GRAFT COPOLYMERS OF A POLY(VINYLIDENE FLUORIDE)-BASED POLYMER AND AT LEAST ONE TYPE OF ELECTRICALLY CONDUCTIVE POLYMER, AND METHODS FOR FORMING THE GRAFT COPOLYMERS
    52.
    发明申请
    GRAFT COPOLYMERS OF A POLY(VINYLIDENE FLUORIDE)-BASED POLYMER AND AT LEAST ONE TYPE OF ELECTRICALLY CONDUCTIVE POLYMER, AND METHODS FOR FORMING THE GRAFT COPOLYMERS 有权
    聚(氟乙烯)共聚物和至少一种导电聚合物类型的共聚物和形成共聚物的方法

    公开(公告)号:US20140367036A1

    公开(公告)日:2014-12-18

    申请号:US14364015

    申请日:2012-12-07

    摘要: Methods for forming a graft copolymer of a poly(vinylidene fluoride)-based polymer and at least one type of electrically conductive polymer, wherein the electrically conductive polymer is grafted on the poly(vinylidene fluoride)-based polymer are provided. The methods comprise a) irradiating a poly(vinylidene fluoride)-based polymer with a stream of electrically charged particles; b) forming a solution comprising the irradiated poly(vinylidene fluoride)-based polymer, an electrically conductive monomer and an acid in a suitable solvent; and c) adding an oxidant to the solution to form the graft copolymer. Graft copolymers of a poly(vinylidene fluoride)-based polymer and at least one type of electrically conductive polymer, wherein the electrically conductive polymer is grafted on the poly(vinylidene fluoride)-based polymer, nanocomposite materials comprising the graft copolymer, and multilayer capacitors comprising the nanocomposite material are also provided.

    摘要翻译: 提供了聚偏二氟乙烯基聚合物与至少一种导电聚合物的接枝共聚物的形成方法,其中导电聚合物接枝在聚(偏二氟乙烯)基聚合物上。 所述方法包括:a)用带电粒子的流照射聚(偏二氟乙烯)基聚合物; b)在合适的溶剂中形成包含被照射的聚偏二氟乙烯基聚合物,导电单体和酸的溶液; 和c)向溶液中加入氧化剂以形成接枝共聚物。 聚偏二氟乙烯基聚合物与至少一种类型的导电聚合物的接枝共聚物,其中导电聚合物接枝在聚(偏二氟乙烯)基聚合物上,包含接枝共聚物的纳米复合材料和多层电容器 也提供了纳米复合材料。

    Release on demand corrosion inhibitor composition
    53.
    发明授权
    Release on demand corrosion inhibitor composition 有权
    释放按需腐蚀抑制剂组成

    公开(公告)号:US08883916B2

    公开(公告)日:2014-11-11

    申请号:US12993527

    申请日:2009-05-19

    IPC分类号: C09D133/14 C08F8/30 C23F11/00

    摘要: Disclosed is cross-linking process for cross-linking polymeric chains in a coating composition. In one embodiment the process utilizes a Hantzsch dihydropyridine reaction to form reaction products including cross-linking polymeric resin chains having beta-keto ester functions using a source of aldehyde and a source of ammonia or a primary amine to form a permanent dihydropyridine bond between the beta-keto ester functions. The novel cross-linking reaction can occur at lower temperatures compared to typical cross-linking reactions and can occur in aqueous solutions that have a neutral to mildly alkaline pH of from 6 to 11. The novel cross-linking reaction provides many advantages to performing cross-linking of polymeric chains in coating resins.

    摘要翻译: 公开了用于在涂料组合物中交联聚合物链的交联方法。 在一个实施方案中,该方法利用汉氏二氢吡啶反应形成反应产物,包括具有β-酮酸酯官能团的交联聚合物树脂链,其使用醛源和氨源或伯胺以形成β-酮酸酯官能团之间的永久二氢吡啶键 酮酯功能。 与典型的交联反应相比,新的交联反应可以在较低的温度下进行,并且可以发生在中性至弱碱性pH为6至11的水溶液中。新的交联反应提供了许多优点, 聚合物链在涂料树脂中的连接。

    SURFACE MODIFYING AGENTS, MODIFIED MATERIALS AND METHODS
    55.
    发明申请
    SURFACE MODIFYING AGENTS, MODIFIED MATERIALS AND METHODS 审中-公开
    表面改性剂,改性材料和方法

    公开(公告)号:US20140206251A1

    公开(公告)日:2014-07-24

    申请号:US14157561

    申请日:2014-01-17

    申请人: Celgard, LLC

    IPC分类号: C09D141/00 C08F299/00

    摘要: The present invention relates to surface modifying agents for polymeric and/or textile materials, methods of making and/or using a surface modifying agent to modify and functionalize polymeric and/or textile materials, and/or methods of using surface modified or functionalized polymeric and textile materials, and/or products using or incorporating surface modified or functionalized polymeric and textile materials. For example, the surface modifying agent in precursor form can be styrene sulfonyl azide monomer, polymer or copolymer capable of undergoing a chemical reaction in the presence of heat or light to form one or more styrene sulfonated nitrene monomers, polymers or copolymers, which are capable of chemically reacting with the surface of a polymeric or textile material to endow a specific or desired chemical surface functionality to the surface of a polymeric or textile material. Furthermore, the present invention is possibly preferably directed to a surface modifying agent which comprises a styrene sulfonated nitrene monomer, polymer or polymer containing one or more nitrene functional groups, which are capable of chemically reacting via an insertion reaction into one or more carbon-hydrogen bonds on the surface of a polymeric or textile material in order to chemically attach a specific or desired chemical functionality to the surface of a polymeric or textile material.

    摘要翻译: 本发明涉及用于聚合物和/或纺织材料的表面改性剂,制备和/或使用表面改性剂来改性和官能化聚合物和/或纺织材料的方法,和/或使用表面改性或官能化聚合物和/ 纺织材料和/或使用或引入表面改性或官能化聚合物和纺织材料的产品。 例如,前体形式的表面改性剂可以是苯乙烯磺酰基叠氮单体,能够在热或光的存在下经历化学反应的聚合物或共聚物,以形成一种或多种苯乙烯磺化的硝酸单体,聚合物或共聚物,其能够 与聚合物或纺织材料的表面化学反应以赋予聚合物或纺织材料表面特定或期望的化学表面官能度。 此外,本发明可能优选地涉及一种表面改性剂,其包括苯乙烯磺化的三聚氰胺单体,含有一个或多个硝基官能团的聚合物或聚合物,其能够通过插入反应与一个或多个碳氢化合物进行化学反应 在聚合物或纺织材料的表面上键合以便将特定的或期望的化学官能化学附着到聚合物或纺织材料的表面上。

    Anion Exchange Block Copolymers, Their Manufacture And Their Use
    56.
    发明申请
    Anion Exchange Block Copolymers, Their Manufacture And Their Use 有权
    阴离子交换嵌段共聚物及其制备及其应用

    公开(公告)号:US20140197032A1

    公开(公告)日:2014-07-17

    申请号:US14154146

    申请日:2014-01-13

    IPC分类号: B01D71/82 B01D61/44

    摘要: Selectively amino- or phosphino-functionalized block copolymers, and their preparation, for use as anion exchange membrane materials. The selectively functionalized block copolymers have at least two end blocks A each of which are substantially free of amino- or phosphino-functional groups, and have at least one interior block D which comprises on average at least one amino- or phosphino-functionalized polymer unit of formula (I) wherein Z is nitrogen or phosphorous; R1 is hydrogen or alkyl; R2 is hydrogen or is tertiary alkyl; R each independently, is hydrogen or is alkyl optionally substituted by a moiety -(A1-NRa)xRb; or two R groups, together with the Z to which they are bonded, form an optionally substituted ring; x is 1, 2 or 3; A1 is straight chain alkylene optionally substituted by one or more methyl and/or ethyl groups; and Ra and Rb, each independently, is hydrogen or alkyl; or a corresponding onium salt.

    摘要翻译: 选择性氨基或膦官能化嵌段共聚物及其制备,用作阴离子交换膜材料。 选择性官能化的嵌段共聚物具有至少两个端基A,其各自基本上不含氨基或膦官能团,并且具有至少一个内部嵌段D,其至少包含至少一个氨基或膦官能化聚合物单元 式(I)其中Z是氮或磷; R1是氢或烷基; R2是氢或是叔烷基; R各自独立地为氢或任选被部分 - (Al-NR a)x R b取代的烷基; 或两个R基团与它们所键合的Z一起形成任选取代的环; x为1,2或3; A1是任选被一个或多个甲基和/或乙基取代的直链亚烷基; 和R a和R b各自独立地是氢或烷基; 或相应的鎓盐。