Cellulose esters or ethers blended with cyclic ester polymers
    80.
    发明授权
    Cellulose esters or ethers blended with cyclic ester polymers 失效
    与环酯聚合物混合的纤维素酯或醚

    公开(公告)号:US3922239A

    公开(公告)日:1975-11-25

    申请号:US40552873

    申请日:1973-10-11

    摘要: Uniform, thermoplastic, normally solid blends containing cyclic ester polymers containing recurring units of the formula

    WHEREIN EACH R, individually, is selected from the class consisting of hydrogen, alkyl, halo, and alkoxy; A is the oxy group; x is an integer from 1 to 4; y is an integer from 1 to 4; z is an integer of zero or one; with the provisos that (a) the sum of x + y + z is at least 4 and not greater than 7, and (b) the total number of R variables which are substituents other than hydrogen does not exceed 3, with or without recurring units of the formula

    wherein each R'' is selected from the class consisting of, individually, hydrogen, alkyl, cyclcoalkyl, aryl, and chloroalkyl, and, together with the ethylene moiety of the oxyethylene chain of Unit II, a saturated cycloaliphatic hydrocarbon ring having from 4 to 8 carbon atoms; and thermoplastic normally solid polymer which can be a condensation polymer, and/or an addition polymer of olefinically unsaturated monomers having no more than one hydrogen bonded to each carbon of each olefinically unsaturated group thereof, including such polymers as cellulose derivatives, nylons, polyester polymers, polyoxyalkylenes, polycarbonates, poly(fluorocarbons), coumaroneindene resins, maleic acid or anhydride addition polymers and copolymers, stilbene addition polymers and copolymers, chlorinated polyethers, aromatic poly(hydroxy ether) polymers, polysufones, polypeptides, etc. These novel blends are useful in the production of fibers, films, coatings, adhesives, wire and cable coatings, molding materials, extrusion materials, or shaped articles, having one or more unique properties, such as, dyeability, improved stress crack resistance, improved optical properties, e.g., improved hiding power, low haze, high gloss and/or high light transmission, improved plasticization, improved toughness, improved melt processability, improved impact resistance, and/or improved ability to disperse additives, such as, fillers coloring agents, antioxidants, extenders, etc.

    摘要翻译: 含有含有式(I)的重复单元的环状酯聚合物的均匀,热塑性,通常为固体的共混物RRO || PARALLEL -O-C - (A)z-C-C-- || RR xy WHEREIN EACH R独立地选自氢,烷基,卤素和烷氧基; A是氧基; x是1至4的整数; y是1至4的整数; z是零或一的整数; 条件是(a)x + y + z的总和至少为4且不大于7,(b)除氢以外的取代基的R变量的总数不超过3,有或没有重复 其中每个R'分别选自氢,烷基,环烷基,芳基和氯代烷基,并且与 单元II的氧化乙烯链的乙烯部分,具有4至8个碳原子的饱和脂环族烃环; 和可以是缩聚物的热塑性常规固体聚合物,和/或具有不超过一个氢键的烯属不饱和单体的加成聚合物,其包含诸如纤维素衍生物,尼龙,聚酯聚合物的各种烯属不饱和基团的各碳 ,聚氧化烯,聚碳酸酯,聚(碳氟化合物),香豆酮 - 茚树脂,马来酸或酸酐加成聚合物和共聚物,二苯乙烯加成聚合物和共聚物,氯化聚醚,芳族聚(羟基醚)聚合物,聚砜,多肽等