (3) and then through the heat transfer unit (4). The problem to be solved in this process is to avoid losses of catalyst and product and to shorten the batch time and, optionally, the reaction time in accordance with German patent applications P 38 13 612.0 and P 38 26 320.3. The invention also relates to a plant for the discontinuous heterogeneously catalyzed production of heat-sensitive products at elevated temperature comprising a reactor (1), characterized by a heat transfer unit (4) arranged outside and connected to the reactor (1), a catalyst container (3) containing a fixed-bed catalyst preceding the heat transfer unit and a pump (2) for continuously circulating the reaction mixture in succession through the catalyst (3) and then through the heat transfer unit (4).

    Abstract translation: 本发明首先涉及一种用于进行非均相催化反应的不连续过程，该反应发生在形成热敏产物的高温下，不同于用于加热的反应器（1）的传热单元（4）和固定 用作催化剂的催化剂（3），反应混合物连续循环通过催化剂（3），然后通过传热单元（4）循环。 在该过程中要解决的问题是避免催化剂和产物的损失，并缩短批料时间，以及根据德国专利申请P 38 13 612.0和P 38 26 3203的任选的反应时间。本发明还涉及 用于在升高的温度下不连续地非均相催化生产热敏产物的设备，包括反应器（1），其特征在于布置在反应器（1）外部并连接到反应器（1）的传热单元（4），催化剂容器（3） 在传热单元之前的固定床催化剂和用于使反应混合物连续循环通过催化剂（3）然后通过传热单元（4）的泵（2）。

    Process for the continuous transesterification of fatty acid lower alkyl esters
    4.
    发明授权
    Process for the continuous transesterification of fatty acid lower alkyl esters 失效
    脂肪酸低级烷基酯连续酯交换的方法

    公开(公告)号：US4976892A

    公开(公告)日：1990-12-11

    申请号：US323517

    申请日：1989-03-14

    Applicant: Lutz Jeromin ,  Eberhard Peukert ,  Bernhard Gutsche ,  Gerhard Wollmann ,  Bernard Schleper

    Inventor： Lutz Jeromin ,  Eberhard Peukert ,  Bernhard Gutsche ,  Gerhard Wollmann ,  Bernard Schleper

    IPC: C07C67/02 ,  B01J23/04 ,  B01J31/02 ,  C07B61/00 ,  C07C69/30

    CPC classification number: C11C3/02

    Abstract: A process for the continuous transesterification of C.sub.6 -C.sub.22 fatty acid lower alkyl esters, particularly methyl esters, with polyhydric C.sub.2 -C.sub.5 alcohols, particularly glycerol, in a reaction column comprising a rectifying and reaction section, alkaline catalysts and polyhydric alcohol are introduced into the upper part of the reaction column and boiling fatty acid methyl ester is introduced into the middle part of the reaction column. The product collected in the sump of the column is removed, heated and returned to the lower part of the reaction column. Product is removed from the sump. Lower alkanols passing from the reaction column section to the rectifying section are rectified. The reaction column is operated in boiling equilibrium in its lower part and predominantly in an absorption/desorption equilibrium in its upper part.

    Abstract translation: 在包含精馏和反应部分的反应塔，碱性催化剂和多元醇中，将C6-C22脂肪酸低级烷基酯，特别是甲基酯与多元醇C 2 -C 5醇，特别是甘油连续酯交换的方法被引入 将反应塔上部和沸腾脂肪酸甲酯引入反应塔的中间部分。 将收集在柱的集水槽中的产物除去，加热并返回到反应塔的下部。 产品从集水槽中取出。 将从反应塔部分流出的低级链烷醇精馏。 反应塔在其下部以沸腾平衡运行，主要在上部的吸收/解吸平衡。

    Process for the epoxidation of olefinically unsaturated hydrocarbon compounds with peracetic acid
    7.
    发明授权
    Process for the epoxidation of olefinically unsaturated hydrocarbon compounds with peracetic acid 失效
    用过乙酸环氧化烯属不饱和烃化合物的方法

    公开(公告)号：US4647678A

    公开(公告)日：1987-03-03

    申请号：US813444

    申请日：1985-12-26

    Applicant: Klemens Eckwert ,  Lutz Jeromin ,  Alfred Meffert ,  Eberhard Peukert ,  Bernhard Gutsche

    Inventor： Klemens Eckwert ,  Lutz Jeromin ,  Alfred Meffert ,  Eberhard Peukert ,  Bernhard Gutsche

    IPC: C07D301/16 ,  C07D301/14 ,  C07D303/04 ,  C07D303/14 ,  C07D303/42

    CPC classification number: C07D303/42 ,  C07D301/14 ,  C07D303/04 ,  C07D303/14 ,  B01J2219/0004

    Abstract: The epoxidation of terminally and/or internally olefinically unsaturated hydrocarbon compounds which are liquid at 50.degree. to 100.degree. C. and at atmospheric pressure (oil phase), in which the oil phase is treated with an acid phase containing acetic acid, hydrogen peroxide and peracetic acid in aqueous solution, after which the aqueous acid phase is separated from the oil phase, the peracetic acid in the aqueous acid phase is regenerated and the regenerated aqueous acid phase is returned to the epoxidation reactor. Epoxidation is carried out using an aqueous acid phase containing at most about 10% by weight of peracetic acid, and the peracetic acid content in the aqueous acid phase is reduced by at most about 50%, based on the peracetic acid content of the aqueous acid phase used, after a single passage through the epoxidation stage. After separation from the oil phase, the aqueous acid phase preferably is cooled before regeneration.

    Abstract translation: 末端和/或内部烯属不饱和烃化合物的环氧化，其在50℃至100℃和大气压（油相）下为液体，其中油相用含有乙酸，过氧化氢和 过乙酸在水溶液中，然后从油相中分离含水酸相，酸性水相中的过乙酸再生，再生的含水酸相返回到环氧化反应器。 使用含有至多约10重量％过乙酸的含水酸相进行环氧化，基于酸水溶液的过乙酸含量，酸性水相中的过乙酸含量减少至多约50％ 在单次通过环氧化阶段后使用。 从油相分离后，酸性水相优选在再生前冷却。

    Process for the production of triglycerides
    8.
    发明授权
    Process for the production of triglycerides 失效
    甘油三酯生产工艺

    公开(公告)号：US5254722A

    公开(公告)日：1993-10-19

    申请号：US195995

    申请日：1988-05-19

    Applicant: Eberhard Peukert ,  Horst Rutzen ,  Gerhard Wollmann

    Inventor： Eberhard Peukert ,  Horst Rutzen ,  Gerhard Wollmann

    IPC: C07C67/03 ,  B01J27/232 ,  C07B61/00 ,  C07C69/18 ,  C07C69/30

    CPC classification number: C07C67/03

    Abstract: A process for the production of triglycerides of C.sub.1 -C.sub.4 alkyl esters of C.sub.6 -C.sub.22 fatty acids:a) where dry sodium carbonate catalyst is dissolved in glycerol and mixed with a molar excess of preferably the methyl ester of C.sub.6 -C.sub.22 fatty acid at a temperature between about 150.degree. C. and 250.degree. C. at less than atmospheric pressure and under substantially anhydrous conditions to produce an initial reaction mixture containing the corresponding triglycerides of said fatty acids, and partially reacted glycerol with unreacted hydroxyl groups (OH values 10-40),b) thereafter, a portion of the initial reaction mixture is reacted with additional C.sub.1 -C.sub.4 alkyl ester of C.sub.6 -C.sub.22 fatty acid under conditions to achieve substantially full conversion of said unreacted hydroxyl groups (OH values of 5 or less), andc) a product containing the corresponding triglycerides of said fatty acids is separated from unreacted alkyl ester and from the sodium carbonate catalyst. Improved light colored triglyceride products are achieved and can be separated readily from the sodium carbonate catalyst by filtration.

    Abstract translation: 制备C 6 -C 22脂肪酸的C 1 -C 4烷基酯的甘油三酸酯的方法：a）其中将干燥的碳酸钠催化剂溶解在甘油中，并与摩尔过量的优选C6-C22脂肪酸的甲酯在 温度在约150℃至250℃之间，低于大气压和基本无水条件下，以产生含有所述脂肪酸的相应甘油三酸酯和部分反应的甘油与未反应的羟基的初始反应混合物（OH值10- 40），b）此后，一部分初始反应混合物与另外的C 6 -C 22脂肪酸的C 1 -C 4烷基酯在使所述未反应的羟基基本上完全转化（OH值为5以下）的条件下反应， 和c）含有所述脂肪酸的相应甘油三酯的产物与未反应的烷基酯和碳酸钠催化剂分离。 实现了改进的浅色甘油三酸酯产物，并且可以通过过滤容易地与碳酸钠催化剂分离。

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