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    Substituted lactones of amino acids
    1.
    发明授权
    Substituted lactones of amino acids 失效
    取代的氨基酸内酯

    公开(公告)号：US4513139A

    公开(公告)日：1985-04-23

    申请号：US393812

    申请日：1982-06-30

    Applicant: Jacques Martel ,  Jean Tessier ,  Andre Teche

    Inventor： Jacques Martel ,  Jean Tessier ,  Andre Teche

    IPC: C07D307/33 ,  C07D207/16 ,  C07D307/93 ,  C07D405/04

    CPC classification number: C07D207/16

    Abstract: Novel substituted lactones of amino acids in all their possible stereoisomeric forms or mixtures thereof of the formula ##STR1## wherein A is a hydrocarbon chain of 1 to 10 chain members containing one or more heteroatoms and one or more unsaturations and the chain members being a mono- or polycyclic system or comprises a system of spiro or endo type and may contain one or more chiral atoms or the lactone copula can present a supplementary chirality due to the asymetric spatial configuration of the molecule make up and R is selected from the group consisting of ##STR2## wherein Z is the organic remainder of an amino acid of the formula ##STR3## Y is derived from a primary, secondary or tertiary alcohol of the formula Y--OH and B is the remainder of a heterocyclic amino acid of 3 to 6 carbon atoms of the formula ##STR4## and their preparation and their use for the resolution of amino acids.

    Abstract translation: 新颖的氨基酸的取代的内酯以其所有可能的立体异构体形式或其混合物，其中A为具有1至10个含有一个或多个杂原子和一个或多个不饱和基团的链成员的烃链，链成员为 单环或多环系统或包含螺或内型的系统，并且可以含有一个或多个手性原子，或由于分子组成的不对称空间构型，内酯共聚物可呈现辅助手性，并且R选自 其中Z是下式的氨基酸的有机剩余部分：III1衍生自式Y-OH的伯，仲或叔醇，B是杂环氨基酸的剩余部分3 至6个碳原子，它们的制备及其用于分解氨基酸的用途。

    Substituted pyridine methyl esters of dimethyl cyclopropane carboxylic acids and their use as insecticides
    2.
    发明授权
    Substituted pyridine methyl esters of dimethyl cyclopropane carboxylic acids and their use as insecticides 失效
    二甲基环丙烷羧酸的取代吡啶甲酯及其作为杀虫剂的用途

    公开(公告)号：US4357335A

    公开(公告)日：1982-11-02

    申请号：US280547

    申请日：1981-07-06

    Applicant: Jacques Martel ,  Jean Tessier ,  Andre Teche ,  Jean-Pierre Demoute

    Inventor： Jacques Martel ,  Jean Tessier ,  Andre Teche ,  Jean-Pierre Demoute

    IPC: A01N53/04 ,  A01N53/00 ,  A01N53/08 ,  A61K31/44 ,  C07D213/64 ,  C07D213/643 ,  C07D213/647 ,  C07D213/70 ,  C07D405/12 ,  C07D409/12 ,  C07D213/55

    CPC classification number: C07D213/643 ,  A01N53/00 ,  A61K31/44 ,  C07D213/647 ,  C07D213/70

    Abstract: Novel esters in all possible isomeric forms and mixtures thereof of the formula ##STR1## wherein A is selected from the group consisting of ##STR2## R is selected from the group consisting of hydrogen, --CN and --C.tbd.CH, Y is selected from the group consisting of oxygen and sulfur, Z is selected from the group consisting of alkyl and alkoxy of 1 to 4 carbon atoms, alkylthio and alkylsulfonyl of 1 to 4 carbon atoms, cycloalkyl of 3 to 4 carbon atoms, 3,4-methylenedioxy, chlorine, fluorine and bromine, n is an integer of 0, 1 or 2, Z.sub.1 and Z.sub.2 may both be methyl or Z.sub.1 is hydrogen and Z.sub.2 is ##STR3## R.sub.3 is selected from the group consisting of hydrogen and halogen, R.sub.1 and R.sub.2 are individually alkyl of 1 to 8 carbon atoms or taken together with the carbon they are attached to form cycloalkyl of 3 to 6 carbon atoms or ##STR4## X is selected from the group consisting of oxygen and sulfur, T is at least one member of the group consisting of halogen, alkyl of 1 to 8 carbon atoms, alkoxy of 1 to 8 carbon atoms optionally substituted with at least one halogen and --CF.sub.3 and m is an integer from 0, 1 or 2 having insecticidal activity as well as nematocidal and acaricidal activity.

    Abstract translation: 所有可能的异构体形式的新型酯及其下式的混合物，其中A选自由下列组成的组：R 1选自氢，-CN和-C 3位CH，Y选自 Z为选自由1至4个碳原子的烷基和烷氧基组成的组，1至4个碳原子的烷硫基和烷基磺酰基，3至4个碳原子的环烷基，3,4-亚甲二氧基 ，氯，氟和溴，n是0,1或2的整数，Z1和Z2都可以是甲基或Z1是氢，Z2是选自氢和卤素，R1和R2 具有1至8个碳原子的单独烷基或与它们所连接的碳一起形成3至6个碳原子的环烷基，或者X选自氧和硫，T是至少一个 由卤素，1至8个碳原子的烷基，1至8个的烷氧基组成的组 任选被至少一个卤素和-CF 3取代的碳原子，m是具有杀虫活性以及杀线虫和杀螨活性的0,1或2的整数。

    Insecticidal esters
    6.
    发明授权
    Insecticidal esters 失效
    杀虫剂

    公开(公告)号：US4489093A

    公开(公告)日：1984-12-18

    申请号：US495481

    申请日：1983-05-17

    Applicant: Jacques Martel ,  Jean Tessier ,  Andre Teche

    Inventor： Jacques Martel ,  Jean Tessier ,  Andre Teche

    IPC: A01N53/00 ,  A01N53/02 ,  A23K1/16 ,  A61K31/22 ,  A61K31/225 ,  C07D213/64 ,  C07D213/647 ,  C07D233/74 ,  C07F9/40 ,  C07C69/743 ,  C07C121/75

    CPC classification number: C07D213/647 ,  A01N53/00 ,  A23K20/105 ,  A23K20/111 ,  A61K31/22 ,  A61K31/225 ,  C07D233/74 ,  C07F9/4006

    Abstract: Novel esters in all possible isomeric forms of the formula ##STR1## wherein R is selected from the group consisting of (a) optionally unsaturated alkyl of 1 to 8 carbon atoms and optionally unsaturated cycloalkyl or cycloalkyl-alkyl of 3 to 8 carbon atoms optionally substituted with at least one member of the group consisting of halogen, ##STR2## aryl optionally substituted with at least one member of the group consisting of --OH, alkoxy of 1 to 8 carbon atoms, alkyl of 1 to 8 carbon atoms, halogen, ##STR3## R' is alkyl of 1 to 8 carbon atoms, R" and R"' are individually selected from the group consisting of hydrogen and alkyl of 1 to 8 carbon atoms, AlK.sub.1, AlK.sub.2 and AlK.sub.3 are individually alkyl of 1 to 18 carbon atoms (b) aryl of 6 to 14 carbon atoms optionally substituted with at least one substituent selected from the group consisting of --OH, alkoxy of 1 to 8 carbon atoms, alkyl of 1 to 8 carbon atoms, halogen, --OCF.sub.3, --CF.sub.3 and --SCF.sub.3 and (c) heterocycle optionally substituted with at least one member of the group consisting of --OH, alkoxy of 1 to 8 carbon atoms, alkyl of 1 to 8 carbon atoms, halogen, --CF.sub.3, --OCF.sub.3 and --SCF.sub.3, B is selected from the group consisting of optionally unsaturated alkyl of 1 to 18 carbon atoms, optionally unsaturated cycloalkyl of 3 to 18 carbon atoms and the remainder of an alcohol used in synthesis of pyrethrinoid esters, X is halogen and the ethylenic double bond may have Z or E geometry having parasitic activity, especially insecticidal acaricidal and nematocidal activity.

    Abstract translation: 式（Ⅰ）的所有可能异构体形式的新型酯，其中R选自（a）1-8个碳原子的任选不饱和烷基和任选不饱和的环烷基或3-8个碳原子的环烷基 - 烷基， 被至少一个由以下组成的组中的至少一个取代：卤素，任选被至少一个由以下组成的组中的一个基团取代：-OH，含有1-8个碳原子的烷氧基， 1至8个碳原子，卤素，R'是1至8个碳原子的烷基，R“和R”'分别选自氢和1至8个碳原子的烷基，AlK1， AlK 2和AlK 3分别是1至18个碳原子的烷基（b）任选被至少一个选自-OH，1至8个碳原子的烷氧基，1至8个碳原子的烷基取代的6至14个碳原子的芳基， 8个碳原子，卤素，-OCF 3，-CF 3和-SCF 3和（c）任选的杂环 由至少一个由-OH组成的基团，1至8个碳原子的烷氧基，1至8个碳原子的烷基，卤素，-CF 3，-OCF 3和-SCF 3，B选自任选的 具有1至18个碳原子的不饱和烷基，3至18个碳原子的任选不饱和环烷基和用于合成除虫菊酯的醇的其余部分，X是卤素，烯键双键可具有具有寄生活性的Z或E几何形状，特别是 杀虫杀螨和杀线虫活性。

    Preparation of .alpha.-cyano-phenoxy-benzyl esters
    7.
    发明授权
    Preparation of .alpha.-cyano-phenoxy-benzyl esters 失效
    α-氰基 - 苯氧基 - 苄基酯的制备

    公开(公告)号：US4434294A

    公开(公告)日：1984-02-28

    申请号：US307690

    申请日：1981-10-01

    Applicant: Jacques Martel ,  Jean Tessier ,  Andre Teche

    Inventor： Jacques Martel ,  Jean Tessier ,  Andre Teche

    IPC: C07C255/39 ,  A01N53/00 ,  C07C67/00 ,  C07C213/00 ,  C07C253/00 ,  C07D333/32 ,  C07C121/75 ,  C07D307/20

    CPC classification number: A01N53/00

    Abstract: Novel imino derivatives of esters of 3-formyl-cyclopropane-1-carboxylic acids in their various isomeric forms and mixtures thereof of the formula ##STR1## wherein Z is an organic residue of a primary amine of the formula Z--NH.sub.2 and the acid moiety may have the cis or trans configuration and the alcohol moiety may have the R,S or RS configuration, novel intermediates therefore and a process for the preparation of the corresponding 3-substituted vinyl esters having insecticidal activity.

    Abstract translation: 3-甲酰基 - 环丙烷-1-羧酸酯的各种异构体形式的新颖的亚氨基衍生物及其混合物，其中Z是式Z-NH 2的伯胺和酸的有机残基 部分可以具有顺式或反式构型，并且醇部分可以具有R，S或RS构型，因此是新的中间体，以及制备相应的具有杀虫活性的3-取代乙烯基酯的方法。

    Cyclopropane carboxylic esters and acids
    10.
    发明授权
    Cyclopropane carboxylic esters and acids 失效
    环丙烷羧酸酯和酸

    公开(公告)号：US4808749A

    公开(公告)日：1989-02-28

    申请号：US932179

    申请日：1986-11-18

    Applicant: Jacques Martel ,  Jean Tessier ,  Andre Teche

    Inventor： Jacques Martel ,  Jean Tessier ,  Andre Teche

    IPC: A01N53/00 ,  A01N53/02 ,  A23K1/16 ,  A61K31/22 ,  A61K31/225 ,  C07D213/64 ,  C07D213/647 ,  C07D233/74 ,  C07F9/40 ,  C07C121/46 ,  C07C53/134

    CPC classification number: C07D213/647 ,  A01N53/00 ,  A23K20/105 ,  A23K20/111 ,  A61K31/22 ,  A61K31/225 ,  C07D233/74 ,  C07F9/4006

    Abstract: Novel esters in all possible isomeric forms of the formula ##STR1## wherein R is selected from the group consisting of (a) optionally unsaturated alkyl of 1 to 8 carbon atoms and optionally unsaturated cycloalkyl or cycloalkyl-alkyl of 3 to 8 carbon atoms optionally substituted with at least one member of the group consisting of halogen, --OH, --SH, --OR', --SR', --NO.sub.2, ##STR2## --CN, --SO.sub.3 H, --PO.sub.4 H.sub.2, ##STR3## --SO.sub.2 AlK.sub.2, --SO.sub.3 AlK.sub.3, aryl optionally substituted with at least one member of the group consisting of --OH, alkoxy of 1 to 8 carbon atoms, alkyl of 1 to 8 carbon atoms, halogen, --CF.sub.3, --OCF.sub.3, --SCF.sub.3 and ##STR4## R' is alkyl of 1 to 8 carbon atoms, R" and R"' are individually selected from the group consisting of hydrogen and alkyl of 1 to 8 carbon atoms, AlK.sub.1, AlK.sub.2 and AlK.sub.3 are individually alkyl of 1 to 18 carbon atoms, (b) aryl of 6 to 14 carbon atoms optionally substituted with at least one substitutent selected from the group consisting of --OH, alkoxy of 1 to 8 carbon atoms, alkyl of 1 to 8 carbon atoms, halogen, --OCF.sub.3, --CF.sub.3 and --SCF.sub.3 and (c) heterocycle optionally substituted with at least one member of the group consisting of --OH, alkoxy of 1 to 8 carbon atoms, alkyl of 1 to 8 carbon atoms, halogen, --CF.sub.3, --OCF.sub.3 and --SCF.sub.3, B is selected from the group consisting of optionally unsaturated alkyl of 1 to 18 carbon atoms, optionally unsaturated cycloalkyl of 3 to 18 carbon atoms and the remainder of an alcohol used in synthesis of pyrethrinoid esters, X is halogen and the ethylenic double bond may have Z or E geometry having parasitic activity, especially insecticidal acaricidal and nematocidal activity.

    Abstract translation: 式（Ⅰ）的所有可能异构体形式的新型酯，其中R选自（a）1-8个碳原子的任选不饱和烷基和任选不饱和的环烷基或3-8个碳原子的环烷基 - 烷基， 被至少一个由卤素，-OH，-SH，-OR'，-SR'，-NO 2，-CN，-SO 3 H，-PO 4 H 2，-SO 2 AlK 2，-SO 3 AlK 3 任选被-OH，1-8个碳原子的烷氧基，1-8个碳原子的烷基，卤素，-CF 3，-OCF 3，-SCF 3和R'中的至少一个成员取代的芳基是 1至8个碳原子的烷基，R“和R”'分别选自氢和1至8个碳原子的烷基，AlK1，AlK2和AlK3分别为1至18个碳原子的烷基（ b）6至14个碳原子的芳基，任选被至少一个选自-OH，1至8个碳原子的烷氧基，1〜 8个碳原子，卤素，-OCF 3，-CF 3和-SCF 3和（c）任选被至少一个选自-OH，1-8个碳原子的烷氧基，1至8个碳原子的烷基取代的杂环， 卤素，-CF 3，-OCF 3和-SCF 3，B选自任选不饱和的1至18个碳原子的烷基，任选地具有3至18个碳原子的不饱和环烷基，剩余的用于合成除虫菊酯的醇 X是卤素，烯键式双键可具有具有寄生活性的Z或E几何形状，特别是杀虫杀螨和杀线虫活性。

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