公开(公告)号：US6003305A

公开(公告)日：1999-12-21

申请号：US922176

申请日：1997-09-02

申请人： Richard J. Martin ,  John D. Stilger ,  Mark R. Holst ,  John D. Young ,  Michael P. Barkdoll ,  Bradley L. Edgar

发明人： Richard J. Martin ,  John D. Stilger ,  Mark R. Holst ,  John D. Young ,  Michael P. Barkdoll ,  Bradley L. Edgar

IPC分类号： B01D53/94 ,  F01N3/01 ,  F01N3/023 ,  F01N3/025 ,  F01N3/037 ,  F01N3/20 ,  F01N3/26 ,  F01N3/28 ,  F01N9/00 ,  F01N13/02 ,  F01N3/00

CPC分类号： F01N9/002 ,  B01D53/9431 ,  F01N13/0097 ,  F01N3/0253 ,  F01N3/027 ,  F01N3/035 ,  F01N3/037 ,  F01N3/26 ,  F01N3/2882 ,  F01N2240/02 ,  F01N2240/16 ,  F01N2330/08 ,  F01N2610/02 ,  F01N2610/03 ,  Y02T10/24 ,  Y02T10/47

摘要： A process is provided for preparing oxymorphone from morphine by:(1) reacting morphine with (1a) an acyl halide or anhydride to form 3-acylmorphine, or (1b) reacting morphine with benzyl-halide to form 3-benzylmorphine;(2) Oxidizing the 6-hydroxy group of the 3-acyl or 3-benzylmorphine so as to form the corresponding 3-acyl or 3-benzylmorphinone; and thereafter either by (3a) or (3b):(3a) introducing a .beta.-oriented hydroxy group at the 14-position of the 3-acyl- or 3-benzyl-morphinone with aqueous hydrogen peroxide and an acid at a temperature of about 15.degree. to about 70.degree. C. to form the 3-acyl or 3-benzyl-14-hydroxymorphinone;(3b) acylating the 3-acyl or 3-benzyl-morphinone with an acylating agent so as to form the dienol acylate followed by oxidizing the dienol acetate to the corresponding 3-acyl or 3-benzyl-14 -hydroxymorphinone;(4) hydrogenating the 3-acyl-14-hydroxymorphinone with a catalyst so as to form the 3-acyloxymorphone;(5) hydrolyzing the 3-acyl-oxymorphone with aqueous acidic or basic solution to form oxymorphone;(6) hydrogenating the 3-benzyl-14-hydroxymorphinone with a catalyst so as to form oxymorphone.

摘要翻译： 提供了通过以下步骤制备吗啡的羟吗啡酮的方法：（1）吗啡与（1a）酰卤或酸酐反应形成3-酰基吗啡，或（1b）使吗啡与苄基卤反应形成3-苄基吗啡; （2）氧化3-酰基或3-苄基吗啡的6-羟基，形成相应的3-酰基或3-苄基吗啡酮; 然后通过（3a）或（3b）：（3a）在3-酰基 - 或3-苄基 - 吗啡酮的14位上引入β-取代的羟基与过氧化氢水溶液和酸在 约15℃至约70℃，以形成3-酰基或3-苄基-14-羟基吗啡酮; （3b）用酰化剂酰化3-酰基或3-苄基吗啡酮，以形成二烯醇酰化物，然后将乙酸烯醇氧化成相应的3-酰基或3-苄基-14-羟基吗啡酮; （4）用催化剂氢化3-酰基-14-羟基吗啡酮以形成3-酰氧基吗啡酮; （5）用酸性或碱性水溶液水解3-酰基羟基吗啡酮以形成羟吗啡酮; （6）用催化剂氢化3-苄基-14-羟基吗啡酮以形成羟吗啡酮。

公开(公告)号：US5533890A

公开(公告)日：1996-07-09

申请号：US393023

申请日：1995-02-23

申请人： Mark R. Holst ,  Richard J. Martin ,  John D. Stilger ,  Samson C. Yee

发明人： Mark R. Holst ,  Richard J. Martin ,  John D. Stilger ,  Samson C. Yee

IPC分类号： F23C99/00 ,  F23G7/06 ,  F23G7/07 ,  F23J15/06 ,  F23D3/40

CPC分类号： F23G7/07 ,  F23C99/006 ,  F23G7/063 ,  F23J15/06 ,  F23G2202/50 ,  F23G2207/101 ,  F23G2207/40 ,  Y02E20/342

摘要： An apparatus and method for the monitoring and abatement of fugitive VOC emissions is disclosed. Suction, generated by a fume pump or a venturi type ejector, pulls air and VOC's from one or more sources of VOC emissions such as the mechanical seals of pumps or compressors. These VOC fumes are collected, separated from any liquids in a knock-out pot, and directed to a flameless combustor/thermal oxidizer comprising a tube packed with heat resistant material and surrounded by an electric heater and thermal insulation. This matrix bed of heat resistant materials is heated to a temperature sufficient to oxidize/destroy the VOC emissions. Thereafter, an optional convective quench section may be used to lower the temperature of the exhaust gases prior to their release to the atmosphere. By monitoring the temperature and/or the amount of power needed, changes in VOC emissions can be detected.

摘要翻译： 公开了一种用于监测和减轻挥发性有机物排放物的方法。 由烟雾泵或文丘里型喷射器产生的吸入可从一个或多个VOC排放源（如泵或压缩机的机械密封）吸入空气和VOC。 这些VOC烟雾被收集，与分离罐中的任何液体分离，并被引导到无焰燃烧器/热氧化器，其包括装有耐热材料并被电加热器和隔热层包围的管。 该耐热材料的矩阵床被加热到足以氧化/破坏VOC排放的温度。 此后，可以使用任选的对流淬火部分来降低废气在释放到大气之前的温度。 通过监测所需功率的温度和/或功率量，可以检测到VOC排放的变化。

公开(公告)号：US5989010A

公开(公告)日：1999-11-23

申请号：US921815

申请日：1997-09-02

申请人： Richard J. Martin ,  John D. Stilger ,  Mark R. Holst ,  John D. Young ,  Bradley L. Edgar

发明人： Richard J. Martin ,  John D. Stilger ,  Mark R. Holst ,  John D. Young ,  Bradley L. Edgar

IPC分类号： F23C99/00 ,  F23D3/40

CPC分类号： F23C99/006 ,  F23G2202/50 ,  F23G2209/14

摘要： A matrix bed is disclosed in which a non-planar reaction wave front is formed during operation. This is accomplished by heating the matrix bed, containing heat-resistant material, until at least a reaction portion of the matrix bed is above the temperature required for a plurality of reactant gas streams to react. Next, the reactant gas streams are directed through the matrix bed in a manner so as to form at least a Bunsen, Burke-Schumann, inverted-V, or some other type of non-planar reaction wave front at the portion of the matrix bed that is heated above the reactant gas streams reaction temperature. At the non-planar reaction wave front, the reactant gas streams react to produce a reaction product gas stream that is then exhausted from the matrix bed.

摘要翻译： 公开了一种矩阵床，其中在操作期间形成非平面反应波前。 这是通过加热含有耐热材料的基质床，直到基质床的至少一个反应部分高于多个反应物气流反应所需的温度来实现的。 接下来，反应物气体流以这样的方式被引导通过基质床，以便在基质床的部分处形成至少Bunsen，Burke-Schumann，倒V或一些其它类型的非平面反应波前 其被加热到反应物气流反应温度以上。 在非平面反应波前，反应气流反应产生反应产物气流，然后将其从基质床中排出。

公开(公告)号：US5921763A

公开(公告)日：1999-07-13

申请号：US641636

申请日：1996-05-02

申请人： Richard J. Martin

发明人： Richard J. Martin

IPC分类号： F23G5/46 ,  F23G7/06 ,  F23D3/40

CPC分类号： F23G5/46 ,  F23G7/06 ,  F23G2202/50 ,  Y02E20/12

摘要： Improved methods for the destruction of methane gas within a colliery ventilation stream are provided that include the efficient utilization of the energy obtained from the oxidation of the methane gas. In practicing the methods, a colliery vent gas, containing a dilute concentration of methane in air, is oxidized within a matrix bed of heat resistant material to convert the methane to oxidation products with the simultaneous release of heat energy. The heat energy is recovered to thermally heat a working fluid used to operate a steam turbine to produce electricity.

摘要翻译： 提供改进的在煤矿通风流中破坏甲烷气体的方法，其包括有效利用从甲烷气体的氧化获得的能量。 在实施这些方法时，在空气中含有稀释的甲烷浓度的煤矿排放气体在耐热材料的基质床内被氧化，以将甲烷转化为氧化产物同时释放热能。 回收热能以热加热用于操作蒸汽轮机的工作流体以产生电力。

公开(公告)号：US5637283A

公开(公告)日：1997-06-10

申请号：US468872

申请日：1995-06-06

申请人： John D. Stilger ,  Richard J. Martin ,  Mark R. Holst ,  Samson C. Yee

发明人： John D. Stilger ,  Richard J. Martin ,  Mark R. Holst ,  Samson C. Yee

IPC分类号： A62D3/00 ,  B01D53/72 ,  B01D53/86 ,  B01J8/00 ,  B01J8/02 ,  B01J8/04 ,  F23C13/00 ,  F23C99/00 ,  F23G5/16 ,  F23G5/50 ,  F23G7/06 ,  C07C11/24

CPC分类号： F23G7/07 ,  B01D53/72 ,  B01D53/8668 ,  B01J8/001 ,  B01J8/0453 ,  F23C13/00 ,  F23C99/006 ,  F23G5/16 ,  F23G5/50 ,  F23G7/06 ,  F23G7/061 ,  F23G2202/103 ,  F23G2202/105 ,  F23G2202/50 ,  F23G2207/101 ,  F23G2207/40

摘要： Methods and apparatus are provided for destruction of volatile organic compounds ("VOC's") from process fumes having variable amounts of such VOC's wherein a nominal amount of the fumes are passed through an oxidizer for destruction of the VOC's and the hot products from the oxidizer are fed to an afterburner that is principally made up of a matrix bed of heat resistant material. The heat from the oxidized gases heats the matrix bed. Fume flows exceeding the nominal flow are bypassed directly to an inlet port of the afterburner where they are passed through the matrix bed of the afterburner, which has been heated by the oxidized gases from the oxidizer, and are combusted into additional gaseous products in a combustion wave. The system allows for utilization of the heat produced from the oxidation of the nominal flow for destructing fume flows that exceed the nominal flow.

摘要翻译： 提供了方法和装置，用于从具有可变量的这种VOC的工艺烟气中破坏挥发性有机化合物（“VOC”），其中标称量的烟雾通过氧化剂以破坏VOC，并且来自氧化剂的热产物是 进料到主要由耐热材料的基质床组成的加力燃烧器。 来自氧化气体的热量加热了基质床。 超过标称流量的烟气流被直接旁路到加力燃烧器的入口，在那里它们通过已经被来自氧化剂的氧化气体加热的再加热器的基质床，并在燃烧中被燃烧成另外的气态产物 波。 该系统允许利用从标称流量的氧化产生的热量来破坏超过额定流量的烟雾流。

公开(公告)号：US6136144A

公开(公告)日：2000-10-24

申请号：US123915

申请日：1998-07-29

申请人： Richard J. Martin ,  John T. Schofield

发明人： Richard J. Martin ,  John T. Schofield

IPC分类号： B01D53/50 ,  B01D53/83 ,  D21C11/00 ,  D21C11/06 ,  D21C11/04

CPC分类号： B01D53/502 ,  B01D53/83 ,  D21C11/0057 ,  D21C11/06 ,  Y02P40/44

摘要： The present invention reduces the sulfur and odor emissions from a paper-making Kraft process by recovering the sulfur in the non-combustible gases (NGCs) emitted by the Kraft process. In a first embodiment of the invention, the NGCs are flamelessly oxidized in a flameless thermal oxidizer to form a sulfur oxide-containing, gaseous products stream. The gaseous products stream is scrubbed with a scrubber solution stream to remove the sulfur components resulting in a scrubbed gas stream and spent scrubber solution stream having S.sub.2 O.sub.3 and SO.sub.4, and SO.sub.3 soluble salts. At least a portion of the spent scrubber solution from the scrubber is directed back into the Kraft process, thus recovering the sulfur. In a second general embodiment of the invention, the NGCs are flamelessly oxidized in a moving, packed bed calcinator. The calcinator receives a lime mud stream from the Kraft process, forms a packed bed therefrom, calcines the packed bed, and releases it as a quick lime stream. Concurrently, the NCGs are directed through the moving, packed bed and are flamelessly oxidized in a reaction wave in the packed bed to form a gaseous products stream with sulfur components. The sulfur components react with the packed bed to form sulfur/calcium components. The sulfur/calcium components exit the calcinator with the quick lime stream and are recovered by the Kraft process.

摘要翻译： 本发明通过回收由牛皮纸方法发射的不可燃气体（NGC）中的硫，减少了造纸牛皮纸工艺的硫和气味排放。 在本发明的第一个实施方案中，NGC在无焰热氧化器中无焰氧化以形成含硫氧化物的气态产物流。 气体产物流用洗涤剂溶液流洗涤以除去硫组分，导致洗涤气流和具有S2O3和SO4以及SO3可溶性盐的废涤气溶液流。 来自洗涤器的废涤洗涤剂溶液的至少一部分被引导回到硫酸盐法，从而回收硫。 在本发明的第二个一般实施方案中，NGC在移动的填充床煅烧器中无焰氧化。 煅烧器从牛皮纸工艺接收石灰泥浆流，从其中形成填充床，煅烧填充床，并将其作为生石灰流释放。 同时，NCG被引导通过移动的填充床，并且在填充床中的反应波中被无焰地氧化以形成具有硫成分的气态产物流。 硫成分与填充床反应形成硫/钙成分。 硫/钙组分用生石灰流离开煅烧器，并通过牛皮纸工艺回收。

公开(公告)号：US06015540A

公开(公告)日：2000-01-18

申请号：US922189

申请日：1997-09-02

申请人： Stephen R. McAdams ,  Bradley L. Edgar ,  Richard J. Martin ,  Marvin M. Kilgo ,  Christopher B. Baer ,  John D. Stilger

发明人： Stephen R. McAdams ,  Bradley L. Edgar ,  Richard J. Martin ,  Marvin M. Kilgo ,  Christopher B. Baer ,  John D. Stilger

IPC分类号： B01J8/00 ,  B01J8/02 ,  B01J8/04 ,  F23C99/00 ,  C01B11/00 ,  F23D11/44 ,  F23B5/20

CPC分类号： F23C99/006 ,  B01J8/001 ,  B01J8/008 ,  B01J8/0242 ,  B01J8/0278 ,  B01J8/04 ,  B01J2208/00061 ,  B01J2208/00097 ,  B01J2208/00495 ,  B01J2208/0084 ,  B01J2219/1942 ,  B01J2219/1946 ,  F23G2202/50 ,  F23G2209/10 ,  F23G2209/14 ,  F23G2209/142

摘要： An improved method and apparatus is provided for thermally reacting chemicals in a matrix bed of porous inert media. The reaction is conducted in an apparatus that is capable of establishing and maintaining a non-planar reaction wave within the matrix bed. The positioning of the non-planar reaction wave permits the interior surfaces of the vessel to be maintained at a temperature at least above 175.degree. F. The apparatus includes a vessel that contains the matrix bed; one or more feed tubes that extend into the matrix bed, where preferably an exterior portion of each of the feed tubes that passes through the vessel is insulated; an exhaust outlet; and a means for heating the matrix bed. The non-planar reaction wave is established by heating at least a portion of the matrix bed to at least the reaction temperature of the chemicals and feeding a process stream containing the chemicals to be reacted into the feed tubes. Upon exiting the feed tubes, the process stream is reacted in a non-planar reaction wave to produce heat and the reacted process stream. The heat from the non-planar reaction wave maintains the interior surfaces of the vessel at a temperature of at least 175.degree. F. during operation of the vessel. The reacted process stream is then directed to the exhaust outlet of the vessel.

摘要翻译： 提供了一种改进的方法和装置，用于使多孔惰性介质的基质床中的化学物质热反应。 反应在能够在基质床内建立和维持非平面反应波的装置中进行。 非平面反应波的定位允许容器的内表面保持在至少高于175°F的温度。该装置包括容纳基质床的容器; 延伸到基质床中的一个或多个进料管，其中优选地，穿过所述容器的每个进料管的外部部分是绝缘的; 排气口 以及用于加热基质床的装置。 通过将至少一部分基质床加热至至少化学品的反应温度并将含有要反应的化学物质的工艺流供给到进料管中来建立非平面反应波。 在离开进料管时，工艺流在非平面反应波中反应以产生热量和反应的工艺流。 来自非平面反应波的热量在容器操作期间将容器的内表面保持在至少175°F的温度。 然后将反应的工艺流引导到容器的排气出口。

公开(公告)号：US5770784A

公开(公告)日：1998-06-23

申请号：US789271

申请日：1997-01-28

申请人： Ann C. Heywood ,  Mark R. Holst ,  Richard J. Martin ,  John T. Schofield

发明人： Ann C. Heywood ,  Mark R. Holst ,  Richard J. Martin ,  John T. Schofield

IPC分类号： F23G5/027 ,  F23G7/06 ,  F23D3/40

CPC分类号： F23G5/027 ,  F23G7/063 ,  F23G2201/50 ,  F23G2202/50

摘要： Improved methods for the treatment of commingled wastes and process systems for practicing those methods are provided. The methods are practiced by first treating the commingled waste material in a primary treatment unit in the presence of a carrier fluid to separate the organic waste from the inorganic waste. The carrier fluid and the gaseous products from the primary unit are then treated in a flameless oxidizer, which efficiently destroys any remaining organic compounds. In one embodiment, the process gases exiting the flameless oxidizer are recycled to the primary treatment unit.

摘要翻译： 提供了改进的方法来处理混合废物和处理系统，用于实践这些方法。 通过在载体流体的存在下首先处理主处理单元中的混合废物以将有机废物与无机废物分离来实施这些方法。 然后将载体流体和来自主要单元的气体产物在无焰的氧化剂中处理，这有效地破坏了任何剩余的有机化合物。 在一个实施方案中，离开无焰氧化剂的处理气体被再循环到主处理单元。

公开(公告)号：US6126913A

公开(公告)日：2000-10-03

申请号：US659579

申请日：1996-06-06

申请人： Richard J. Martin ,  John D. Stilger ,  Mark R. Holst

发明人： Richard J. Martin ,  John D. Stilger ,  Mark R. Holst

IPC分类号： B01J8/02 ,  F23G7/06 ,  B01J8/00 ,  A62D3/00 ,  F23D21/00 ,  F23B5/20

CPC分类号： B01J8/0285 ,  B01J8/025 ,  F23G7/06 ,  B01J2208/00044 ,  B01J2208/00061 ,  B01J2208/00371 ,  B01J2208/00513 ,  F23G2202/50

摘要： The present invention provides thermal oxidizers containing improved preheating designs and processes for improving the preheating of thermal oxidizers. The processes are practiced by preheating the matrix-bed of matrix materials in a flow path that is opposite in direction to the flow path for the processing fluids through the matrix bed. In such a process, there is a substantial reduction in the time and energy required for the preheating of the matrix bed in comparison to the prior processes using same flow direction preheating.

摘要翻译： 本发明提供了包含改进的预热设计和改进热氧化剂预热的方法的热氧化剂。 该过程通过在与通过基质床的加工流体的流动路径相反的流动路径中预热基质材料的基质床来实施。 在这种过程中，与使用相同的流动方向预热的现有方法相比，基体床的预热所需的时间和能量显着减少。

公开(公告)号：US5635139A

公开(公告)日：1997-06-03

申请号：US527545

申请日：1995-09-13

申请人： Mark Holst ,  Richard J. Martin

发明人： Mark Holst ,  Richard J. Martin

IPC分类号： B01D53/44 ,  A62D3/00 ,  B01D53/74 ,  B01D53/86 ,  B01J8/00 ,  B01J8/02 ,  B01J8/04 ,  F23G7/06 ,  G05D9/00 ,  B01D50/00 ,  B01J8/08

CPC分类号： F23G7/07 ,  B01D53/8668 ,  B01J8/001 ,  B01J8/0453 ,  B01J2208/00061 ,  B01J2208/025 ,  F23G2202/50 ,  F23G2207/101 ,  F23G2207/20 ,  F23G2207/30 ,  F23G2207/40

摘要： Apparatuses for treating gas streams containing variations in VOC concentration whereby the VOC's are destroyed in a combination non-catalytic/catalytic oxidation system are disclosed. A non-catalytic destruction matrix composed of inert ceramic materials that enhance process mixing and provide thermal inertia for process stability is used when VOC concentrations are high and a catalytic oxidizer is principally used when VOC concentrations are low. The exhaust from the non-catalytic destruction matrix is passed through the catalytic oxidizer to maintain proper catalytic oxidizer operating temperatures. Supplemental fuel and air are added as appropriate upstream or downstream of the non-catalytic oxidizer to maintain proper heat values in each portion of the system.

摘要翻译： 公开了用于处理含有VOC浓度变化的气流的设备，由此VOC在非催化/催化氧化系统组合中被破坏。 当VOC浓度高时使用由惰性陶瓷材料组成的非催化破坏基质，其增强工艺混合并提供工艺稳定性的热惯性，当VOC浓度低时，主要使用催化氧化剂。 来自非催化破坏基质的废气通过催化氧化剂以保持适当的催化氧化剂操作温度。 补充的燃料和空气适当地在非催化氧化剂的上游或下游添加，以在系统的每个部分中保持适当的热值。