Self-accelerating and replenishing non-formaldehyde immersion coating
method
    2.
    发明授权
    Self-accelerating and replenishing non-formaldehyde immersion coating method 失效
    自加速补充非甲醛浸涂法

    公开(公告)号:US5543182A

    公开(公告)日:1996-08-06

    申请号:US389565

    申请日:1995-02-16

    摘要: A process for applying a metal coating to a non-conductive substrate without an electroless coating is disclosed. The process includes the step of: a. contacting said substrate with an activator comprising a noble metal/Group IVA metal sol to obtain a treated substrate; b. contacting said treated substrate with a self accelerating and replenishing immersion metal composition comprising a solution of (i) a soluble metal salt whose metal is more noble than said Group IVA metal, (ii) a Group IA metal hydroxide, (iii) a complexing agent comprising an organic material having a cumulative formation constant log K of from about 0.73 to about 21.95 for an ion of the metal of said metal salt. The Group IVA metal is employed in a stoichiometric excess compared to the noble metal, the excess Group IVA metal being in its lowest oxidation state. Self accelerating and replenishing non-formaldehyde immersion metal compositions are also disclosed. The composition is used in a two step process to electrolytically coat a nonconductive substrate. In the first step the conductivity of the substrate is increased by applying the composition to it. In the second step, the substrate treated with the composition is electrolytically coated with a metal.

    摘要翻译: 公开了一种将金属涂层施加到不带无电涂层的非导电基底上的方法。 该过程包括以下步骤:a。 使所述衬底与包含贵金属/ IVA族金属溶胶的活化剂接触以获得经处理的衬底; b。 使所述经处理的基材与自加速和补充的浸入金属组合物接触,所述组合物包含(i)其金属比所述IVA族金属更贵的可溶性金属盐,(ii)IA族金属氢氧化物,(iii)络合剂 包括对于所述金属盐的金属的离子,累积形成常数log K为约0.73至约21.95的有机材料。 与贵金属相比,IVA族金属以化学计量过量使用,过量的IVA族金属处于其最低的氧化态。 还公开了自加速和补充非甲醛浸渍金属组合物。 该组合物用于电解涂覆非导电基材的两步法。 在第一步中,通过将组合物施加到基底上来增加基底的电导率。 在第二步骤中,用金属电解涂覆用组合物处理的基材。

    Fluid delivery method
    3.
    发明授权
    Fluid delivery method 失效
    流体输送方法

    公开(公告)号:US6045874A

    公开(公告)日:2000-04-04

    申请号:US187595

    申请日:1998-11-06

    申请人: Ricky A. Himes

    发明人: Ricky A. Himes

    摘要: A fluid delivery method is provided wherein either liquid or gaseous fluid is provided from fluid dispenser manifolds, via nozzle plates associated therewith, on each side of a path of travel of articles being treated by the fluid, and wherein nozzle openings in a nozzle plates cooperate with transverse groove(s) to provide a screen flow of fluid extending transversely of the path of travel of articles, and directed toward the articles. In the case of the fluid being a liquid, the nozzle openings provide cylindrical filament-like columns of liquid which are rendered by the associated grooves into generally flat, transversely disposed screen spray of liquid. In the case of the fluid being a gas, the nozzle openings and transverse grooves cooperate to deliver the gas in transversely spaced apart, transverse, planar zones of gas directed toward the path of article travel.In the case of liquid flow, the openings are generally cylindrical, and in the case of gas flow the openings are generally spaced-apart slotted holes. In the cases of both liquid and gas fluids, one of the grooves and/or nozzles are directed upstream relative to the path of article flow. Various adjustments are provided for adjusting the positions of the nozzle plates relative to the path of flow.The nozzle plate has a removable portion, for ease of cleaning and the like, that contains the nozzle orifices, sealing connected to the nozzle base section. The transverse groove that connects the line of orifices can have its center line varied from the center line of the orifices, in the direction of the longitudinal path, and/or the groove can have its angular orientation varied such that the path of flow of fluid discharged can be at an angle other than 90.degree. to the discharge surface of the nozzle plate.

    摘要翻译: 提供了一种流体输送方法,其中液体或气体流体通过流体分配器歧管通过与其相关联的喷嘴板在由流体处理的制品的行进路径的每一侧上提供,并且其中喷嘴板中的喷嘴开口配合 具有横向槽以提供横向于物品行进路径延伸并且朝向物品的流体的筛网流。 在流体为液体的情况下,喷嘴开口提供圆柱状的细丝状液体柱,其通过相关联的凹槽形成大致平坦的横向设置的液体喷雾。 在流体是气体的情况下,喷嘴开口和横向槽协作以将气体输送到朝向物品行进路径的横向间隔开的横向平坦区域中。 在液体流动的情况下,开口通常是圆柱形的,并且在气流的情况下,开口通常是间隔开的开槽孔。 在液体和气体流体的情况下,凹槽和/或喷嘴之一相对于制品流动的路径被引向上游。 提供了各种调整以调节喷嘴板相对于流动路径的位置。 喷嘴板具有易于清洁等的可移除部分,其包含喷嘴孔,密封件连接到喷嘴基部。 连接孔线的横向槽可以使其中心线从孔的中心线沿着纵向路径的方向变化,和/或者槽可以具有其角度取向变化,使得流体的流动路径 排出口可以与喷嘴板排放面90度以外的角度排出。

    Etchant for aluminum alloys
    4.
    发明授权
    Etchant for aluminum alloys 失效
    铝合金蚀刻剂

    公开(公告)号:US5895563A

    公开(公告)日:1999-04-20

    申请号:US773300

    申请日:1996-12-23

    CPC分类号: C25D5/44

    摘要: An iron immersion composition of matter is disclosed comprising a compound having a divalent or trivalent iron ion, a compound having a fluoride ion, and a compound having an acid hydrogen ion. A process for treating an aluminum substrate to improve the adhesion of metal layers to the substrate is also disclosed comprising contacting the substrate with the acidic iron immersion composition to produce an iron immersion coating on the alloy, and contacting the iron immersion coating with an etchant to substantially remove the coating and produce a microporous surface on the substrate.

    摘要翻译: 公开了一种铁浸渍组合物,其包含具有二价或三价铁离子的化合物,具有氟离子的化合物和具有酸性氢离子的化合物。 还公开了一种用于处理铝基材以改善金属层对基材的粘合性的方法,包括使基材与酸性铁浸渍组合物接触以在合金上产生铁浸渍涂层,并将铁浸渍涂层与蚀刻剂接触 基本上除去涂层并在基底上产生微孔表面。

    High current density zinc chloride electrogalvanizing process and
composition
    5.
    发明授权
    High current density zinc chloride electrogalvanizing process and composition 失效
    高电流密度氯化锌电镀锌工艺及组成

    公开(公告)号:US5656148A

    公开(公告)日:1997-08-12

    申请号:US397479

    申请日:1995-03-02

    IPC分类号: C25D3/22

    CPC分类号: C25D3/22

    摘要: An electrogalvanizing process and composition are disclosed for reducing high current density dendrite (HCD) formation and edge burn and controlling high current density roughness, grain size and orientation of a zinc coating obtained from a zinc halide aqueous acidic electrogalvanic coating bath. A low molecular weight polyoxyalkylene glycol homopolymer or copolymer based on 3 to about 4 carbon atom alkylene oxides as a grain refining agent in combination with a sulfonated condensation product of naphthalene and formaldehyde which is used as an antidendritic agent. A glycol compound comprising a high molecular weight polyoxyalkylene glycol homopolymer or copolymer, a depolarizer such as an aniline compound, and a carbamate compound comprising a di-lower alkyl dithio carbamyl lower alkyl sulfonic acid may also be used, optionally in combination with an aldehyde and/or a grain refining agent such as a low molecular weight polyoxyalkylene glycol homopolymer or copolymer and/or an antidendritic agent comprising a sulfonated condensation product of naphthalene and formaldehyde. HCD zinc coatings applied according to the process described herein will be smoother when using a sulfonated naphthalene formaldehyde antidendritic agent and a low molecular weight ethylene oxide polymer grain refining agent by increasing the antidendritic agent to an amount greater than the grain refining agent. A boron oxide composition can be used to further reduce HCD burn and a lignin compound to increase brightness.

    摘要翻译: 公开了一种用于降低高电流密度枝晶(HCD)形成和边缘烧蚀并控制从卤化锌水性酸性电镀锌浴获得的锌涂层的高电流密度粗糙度,晶粒尺寸和取向的电镀锌方法和组合物。 一种低分子量的聚氧亚烷基二醇均聚物或共聚物,其基于3至约4个碳原子的氧化烯作为晶粒细化剂与萘和甲醛的磺化缩合产物组合,用作抗枝霉剂。 还可以使用包含高分子量聚氧亚烷基二醇均聚物或共聚物的二醇化合物,去极化剂如苯胺化合物和包含二低级烷基二硫代氨基甲酰基低级烷基磺酸的氨基甲酸酯化合物,任选与醛和 /或诸如低分子量聚氧亚烷基二醇均聚物或共聚物的晶粒细化剂和/或包含萘和甲醛的磺化缩合产物的抗枝晶剂。 当使用磺化萘甲醛抗寄生剂和低分子量环氧乙烷聚合物晶粒细化剂时,通过将抗枝晶剂增加到大于晶粒细化剂的量,根据本文所述方法施用的HCD锌涂层将更平滑。 氧化硼组合物可用于进一步减少HCD燃烧和木质素化合物以增加亮度。

    Fluid delivery apparatus and method
    6.
    发明授权
    Fluid delivery apparatus and method 失效
    流体输送装置及方法

    公开(公告)号:US5614264A

    公开(公告)日:1997-03-25

    申请号:US514313

    申请日:1995-08-11

    申请人: Ricky A. Himes

    发明人: Ricky A. Himes

    摘要: A fluid delivery apparatus and method is provided wherein either liquid or gaseous fluid is provided from fluid dispenser manifolds, via nozzle plates associated therewith, on each side of a path of travel of articles being treated by the fluid, and wherein nozzle openings in a nozzle plates cooperate with transverse groove(s) to provide a screen flow of fluid extending transversely of the path of travel of articles, and directed toward the articles. In the case of the fluid being a liquid, the nozzle openings provide cylindrical filament-like columns of liquid which are rendered by the associated grooves into generally flat, transversely disposed semen spray of liquid. In the case of the fluid being a gas, the nozzle openings and transverse grooves cooperate to deliver the gas in transversely spaced apart, transverse, planar zones of gas directed toward the path of article travel.In the case of liquid flow, the openings are generally cylindrical, and in the case of gas flow the openings are generally spaced-apart slotted holes. In the cases of both liquid and gas fluids, one of the grooves and/or nozzles are directed upstream relative to the path of article flow. Various adjustments are provided for adjusting the positions of the nozzle plates relative to the path of flow.

    摘要翻译: 提供了一种流体输送装置和方法,其中液体或气体流体由流体分配器歧管通过与其相关联的喷嘴板在由流体处理的制品的行进路径的每一侧上提供,并且其中喷嘴中的喷嘴开口 板与横向槽配合以提供横向于物品行进路径延伸且朝向物品的流体的筛网流。 在流体为液体的情况下,喷嘴开口提供圆柱形的丝状液体柱,其通过相关联的凹槽形成通常平坦的横向设置的液体的精液喷射。 在流体是气体的情况下,喷嘴开口和横向槽协作以将气体输送到朝向物品行进路径的横向间隔开的横向平坦区域中。 在液体流动的情况下,开口通常是圆柱形的,并且在气流的情况下,开口通常是间隔开的开槽孔。 在液体和气体流体的情况下,凹槽和/或喷嘴之一相对于制品流动的路径被引向上游。 提供了各种调整以调节喷嘴板相对于流动路径的位置。

    Apparatus for treatment of printed circuit boards and the like
    8.
    发明授权
    Apparatus for treatment of printed circuit boards and the like 失效
    印刷电路板等的处理装置

    公开(公告)号:US5553633A

    公开(公告)日:1996-09-10

    申请号:US551067

    申请日:1995-10-31

    摘要: Apparatus for treating printed circuit boards or other items is provided, wherein a drying apparatus is specifically provided, generally for use as part of a cleaning or other treatment apparatus, but which can be separately provided, if desired. The drying apparatus employs preferably warm air discharge tubes, for drying items of varying thicknesses, and/or that have varying thicknesses of components mounted thereon. Generally, the printed circuit or other items are carried through the apparatus between upper and lower foraminous conveyor belts, with one of the belts, conforming to the varying thicknesses of the items, or components carried by the items. While some of the air discharge tubes may be stationarily mounted, at least some of them are pivotally mounted, such that their discharge opening zones can slide along and conform to variations in thickness. The discharge tube will pivot in response to the varying thicknesses. The pivotal motion of the tube may be provided with a means for balancing the same.

    摘要翻译: 提供了一种用于处理印刷电路板或其它物品的设备,其特征在于,干燥设备通常用作清洁或其他处理设备的一部分,但如果需要,可以单独提供。 干燥装置优选采用温暖的空气放电管,用于干燥不同厚度的物品,和/或具有安装在其上的部件的厚度不同的干燥装置。 通常,印刷电路或其它物品通过上下多孔输送带之间的装置进行运送,其中一条带符合物品的变化厚度或物品承载的部件。 虽然一些排气管可以固定地安装,但是其中至少一些可枢转地安装,使得其排放开口区域可以沿着厚度滑动并且符合厚度变化。 放电管将响应于变化的厚度而枢转。 管的枢转运动可以设置有用于平衡其的装置。

    Treatment method for cleaning and drying printed circuit boards and the
like
    9.
    发明授权
    Treatment method for cleaning and drying printed circuit boards and the like 失效
    印刷电路板等的清洁干燥处理方法

    公开(公告)号:US5494529A

    公开(公告)日:1996-02-27

    申请号:US199563

    申请日:1994-02-22

    摘要: A method of treating printed circuit boards or other items is provided, wherein a drying apparatus is specifically provided, generally for use as part of a cleaning or other treatment apparatus, but which can be separately provided, if desired. The drying apparatus employs preferably warm air discharge tubes, for drying items of varying thicknesses, and/or that have varying thicknesses of components mounted thereon. Generally, the printed circuit or other items are carried through the apparatus between upper and lower foraminous conveyor belts, with one of the belts, conforming to the varying thicknesses of the items, or components carried by the items. While some of the air discharge tubes may be stationarily mounted, at least some of them are pivotally mounted, such that their discharge opening zones can slide along and conform to variations in thickness. The discharge tube will pivot in response to the varying thicknesses. The pivotal motion of the tube may be provided with a means for balancing the same.

    摘要翻译: 提供了一种处理印刷电路板或其它物品的方法,其特征在于,干燥装置通常用作清洁或其他处理装置的一部分,但如果需要,可以单独提供。 干燥装置优选采用温暖的空气放电管,用于干燥不同厚度的物品,和/或具有安装在其上的部件的厚度不同的干燥装置。 通常,印刷电路或其它物品通过上下多孔输送带之间的装置进行运送,其中一条带符合物品的变化厚度或物品承载的部件。 虽然一些排气管可以固定地安装,但是其中至少一些可枢转地安装,使得其排放开口区域可以沿着厚度滑动并且符合厚度变化。 放电管将响应于变化的厚度而枢转。 管的枢转运动可以设置有用于平衡其的装置。

    Deposition of chromium oxides from a trivalent chromium solution
containing a complexing agent for a buffer
    10.
    发明授权
    Deposition of chromium oxides from a trivalent chromium solution containing a complexing agent for a buffer 失效
    从含有缓冲剂络合剂的三价铬溶液中沉积铬氧化物

    公开(公告)号:US6004448A

    公开(公告)日:1999-12-21

    申请号:US487437

    申请日:1995-06-07

    IPC分类号: C25D11/38 C25D5/12

    CPC分类号: C25D9/08 C25D9/10 C25D9/12

    摘要: A water-soluble composition of matter free of an added buffering agent, for electrolytically depositing a chromium oxide coating on a metal substrate is disclosed comprising a mixture of a complexing agent for a buffering agent such as a boron oxide complexing agent that might be introduced into the composition, a trivalent chromium compound, a weak chelating agent, an optional conductivity enhancing cation, an optional depolarizer, and an optional surfactant. A process is also described as well as a product obtained by the process.

    摘要翻译: 公开了一种不含添加的缓冲剂的水溶性组合物,用于在金属基底上电解沉积氧化铬涂层,其包括用于缓冲剂的络合剂如氧化硼络合剂的混合物,所述缓冲剂可以被引入到 组合物,三价铬化合物,弱螯合剂,任选的导电性增强阳离子,任选的去极化剂和任选的表面活性剂。 还描述了一种方法以及通过该方法获得的产物。