Storage stable foam-forming system
    61.
    发明授权
    Storage stable foam-forming system 有权
    储存稳定的泡沫成型系统

    公开(公告)号:US06262136B1

    公开(公告)日:2001-07-17

    申请号:US09320016

    申请日:1999-05-26

    IPC分类号: C08J914

    摘要: An isocyanate-reactive composition containing a blowing agent that is generally a gas at ambient temperature and pressure which is storage stable is produced by including a phenol or alkylphenol having at least one phenolic hydroxyl group in the isocyanate-reactive composition in an amount sufficient to promote the solubility of the blowing agent. The isocyanate-reactive composition may be stored at ambient conditions rather than under pressure. The isocyanate-reactive composition containing blowing agent may be used to produce foams having good physical properties after storage at ambient temperature and pressure for periods as long as 3 months.

    摘要翻译: 通过在异氰酸酯反应性组合物中包含具有至少一个酚羟基的苯酚或烷基酚以足以促进的量来制备含有通常为环境温度和压力下的气体的发泡剂的异氰酸酯反应性组合物 发泡剂的溶解度。 异氰酸酯反应性组合物可以在环境条件下而不是在压力下储存。 含有发泡剂的异氰酸酯反应性组合物可用于在环境温度和压力下储存长达3个月的时间后生产具有良好物理性能的泡沫。

    Decomposition inhibitor for hydrogen- and fluorine-containing
halogenated hydrocarbons and method of inhibiting decomposition using
same
    66.
    发明授权
    Decomposition inhibitor for hydrogen- and fluorine-containing halogenated hydrocarbons and method of inhibiting decomposition using same 失效
    含氢和含氟卤代烃的分解抑制剂及其使用方法抑制分解

    公开(公告)号:US5696306A

    公开(公告)日:1997-12-09

    申请号:US433347

    申请日:1995-06-22

    IPC分类号: C07C17/42 C08J9/14 C07C19/08

    摘要: A decomposition inhibitor for hydrochlorofluorocarbons and hydrofluorocarbons (HCFCs/HFCs) which comprises at least one member of the class consisting of organic acid-amine mixtures, fluorine-free halogenated hydrocarbons, carboxylic acid esters, nitrile compounds, carbonyl compounds and halogenated nitro compounds. A method of inhibiting the decomposition of HCFCs/HFCs which comprises using the decomposition inhibitor mentioned above. In the field of polyurethane foam manufacture using HCFCs/HFCs as blowing agents, the effect of inhibiting the decomposition of HCFCs/HFCs can be produced over a long period of time covering the storage of raw materials, the foam manufacturing process and the use of foamed products.

    摘要翻译: PCT No.PCT / JP93 / 01639 Sec。 371日期:1995年6月22日 102(e)1995年6月22日PCT 1993年11月10日PCT公布。 公开号WO94 / 11329 日期1994年5月26日氢氯氟烃和氢氟烃(HCFCs / HFCs)的分解抑制剂,其包含由有机酸 - 胺混合物,无氟卤代烃,羧酸酯,腈化合物,羰基化合物和卤代的至少一种成员 硝基化合物。 包括使用上述分解抑制剂的抑制HCFCs / HFCs分解的方法。 在使用氟氯烃/氢氟碳化合物作为发泡剂的聚氨酯泡沫塑料制造领域,可以长时间生产抑制氟氯烃/氢氟碳化合物分解的效果,包括原料的储存,泡沫制造过程和泡沫的使用 产品。

    Polyisocyanate-based foam and blowing agent therefor
    67.
    发明授权
    Polyisocyanate-based foam and blowing agent therefor 失效
    聚异氰酸酯基泡沫塑料及其发泡剂

    公开(公告)号:US5684056A

    公开(公告)日:1997-11-04

    申请号:US699984

    申请日:1996-08-20

    申请人: Richard Stevenson

    发明人: Richard Stevenson

    IPC分类号: C08G18/48 C08G101/00 C08J9/14

    CPC分类号: C08J9/144 C08J2375/04

    摘要: A blowing agent for use in preparing a polyisocyanate-based foam which comprises a major portion of HCFC-123, a minor portion of HCFC-141b, a branched or unbranched aliphatic alkane having from 6 to 10 carbon atoms or mixtures thereof, and a polyether component which reduces cell size in the resultant polyisocyanate-based foam. The polyether component includes a mixture of polymerized, oxidized perfluorinated propene polyethers having a molecular weight distribution of from about 400 to about 1800 units. Alternatively, the polyether component can be added to the foam precursor materials separate from the blowing agent. Blowing agents and polyether additives for polyurethane-based foams are also provided.

    摘要翻译: 一种用于制备多异氰酸酯基泡沫体的发泡剂,其包含主要部分的HCFC-123,少部分HCFC-141b,具有6至10个碳原子的支链或非支链脂族烷烃或其混合物,以及聚醚 在所得多异氰酸酯基泡沫体中降低泡孔尺寸的组分。 聚醚组分包括聚合的,氧化的全氟化丙烯聚醚的混合物,其分子量分布为约400至约1800单位。 或者,可以将聚醚组分加入到与发泡剂分开的泡沫前体材料中。 还提供了用于聚氨酯泡沫的发泡剂和聚醚添加剂。

    Insulating rigid polyurethane foam compositions
    70.
    发明授权
    Insulating rigid polyurethane foam compositions 失效
    绝缘硬质聚氨酯泡沫组合物

    公开(公告)号:US5547998A

    公开(公告)日:1996-08-20

    申请号:US551507

    申请日:1995-11-01

    摘要: There is now provided storage stable polyol compositions and polyisocyanate based rigid dosed cell foam made by reacting an organic isocyanate with polyol compositions in the presence of a blowing agent, where the polyol composition contains at least:a) an aromatic amine initiated polyoxyalkylene polyether polyol having an hydroxyl number of 200 meq polyol/g KOH or more;b) an aliphatic amine initiated polyoxyalkylene polyether polyol having an hydroxyl number of 200 meq polyol/g KOH or more;and the blowing agent is at least cyclopentane in an amount of 7 weight percent or more based on the weight of the polyol composition; and further, the cyclopentane blowing agent is soluble in the polyol composition, and the amount of the aliphatic amine initiated polyoxyalkylene polyether polyol is 10 weight percent or less based on the weight of the polyol composition.The polyol composition is adapted to solubilize cyclopentane in the polyol composition without sacrificing, and advantageously improving, the thermal insulation and dimensional stability of the resulting polyurethane foam. It was surprising to discover that less than 10 weight percent of the aliphatic amine initiated polyol was need to accomplish these objectives, and it was further surprising to discover that the aromatic amine initiated polyether polyol improved the thermal insulation of the foam.

    摘要翻译: 现在提供储存稳定的多元醇组合物和通过有机异氰酸酯与多元醇组合物在发泡剂存在下反应制备的多异氰酸酯基刚性定量泡沫泡沫,其中多元醇组合物至少包含:a)芳族胺引发的聚氧化烯聚醚多元醇,其具有 羟值为200meq多元醇/ g KOH以上; b)具有羟值为200meq多元醇/ g KOH或更高的脂族胺引发的聚氧化烯聚醚多元醇; 发泡剂至少为多元醇组合物重量的7重量%以上的环戊烷; 此外,环戊烷发泡剂可溶于多元醇组合物,并且脂肪族胺引发的聚氧化烯聚醚多元醇的量相对于多元醇组合物的重量为10重量%以下。 多元醇组合物适于在多元醇组合物中溶解环戊烷,而不会牺牲所得聚氨酯泡沫体的绝热性和尺寸稳定性,有利地改善。 令人惊奇地发现,少于10重量%的脂族胺引发的多元醇需要实现这些目的,并且令人惊奇的是发现芳族胺引发的聚醚多元醇改善了泡沫的隔热性。