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公开(公告)号：US5786401A
公开(公告)日：1998-07-28
申请号：US964743
申请日：1997-11-05
CPC分类号： C08J9/144 , C08G18/0885 , C08G18/482 , C08G2101/0025 , C08G2101/005 , C08J2203/14 , C08J2203/142 , C08J2203/162 , C08J2203/202 , C08J2375/04
摘要： A polyurethane foam is constituted by using a blowing agent selected from the group consisting of iodofluorohydrocarbons, perfluoroalkenes and hydrogen-containing fluoromorpholine derivatives. These blowing agents have a low thermal conductivity and a short life in the air, and thus impose no or very small load such as ozone layer depletion potential (ODP) and global warming potential (GWP) on the environment. The iodofluorohydrocarbon, in particular, can give an incombustibility and self-extinguishing property to the conventionally used inflammable substance such as cyclopentane or the like, and thus is also advantageous from the viewpoint of safety of the thermal insulating material.
摘要翻译： 通过使用选自由氟碘烃，全氟烯烃和含氢氟代吗啉衍生物组成的组的发泡剂构成聚氨酯泡沫体。 这些发泡剂具有低的导热性和在空气中的短寿命，因此在环境中施加无臭氧层消耗潜能（ODP）和全球变暖潜能值（GWP）等负载或非常小的负荷。 特别是碘氟化烃可以赋予常规使用的可燃性物质如环戊烷等的不燃性和自熄性，因此从绝热材料的安全性的观点来看也是有利的。
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公开(公告)号：US5721285A
公开(公告)日：1998-02-24
申请号：US592068
申请日：1996-01-26
申请人： Hideo Nakamoto , Tomohisa Tenra , Tsukasa Takushima , Takayoshi Ueno , Masaaki Suzuki , Fumihiro Inagaki , Takashi Hashida , Yoshio Kishimoto
发明人： Hideo Nakamoto , Tomohisa Tenra , Tsukasa Takushima , Takayoshi Ueno , Masaaki Suzuki , Fumihiro Inagaki , Takashi Hashida , Yoshio Kishimoto
CPC分类号： C08J9/0066 , C08J9/14 , C08J2375/04
摘要： The present invention provides a thermal insulating foamed material with excellent thermal insulating properties and a method of manufacturing the same. The method comprises the steps of: concurrently mixing and blowing a polyurethane material to produce a foamed polyurethane resin composition with a multiplicity of closed cells, the polyurethane material including a reactive blowing agent, a volatile compound having a boiling point of not higher than 150.degree. C. and a molecular weight of not less than 70, an epoxy compound, and a carbon dioxide fixation catalyst, wherein the closed cells are filled with the volatile compound and carbon dioxide produced by a reaction of the reactive blowing agent with a polyisocyanate; and allowing the carbon dioxide to chemically react with epoxy groups of the epoxy compound in the presence of the carbon dioxide fixation catalyst to form a solid or liquid cyclic carbonate. The method gives a foamed material with the closed cells substantially filled with vapor of the volatile compound at a partial pressure of at least 5 mmHg at 25.degree. C.
摘要翻译： 本发明提供一种隔热性优异的绝热发泡体及其制造方法。 该方法包括以下步骤：同时混合和吹塑聚氨酯材料以制备具有多个闭孔的发泡聚氨酯树脂组合物，所述聚氨酯材料包括反应性发泡剂，沸点不高于150℃的挥发性化合物 C，分子量不小于70，环氧化合物和二氧化碳固定催化剂，其中闭孔充满挥发性化合物和通过反应性发泡剂与多异氰酸酯的反应产生的二氧化碳; 并且在二氧化碳固定催化剂的存在下使二氧化碳与环氧化合物的环氧基发生化学反应以形成固体或液体环状碳酸酯。 该方法产生泡沫材料，其中闭孔在25℃下在至少5mmHg的分压下基本上充满挥发性化合物的蒸气。
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公开(公告)号：US20100277057A1
公开(公告)日：2010-11-04
申请号：US12835618
申请日：2010-07-13
申请人： Fumihiro Inagaki , Masaaki Hama
发明人： Fumihiro Inagaki , Masaaki Hama
IPC分类号： H01J63/04
摘要： The present invention provides a fluorescent lamp, comprising: a glass bulb; mercury that is enclosed within the glass bulb, an amount of the mercury being from 2.2 μg/cm3 to 8.8 μg/cm3; a rare gas that is enclosed within the glass bulb; an electrode that is attached to the glass bulb; a protective layer that is formed on an inside surface of the glass bulb, and includes metal oxide particles and at least 50 wt % of silica, a thickness of the protective layer being from 0.5 μm to 5.0 μm; and a phosphor layer that is formed over the protective layer.
摘要翻译： 本发明提供一种荧光灯，包括：玻璃灯泡; 封闭在玻璃灯泡内的汞，一定量的汞为2.2μg/ cm3至8.8μg/ cm3; 封闭在玻璃灯泡内的稀有气体; 连接到玻璃灯泡的电极; 保护层，其形成在玻璃泡的内表面上，并且包括金属氧化物颗粒和至少50重量％的二氧化硅，所述保护层的厚度为0.5μm至5.0μm; 以及形成在保护层上的荧光体层。
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公开(公告)号：US20050285537A1
公开(公告)日：2005-12-29
申请号：US11165396
申请日：2005-06-23
申请人： Fumihiro Inagaki , Masaaki Hama
发明人： Fumihiro Inagaki , Masaaki Hama
摘要： The present invention provides a fluorescent lamp, comprising: a glass bulb; mercury that is enclosed within the glass bulb, an amount of the mercury being from 2.2 μg/cm3 to 8.8 μg/cm3; a rare gas that is enclosed within the glass bulb; an electrode that is attached to the glass bulb; a protective layer that is formed on an inside surface of the glass bulb, and includes metal oxide particles and at least 50 wt % of silica, a thickness of the protective layer being from 0.5 μm to 5.0 μm; and a phosphor layer that is formed over the protective layer.
摘要翻译： 本发明提供一种荧光灯，包括：玻璃灯泡; 封闭在玻璃灯泡内的汞，一定量的汞为2.2mug / cm 3至8.8mug / cm 3; 封闭在玻璃灯泡内的稀有气体; 连接到玻璃灯泡的电极; 形成在玻璃管的内表面上的保护层，包括金属氧化物粒子和至少50重量％的二氧化硅，保护层的厚度为0.5〜5.0μm; 以及形成在保护层上的荧光体层。
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公开(公告)号：US06281625B1
公开(公告)日：2001-08-28
申请号：US09294502
申请日：1999-04-20
IPC分类号： H01J3100
CPC分类号： C03C17/007 , C03C2217/212 , C03C2217/213 , C03C2217/214 , C03C2217/228 , C03C2217/42 , H01J61/35 , H01J61/72
摘要： A fluorescent lamp highly capable of inhibiting penetration of mercury or ultraviolet ray, in which blackening of a glass tube is prevented, and which displays excellent luminous flux maintenance. The lamp has a protective film mainly composed of substantially spherical metal oxide particles, which is formed between a glass tube and a fluorescent layer on the inner surface of the glass tube.
摘要翻译： 能够防止水银或紫外线渗透的荧光灯，其中防止玻璃管变黑，并且显示出优良的光通量维持。 灯具有主要由基本上球形的金属氧化物颗粒组成的保护膜，其形成在玻璃管的内表面上的玻璃管和荧光层之间。
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6.发明授权
公开(公告)号：US5773482A
公开(公告)日：1998-06-30
申请号：US809959
申请日：1997-05-22
申请人： Takayoshi Ueno , Takashi Hashida , Masaaki Suzuki , Fumihiro Inagaki , Nobuo Sonoda , Hideo Nakamoto , Tomohisa Tenra , Tsukasa Takushima , Yoshio Kishimoto
发明人： Takayoshi Ueno , Takashi Hashida , Masaaki Suzuki , Fumihiro Inagaki , Nobuo Sonoda , Hideo Nakamoto , Tomohisa Tenra , Tsukasa Takushima , Yoshio Kishimoto
CPC分类号： C08J9/0061 , C08G18/003 , C08G18/088 , C08G18/58 , C08G2101/00 , C08G2101/0025 , C08J2205/052 , C08J2375/04 , C08J2463/00
摘要： There are disclosed a thermal insulating foamed material, which is superior in thermal insulating property and does not cause deterioration of the thermal insulating property with a time lapse, and a method for producing the same. According to a method for producing a thermal insulating foamed material, a foamed polyurethane resin composition having closed cells, in which at least carbon dioxide is filled, is formed by blowing a raw material mixture containing epoxides comprising at least two members of an epoxide compound having high reactivity with carbon dioxide and an epoxide compound having low reactivity with carbon dioxide, a carbon dioxide fixation catalyst, polyisocyanate, a reactive blowing agent which evolves carbon dioxide by reacting with said polyisocyanate, and a polyol composition. Then, the carbon dioxide in the closed cells is allowed to react with the epoxides in the presence of the carbon dioxide fixation catalyst, thereby to fix carbon dioxide as carbonate compounds.
摘要翻译： PCT No.PCT / JP96 / 02386 Sec。 371日期：1997年5月22日 102（e）日期1997年5月22日PCT提交1996年8月26日PCT公布。 出版物WO97 / 09361 日期1997年3月13日公开了绝热发泡材料，其隔热性优异，并且不会随时间推移导致绝热性的劣化及其制造方法。 根据绝热发泡材料的制造方法，通过吹入含有环氧化物的原料混合物形成至少填充了二氧化碳的封闭气泡的发泡聚氨酯树脂组合物，所述环氧化物包含至少两种具有 与二氧化碳的高反应性和与二氧化碳反应性低的环氧化合物，二氧化碳固定催化剂，多异氰酸酯，通过与所述多异氰酸酯反应释放二氧化碳的反应性发泡剂和多元醇组合物。 然后，在二氧化碳固定催化剂的存在下，闭孔中的二氧化碳与环氧化物反应，从而将二氧化碳固定为碳酸盐化合物。
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公开(公告)号：US5693685A
公开(公告)日：1997-12-02
申请号：US638308
申请日：1996-04-26
CPC分类号： C08J9/0066 , C08G18/0814 , C08G18/0885 , C08G2101/0025 , C08G2101/0083 , C08J2375/04 , F25D2201/14
摘要： A thermal insulator of the present invention includes a foam containing solidified CO.sub.2 gas. A method for producing the thermal insulator includes the steps of: mixing a metal compound selected from the group consisting of a metal oxide and a metal hydroxide, water, a polyol component, and an isocyanate component to generate a mixture; foaming the mixture in a container to generate closed-cells made of a water-foamed polyurethane; and allowing CO.sub.2 gas generated during the foaming step to react with the selected metal compound to solidify the CO.sub.2 gas, thereby depressurizing the closed-cells in the closed-celled foam.
摘要翻译： 本发明的绝热体包括含有固体CO 2气体的泡沫体。 制造绝热体的方法包括以下步骤：将选自金属氧化物和金属氢氧化物的金属化合物，水，多元醇组分和异氰酸酯组分混合以产生混合物; 将混合物在容器中发泡以产生由水发泡聚氨酯制成的闭孔; 并且允许在发泡步骤期间产生的CO 2气体与所选择的金属化合物反应以固化CO 2气体，从而使闭孔泡沫体中的闭孔减压。
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8.发明授权Fluorescent lamp with glass tube and protective layer, method for producing the same, and lighting system 有权具有玻璃管和保护层的荧光灯，其制造方法和照明系统公开(公告)号：US07986082B2
公开(公告)日：2011-07-26
申请号：US11914635
申请日：2006-05-29
申请人： Yoshio Manabe , Fumihiro Inagaki , Shogo Toda , Masaaki Hama
发明人： Yoshio Manabe , Fumihiro Inagaki , Shogo Toda , Masaaki Hama
IPC分类号： H01J1/62
摘要： A fluorescent lamp according to the present invention includes: a glass tube 1 in which mercury and a rare gas are enclosed; a protective film 3 that is attached so as to cover an inner face of the glass tube 1; and a phosphor layer 4 that is laminated on the protective film 3. The protective film 3 has a thickness of 0.5 μm to 3 μm. Further, the protective film 3 is formed of inorganic particles and has a volume ratio of 0.1 to 0.5. Preferably, the inorganic particles are of at least one selected from the group consisting of aluminum oxide, silicon dioxide, magnesium oxide, zinc oxide, titanium oxide, cerium oxide, yttrium oxide, and calcium halophosphate.
摘要翻译： 根据本发明的荧光灯包括：包围汞和稀有气体的玻璃管1; 安装以覆盖玻璃管1的内表面的保护膜3; 以及层叠在保护膜3上的荧光体层4.保护膜3的厚度为0.5μm〜3μm。 此外，保护膜3由无机粒子形成，体积比为0.1〜0.5。 优选地，无机颗粒是选自氧化铝，二氧化硅，氧化镁，氧化锌，氧化钛，氧化铈，氧化钇和卤代磷酸钙中的至少一种。
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公开(公告)号：US20090079325A1
公开(公告)日：2009-03-26
申请号：US11914635
申请日：2006-05-29
申请人： Yoshio Manabe , Fumihiro Inagaki , Shogo Toda , Masaaki Hama
发明人： Yoshio Manabe , Fumihiro Inagaki , Shogo Toda , Masaaki Hama
摘要： A fluorescent lamp according to the present invention includes: a glass tube 1 in which mercury and a rare gas are enclosed; a protective film 3 that is attached so as to cover an inner face of the glass tube 1; and a phosphor layer 4 that is laminated on the protective film 3. The protective film 3 has a thickness of 0.5 μm to 3 μm. Further, the protective film 3 is formed of inorganic particles and has a volume ratio of 0.1 to 0.5. Preferably, the inorganic particles are of at least one selected from the group consisting of aluminum oxide, silicon dioxide, magnesium oxide, zinc oxide, titanium oxide, cerium oxide, yttrium oxide, and calcium halophosphate.
摘要翻译： 根据本发明的荧光灯包括：包围汞和稀有气体的玻璃管1; 安装以覆盖玻璃管1的内表面的保护膜3; 以及层叠在保护膜3上的荧光体层4.保护膜3的厚度为0.5μm〜3μm。 此外，保护膜3由无机粒子形成，体积比为0.1〜0.5。 优选地，无机颗粒是选自氧化铝，二氧化硅，氧化镁，氧化锌，氧化钛，氧化铈，氧化钇和卤代磷酸钙中的至少一种。
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公开(公告)号：US5741825A
公开(公告)日：1998-04-21
申请号：US524194
申请日：1995-09-06
CPC分类号： C08J9/144 , C08G18/0885 , C08G18/482 , C08G2101/0025 , C08G2101/005 , C08J2203/14 , C08J2203/142 , C08J2203/162 , C08J2203/202 , C08J2375/04
摘要： A polyurethane foam is constituted by using a blowing agent selected from the group consisting of iodofluorohydrocarbons, perfluoroalkenes and hydrogen-containing fluoromorpholine derivatives. These blowing agents have a low thermal conductivity and a short life in the air, and thus impose no or very small load such as ozone layer depletion potential (ODP) and global warming potential (GWP) on the environment. The iodofluorohydrocarbon, in particular, can give an incombustibility and self-extinguishing property to the conventionally used inflammable substance such as cyclopentane or the like, and thus is also advantageous from the viewpoint of safety of the thermal insulating material.
摘要翻译： 通过使用选自由氟碘烃，全氟烯烃和含氢氟代吗啉衍生物组成的组的发泡剂构成聚氨酯泡沫体。 这些发泡剂具有低的导热性和在空气中的短寿命，因此在环境中施加无臭氧层消耗潜能（ODP）和全球变暖潜能值（GWP）等负载或非常小的负荷。 特别是碘氟化烃可以赋予常规使用的可燃性物质如环戊烷等的不燃性和自熄性，因此从绝热材料的安全性的观点来看也是有利的。
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