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    Substituted lactones of amino acids
    1.
    发明授权
    Substituted lactones of amino acids 失效
    取代的氨基酸内酯

    公开(公告)号：US4513139A

    公开(公告)日：1985-04-23

    申请号：US393812

    申请日：1982-06-30

    申请人： Jacques Martel ,  Jean Tessier ,  Andre Teche

    发明人： Jacques Martel ,  Jean Tessier ,  Andre Teche

    IPC分类号： C07D307/33 ,  C07D207/16 ,  C07D307/93 ,  C07D405/04

    CPC分类号： C07D207/16

    摘要： Novel substituted lactones of amino acids in all their possible stereoisomeric forms or mixtures thereof of the formula ##STR1## wherein A is a hydrocarbon chain of 1 to 10 chain members containing one or more heteroatoms and one or more unsaturations and the chain members being a mono- or polycyclic system or comprises a system of spiro or endo type and may contain one or more chiral atoms or the lactone copula can present a supplementary chirality due to the asymetric spatial configuration of the molecule make up and R is selected from the group consisting of ##STR2## wherein Z is the organic remainder of an amino acid of the formula ##STR3## Y is derived from a primary, secondary or tertiary alcohol of the formula Y--OH and B is the remainder of a heterocyclic amino acid of 3 to 6 carbon atoms of the formula ##STR4## and their preparation and their use for the resolution of amino acids.

    摘要翻译： 新颖的氨基酸的取代的内酯以其所有可能的立体异构体形式或其混合物，其中A为具有1至10个含有一个或多个杂原子和一个或多个不饱和基团的链成员的烃链，链成员为 单环或多环系统或包含螺或内型的系统，并且可以含有一个或多个手性原子，或由于分子组成的不对称空间构型，内酯共聚物可呈现辅助手性，并且R选自 其中Z是下式的氨基酸的有机剩余部分：III1衍生自式Y-OH的伯，仲或叔醇，B是杂环氨基酸的剩余部分3 至6个碳原子，它们的制备及其用于分解氨基酸的用途。

    Substituted pyridine methyl esters of dimethyl cyclopropane carboxylic acids and their use as insecticides
    2.
    发明授权
    Substituted pyridine methyl esters of dimethyl cyclopropane carboxylic acids and their use as insecticides 失效
    二甲基环丙烷羧酸的取代吡啶甲酯及其作为杀虫剂的用途

    公开(公告)号：US4357335A

    公开(公告)日：1982-11-02

    申请号：US280547

    申请日：1981-07-06

    申请人： Jacques Martel ,  Jean Tessier ,  Andre Teche ,  Jean-Pierre Demoute

    发明人： Jacques Martel ,  Jean Tessier ,  Andre Teche ,  Jean-Pierre Demoute

    IPC分类号： A01N53/04 ,  A01N53/00 ,  A01N53/08 ,  A61K31/44 ,  C07D213/64 ,  C07D213/643 ,  C07D213/647 ,  C07D213/70 ,  C07D405/12 ,  C07D409/12 ,  C07D213/55

    CPC分类号： C07D213/643 ,  A01N53/00 ,  A61K31/44 ,  C07D213/647 ,  C07D213/70

    摘要： Novel esters in all possible isomeric forms and mixtures thereof of the formula ##STR1## wherein A is selected from the group consisting of ##STR2## R is selected from the group consisting of hydrogen, --CN and --C.tbd.CH, Y is selected from the group consisting of oxygen and sulfur, Z is selected from the group consisting of alkyl and alkoxy of 1 to 4 carbon atoms, alkylthio and alkylsulfonyl of 1 to 4 carbon atoms, cycloalkyl of 3 to 4 carbon atoms, 3,4-methylenedioxy, chlorine, fluorine and bromine, n is an integer of 0, 1 or 2, Z.sub.1 and Z.sub.2 may both be methyl or Z.sub.1 is hydrogen and Z.sub.2 is ##STR3## R.sub.3 is selected from the group consisting of hydrogen and halogen, R.sub.1 and R.sub.2 are individually alkyl of 1 to 8 carbon atoms or taken together with the carbon they are attached to form cycloalkyl of 3 to 6 carbon atoms or ##STR4## X is selected from the group consisting of oxygen and sulfur, T is at least one member of the group consisting of halogen, alkyl of 1 to 8 carbon atoms, alkoxy of 1 to 8 carbon atoms optionally substituted with at least one halogen and --CF.sub.3 and m is an integer from 0, 1 or 2 having insecticidal activity as well as nematocidal and acaricidal activity.

    摘要翻译： 所有可能的异构体形式的新型酯及其下式的混合物，其中A选自由下列组成的组：R 1选自氢，-CN和-C 3位CH，Y选自 Z为选自由1至4个碳原子的烷基和烷氧基组成的组，1至4个碳原子的烷硫基和烷基磺酰基，3至4个碳原子的环烷基，3,4-亚甲二氧基 ，氯，氟和溴，n是0,1或2的整数，Z1和Z2都可以是甲基或Z1是氢，Z2是选自氢和卤素，R1和R2 具有1至8个碳原子的单独烷基或与它们所连接的碳一起形成3至6个碳原子的环烷基，或者X选自氧和硫，T是至少一个 由卤素，1至8个碳原子的烷基，1至8个的烷氧基组成的组 任选被至少一个卤素和-CF 3取代的碳原子，m是具有杀虫活性以及杀线虫和杀螨活性的0,1或2的整数。

    Cyclopropane carboxylic esters and acids
    6.
    发明授权
    Cyclopropane carboxylic esters and acids 失效
    环丙烷羧酸酯和酸

    公开(公告)号：US4808749A

    公开(公告)日：1989-02-28

    申请号：US932179

    申请日：1986-11-18

    申请人： Jacques Martel ,  Jean Tessier ,  Andre Teche

    发明人： Jacques Martel ,  Jean Tessier ,  Andre Teche

    IPC分类号： A01N53/00 ,  A01N53/02 ,  A23K1/16 ,  A61K31/22 ,  A61K31/225 ,  C07D213/64 ,  C07D213/647 ,  C07D233/74 ,  C07F9/40 ,  C07C121/46 ,  C07C53/134

    CPC分类号： C07D213/647 ,  A01N53/00 ,  A23K20/105 ,  A23K20/111 ,  A61K31/22 ,  A61K31/225 ,  C07D233/74 ,  C07F9/4006

    摘要： Novel esters in all possible isomeric forms of the formula ##STR1## wherein R is selected from the group consisting of (a) optionally unsaturated alkyl of 1 to 8 carbon atoms and optionally unsaturated cycloalkyl or cycloalkyl-alkyl of 3 to 8 carbon atoms optionally substituted with at least one member of the group consisting of halogen, --OH, --SH, --OR', --SR', --NO.sub.2, ##STR2## --CN, --SO.sub.3 H, --PO.sub.4 H.sub.2, ##STR3## --SO.sub.2 AlK.sub.2, --SO.sub.3 AlK.sub.3, aryl optionally substituted with at least one member of the group consisting of --OH, alkoxy of 1 to 8 carbon atoms, alkyl of 1 to 8 carbon atoms, halogen, --CF.sub.3, --OCF.sub.3, --SCF.sub.3 and ##STR4## R' is alkyl of 1 to 8 carbon atoms, R" and R"' are individually selected from the group consisting of hydrogen and alkyl of 1 to 8 carbon atoms, AlK.sub.1, AlK.sub.2 and AlK.sub.3 are individually alkyl of 1 to 18 carbon atoms, (b) aryl of 6 to 14 carbon atoms optionally substituted with at least one substitutent selected from the group consisting of --OH, alkoxy of 1 to 8 carbon atoms, alkyl of 1 to 8 carbon atoms, halogen, --OCF.sub.3, --CF.sub.3 and --SCF.sub.3 and (c) heterocycle optionally substituted with at least one member of the group consisting of --OH, alkoxy of 1 to 8 carbon atoms, alkyl of 1 to 8 carbon atoms, halogen, --CF.sub.3, --OCF.sub.3 and --SCF.sub.3, B is selected from the group consisting of optionally unsaturated alkyl of 1 to 18 carbon atoms, optionally unsaturated cycloalkyl of 3 to 18 carbon atoms and the remainder of an alcohol used in synthesis of pyrethrinoid esters, X is halogen and the ethylenic double bond may have Z or E geometry having parasitic activity, especially insecticidal acaricidal and nematocidal activity.

    摘要翻译： 式（Ⅰ）的所有可能异构体形式的新型酯，其中R选自（a）1-8个碳原子的任选不饱和烷基和任选不饱和的环烷基或3-8个碳原子的环烷基 - 烷基， 被至少一个由卤素，-OH，-SH，-OR'，-SR'，-NO 2，-CN，-SO 3 H，-PO 4 H 2，-SO 2 AlK 2，-SO 3 AlK 3 任选被-OH，1-8个碳原子的烷氧基，1-8个碳原子的烷基，卤素，-CF 3，-OCF 3，-SCF 3和R'中的至少一个成员取代的芳基是 1至8个碳原子的烷基，R“和R”'分别选自氢和1至8个碳原子的烷基，AlK1，AlK2和AlK3分别为1至18个碳原子的烷基（ b）6至14个碳原子的芳基，任选被至少一个选自-OH，1至8个碳原子的烷氧基，1〜 8个碳原子，卤素，-OCF 3，-CF 3和-SCF 3和（c）任选被至少一个选自-OH，1-8个碳原子的烷氧基，1至8个碳原子的烷基取代的杂环， 卤素，-CF 3，-OCF 3和-SCF 3，B选自任选不饱和的1至18个碳原子的烷基，任选地具有3至18个碳原子的不饱和环烷基，剩余的用于合成除虫菊酯的醇 X是卤素，烯键式双键可具有具有寄生活性的Z或E几何形状，特别是杀虫杀螨和杀线虫活性。

    Certain cyclopropyl dicarboxylates having pesticidal and insecticidal activity
    7.
    发明授权
    Certain cyclopropyl dicarboxylates having pesticidal and insecticidal activity 失效
    某些具有杀虫活性和杀虫活性的环丙基二羧酸酯

    公开(公告)号：US4732903A

    公开(公告)日：1988-03-22

    申请号：US756396

    申请日：1985-07-17

    申请人： Jacques Martel ,  Jean Tessier ,  Andre Teche

    发明人： Jacques Martel ,  Jean Tessier ,  Andre Teche

    IPC分类号： A01N53/00 ,  A23K1/16 ,  A61K31/22 ,  C07D209/48 ,  C07D213/64 ,  C07D213/647 ,  C07D233/72 ,  C07D307/20 ,  C07D307/45 ,  C07D309/12 ,  C07D213/55 ,  A01N43/40 ,  C07C69/743 ,  C07C121/75

    CPC分类号： C07D213/647 ,  A01N53/00 ,  A23K20/105 ,  A23K20/111 ,  A23K20/132 ,  A61K31/22 ,  C07D209/48 ,  C07D233/72 ,  C07D307/20 ,  C07D307/42 ,  C07D309/12

    摘要： Novel isomers and mixtures thereof of cyclopropane carboxylic acid derivatives with a 3-unsaturated side chain of the formula ##STR1## wherein A' is selected from the group consisting of wherein B is selected from the group consisting of --CH.sub.2 --, ##STR2## --O-- and --S--, R.sub.4 is selected from the group consisting of hydrogen, --CH.sub.3,--C.tbd.N--CONH.sub.2, --CSNH.sub.2 and --C.tbd.CH, n is an integer from 0, 1 or 2 and R.sub.5 is selected from the group consisting of halogen and --CH.sub.3 ##STR3## wherein R.sub.13 is selected from the group consisting of hydrogen and ##STR4## wherein R.sub.13 has the above definition and the benzoyl is in the 3- or 4-position, ##STR5## wherein R.sub.14 is selected from the group consisting of hydrogen, methyl, ethynyl and --CN and R.sub.15 and R.sub.16 are individually selected from the group consisting of hydrogen, bromine and fluorine and ##STR6## wherein R.sub.14 has the above definition, p is 0, 1 or 2, each R.sub.17 is selected from the group consisting of alkyl of 1 to 4 carbon atoms, alkoxy of 1 to 4 carbon atoms, alkylthio of 1 to 4 carbon atoms, alkylsulfonyl of 1 to 4 carbon atoms, --CF.sub.3, 3,4-methylenedioxy, chlorine, bromine and fluorine B' is selected from the group consisting of --O-- and --S-- and R is selected from the group consisting of alkyl of 1 to 18 carbon atoms substituted with one or more, optionally different functional groups, aryl of 6 to 14 carbon atoms optionally substituted with one or more optionally different functional groups, the double bond having Z or E geometry having insecticidal and nematocidal activity as well as plant and animal acaricidal activity and their preparation.

    摘要翻译： 环丙烷羧酸衍生物与式（I）所示的3-不饱和侧链的新颖异构体及其混合物，其中A'选自由下列组成的组：其中B选自： -CH 2 - ， -O-和-S-，R 4选自氢，-CH 3，-C 3BOND N CONH 2，-CSNH 2和-C 3 CH 3，n是0的整数， （3）其中R 13选自氢和（4）其中R 13具有上述基团，其中R 13选自氢和 （14）其中R 14选自氢，甲基，乙炔基和-CN，R 15和R 16分别选自氢， ，溴和氟，并且其中R 14具有上述定义，p为0,1或2，每个R 17选自1至4个碳原子的烷基 1至4个碳原子的烷氧基，1至4个碳原子的烷硫基，1至4个碳原子的烷基磺酰基，-CF 3，3,4-亚甲二氧基，氯，溴和氟B'选自： -O-和-S-，并且R选自被一个或多个任选不同的官能团取代的1至18个碳原子的烷基，任选被一个或多个任选不同的官能团取代的6至14个碳原子的芳基 组，具有Z或E几何形状的双键具有杀虫和杀线虫活性以及植物和动物杀螨活性及其制备。

    Ethers of pantolactone
    8.
    发明授权
    Ethers of pantolactone 失效
    泛酸内酯醚

    公开(公告)号：US4658043A

    公开(公告)日：1987-04-14

    申请号：US745653

    申请日：1985-06-17

    申请人： Jacques Martel ,  Jean Tessier ,  Andre Teche

    发明人： Jacques Martel ,  Jean Tessier ,  Andre Teche

    IPC分类号： B01J31/02 ,  C07B31/00 ,  C07B57/00 ,  C07B61/00 ,  C07C27/00 ,  C07C29/10 ,  C07C29/88 ,  C07C37/86 ,  C07C41/18 ,  C07C43/295 ,  C07C45/57 ,  C07C51/487 ,  C07C62/02 ,  C07C62/04 ,  C07C67/00 ,  C07D307/33 ,  C07D307/88 ,  C07D307/93 ,  C07D315/00

    CPC分类号： C07D307/33 ,  C07C29/10 ,  C07C41/26 ,  C07C43/295 ,  C07C45/57 ,  C07D307/93 ,  C07D315/00 ,  C07B2200/07 ,  C07C2101/14

    摘要： Novel ethers of organic compounds containing chiral atoms of the formula ##STR1## wherein A is a hydrocarbonated chain of 1 to 10 groups, the said chain containing one or more heteroatoms, one or more unsaturations, the assembly of the groups constituting the chain may represent a mono- or polycyclic system, including a system of the spiro or endo type, the chain A can contain one or more chiral atoms or the lactone moiety can present a chirality due to the dissymetric spatial configuration of the whole of the molecule and Z is selected from the group consisting of primary, secondary or tertiary alcohol moiety containing at least an asymetric carbon atom, a phenol moiety substituted comprising at least one asymetric carbon atom and a substituted alcohol or phenol moiety with a chirality due to the dissymetric spatial configuration of the whole of the molecule, with the proviso Z is not (R) or (S) .alpha.-cyano-3-phenoxy-benzyl when A is ##STR2## which are useful for the resolution of compounds of the formulae ##STR3## wherein A and Z have the above definitions and X is selected from the group consisting of hydrogen and alkyl of 1 to 4 carbon atoms.

    摘要翻译： 含有式（I）的手性原子的有机化合物的新型醚，其中A是1至10个基团的烃化链，所述链含有一个或多个杂原子，一个或多个不饱和基团，构成链的基团的组合 代表单环或多环系统，包括螺或内型的系统，链A可以含有一个或多个手性原子，或者内酯部分可以呈现手性，这是由于整个分子的不对称空间结构和Z 选自至少含有不对称碳原子的伯醇，仲醇或叔醇部分，被至少一个不对称碳原子取代的苯酚部分和取代的醇或苯酚部分具有由于不对称空间构型引起的手性 整个分子，条件是Z不是（R）或（S）α-氰基-3-苯氧基 - 苄基，当A是，它们可用于共沉淀 式II或ZOH III的化合物，其中A和Z具有上述定义，X选自氢和1至4个碳原子的烷基。

    Substituted lactones of amino acids
    10.
    发明授权
    Substituted lactones of amino acids 失效
    取代的氨基酸内酯

    公开(公告)号：US4350637A

    公开(公告)日：1982-09-21

    申请号：US212569

    申请日：1980-12-03

    申请人： Jacques Martel ,  Jean Tessier ,  Andre Teche

    发明人： Jacques Martel ,  Jean Tessier ,  Andre Teche

    IPC分类号： C07D307/33 ,  C07D207/16 ,  C07D307/93 ,  C07D307/77 ,  C07D307/32 ,  C07D309/30

    CPC分类号： C07D207/16

    摘要： Novel substituted lactones of amino acids in all their possible stereoisomeric forms or mixtures thereof of the formula ##STR1## wherein A is a hydrocarbon chain of 1 to 10 chain members containing one or more heteroatoms and one or more unsaturations and the chain members being a mono- or polycyclic system or comprises a system of spiro or endo type and may contain one or more chiral atoms or the lactone copula can present a supplementary chirality due to the asymetric spatial configuration of the molecule make up and R is selected from the group consisting of: ##STR2## wherein Z is the organic remainder of an amino acid of the formula: ##STR3## Y is derived from a primary, secondary or tertiary alcohol of the formula Y-OH and B is the remainder of a heterocycle amino acid of 3 to 6 carbon atoms of the formula: ##STR4## and their preparation and their use for the resolution of amino acids.

    摘要翻译： 新颖的氨基酸的取代的内酯以其所有可能的立体异构体形式或其混合物，其中A为具有1至10个含有一个或多个杂原子和一个或多个不饱和基团的链成员的烃链，链成员为 单环或多环系统或包含螺或内型的系统，并且可以含有一个或多个手性原子，或由于分子组成的不对称空间构型，内酯共聚物可呈现辅助手性，并且R选自 其中Z是下式的氨基酸的有机剩余物：III1Y衍生自式Y-OH的伯，仲或叔醇，B是杂环氨基酸的剩余部分 3至6个碳原子的结构式：它们的制备及其用于分解氨基酸的用途。