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公开(公告)号：US08241524B2
公开(公告)日：2012-08-14
申请号：US12467537
申请日：2009-05-18
IPC分类号： C23F11/00
CPC分类号： C09D5/084 , C09D139/04 , C08L2666/02 , C08L2666/04
摘要： Disclosed is a release on demand type corrosion inhibitor composition for a metal substrate formed from only non-electrically conductive film forming copolymer(s); a nitrogen containing functional group X, where the group X comprises a pyridine, a dihydropyridine, a pyrrole, an imidazole, or a mixtures thereof; and a metallate anion. The metallate anion binds to a nitrogen in the functional group X by ion pairing. A localized rise in pH is believed to cause release of the anion via a protonation/deprotonation reaction and the released anion suppresses the corrosion formation. The coating composition includes no electrically conductive polymers.
摘要翻译： 公开了一种用于仅由非导电成膜共聚物形成的金属基材的按需型缓蚀剂组合物; 含氮官能团X，其中基团X包括吡啶，二氢吡啶，吡咯，咪唑或其混合物; 和金属盐阴离子。 金属离子阴离子通过离子配对结合官能团X中的氮。 认为pH的局部升高通过质子化/去质子化反应引起阴离子的释放，释放的阴离子抑制腐蚀形成。 涂料组合物不包括导电聚合物。
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公开(公告)号：US20100291307A1
公开(公告)日：2010-11-18
申请号：US12467537
申请日：2009-05-18
CPC分类号： C09D5/084 , C09D139/04 , C08L2666/02 , C08L2666/04
摘要： Disclosed is a release on demand type corrosion inhibitor composition for a metal substrate formed from only non-electrically conductive film forming copolymer(s); a nitrogen containing functional group X, where the group X comprises a pyridine, a dihydropyridine, a pyrrole, an imidazole, or a mixtures thereof; and a metallate anion. The metallate anion binds to a nitrogen in the functional group X by ion pairing. A localized rise in pH is believed to cause release of the anion via a protonation/deprotonation reaction and the released anion suppresses the corrosion formation. The coating composition includes no electrically conductive polymers.
摘要翻译： 公开了一种用于仅由非导电成膜共聚物形成的金属基材的按需型缓蚀剂组合物; 含氮官能团X，其中基团X包括吡啶，二氢吡啶，吡咯，咪唑或其混合物; 和金属盐阴离子。 金属离子阴离子通过离子配对结合官能团X中的氮。 认为pH的局部升高通过质子化/去质子化反应引起阴离子的释放，释放的阴离子抑制腐蚀形成。 涂料组合物不包括导电聚合物。
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3.发明申请MILDLY ALKALINE THIN INORGANIC CORROSION PROTECTIVE COATING FOR METAL SUBSTRATES 审中-公开用于金属基材的乳液碱性薄弱无害防腐涂料公开(公告)号：US20110117381A1
公开(公告)日：2011-05-19
申请号：US12993579
申请日：2009-05-19
CPC分类号： C23C22/60 , C23C22/66 , Y10T428/12493 , Y10T428/1266
摘要： Disclosed is a neutral to alkaline inorganic chrome-free conversion coating composition that can be applied directly to a metal surface without a phosphatizing pre-treatment and that provides significant corrosion protection to the surface. The conversion coating composition preferably has a pH of from about 6 to 11 and more preferably from 8 to 10. The coating composition includes at least one element from group IVB of the Periodic table and at least one element from group VB of the Periodic Table. Preferably, the coating composition includes from 1 to 7% by weight of the at least one element from group IVB and from 0.20% to 2.00% by weight of the at least one element from group VB. The conversion coating composition is a dry in place coating and being chrome free it does not have the environmental issues associated with chrome-based coatings. The coating composition is very versatile and can accommodate addition of a wide variety of organic coating resins which can be added directly to the coating composition thus eliminating multistep coating processes.
摘要翻译： 公开了一种中性至碱性无机无铬转化涂层组合物，其可以直接施加到金属表面而无需磷化预处理，并且对表面提供显着的腐蚀保护。 转化涂料组合物优选具有约6至11，更优选8至10的pH。涂料组合物包含至少一种元素周期表IVB族元素和元素周期表第VB族元素中的至少一种元素。 优选地，涂料组合物包含1至7重量％的来自IVB族的至少一种元素和0.20重量％至2.00重量％的来自VB的至少一种元素。 转化涂料组合物是干燥的涂层，并且是无铬的，其不具有与铬基涂层相关的环境问题。 涂料组合物是非常通用的，并且可以适应添加多种可以直接加入到涂料组合物中的有机涂料树脂，从而消除多步涂布方法。
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公开(公告)号：US08883916B2
公开(公告)日：2014-11-11
申请号：US12993527
申请日：2009-05-19
IPC分类号： C09D133/14 , C08F8/30 , C23F11/00
CPC分类号： C09D133/04 , C08F8/30 , C08F2800/20 , C08F2810/20 , C08K3/30 , C08K5/41 , C09D191/06 , Y10T428/273 , Y10T428/31688 , Y10T428/31699 , C08F8/00 , C08F220/14
摘要： Disclosed is cross-linking process for cross-linking polymeric chains in a coating composition. In one embodiment the process utilizes a Hantzsch dihydropyridine reaction to form reaction products including cross-linking polymeric resin chains having beta-keto ester functions using a source of aldehyde and a source of ammonia or a primary amine to form a permanent dihydropyridine bond between the beta-keto ester functions. The novel cross-linking reaction can occur at lower temperatures compared to typical cross-linking reactions and can occur in aqueous solutions that have a neutral to mildly alkaline pH of from 6 to 11. The novel cross-linking reaction provides many advantages to performing cross-linking of polymeric chains in coating resins.
摘要翻译： 公开了用于在涂料组合物中交联聚合物链的交联方法。 在一个实施方案中，该方法利用汉氏二氢吡啶反应形成反应产物，包括具有β-酮酸酯官能团的交联聚合物树脂链，其使用醛源和氨源或伯胺以形成β-酮酸酯官能团之间的永久二氢吡啶键 酮酯功能。 与典型的交联反应相比，新的交联反应可以在较低的温度下进行，并且可以发生在中性至弱碱性pH为6至11的水溶液中。新的交联反应提供了许多优点， 聚合物链在涂料树脂中的连接。
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5.发明授权Cross linking thin organic coating resins to substrates through polyfunctional bridging molecules 有权通过多功能桥接分子将薄有机涂层树脂交联到底物上公开(公告)号：US08491729B2
公开(公告)日：2013-07-23
申请号：US12993561
申请日：2009-05-19
IPC分类号： C23C22/48
CPC分类号： C09D143/02
摘要： Disclosed is a method for providing an anti-corrosion protective coating to a metal substrate that uses a coating composition comprising a resin and a polyfunctional bridging molecule to both bind to the resin and to chelate the bound polymeric resin directly to the metal substrate. One category of polyfunctional bridging molecules preferably includes at least one amine function to bind to a resin and at least one carboxylate, thiol, silane, phenolate, acetoacetonate, imine, phosphate, or phosphonate function to chelate to a metal substrate. It is theorized that the amine function can bind to certain pendent chains in coating resins through a Michael addition reaction while the carboxylate, thiol, silane, phenolate, acetoacetonate, imine, phosphate, or phosphonate functions chelate to the metal substrate. These polyfunctional bridging molecules provide an organic binding of the resin to the metal substrates.
摘要翻译： 公开了一种向金属基材提供抗腐蚀保护涂层的方法，其使用包含树脂和多官能桥连分子的涂料组合物来结合树脂并将结合的聚合树脂直接螯合到金属基材上。 一类多官能桥连分子优选包括至少一个胺键，其结合树脂和至少一种羧酸盐，硫醇，硅烷，酚盐，乙酰丙酮盐，亚胺，磷酸盐或膦酸盐的功能以螯合到金属底物。 理论上，胺官能团可以通过迈克尔加成反应与包衣树脂中的某些侧链结合，而羧酸盐，硫醇，硅烷，酚盐，乙酰丙酮盐，亚胺，磷酸盐或膦酸盐与金属底物起螯合作用。 这些多官能桥连分子提供树脂与金属基材的有机结合。
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公开(公告)号：US20110111237A1
公开(公告)日：2011-05-12
申请号：US12993527
申请日：2009-05-19
IPC分类号： C09D179/04 , C09D167/07 , B32B15/08 , B05D3/00
CPC分类号： C09D133/04 , C08F8/30 , C08F2800/20 , C08F2810/20 , C08K3/30 , C08K5/41 , C09D191/06 , Y10T428/273 , Y10T428/31688 , Y10T428/31699 , C08F8/00 , C08F220/14
摘要： Disclosed is cross-linking process for cross-linking polymeric chains in a coating composition. In one embodiment the process utilizes a Hantzsch dihydropyridine reaction to form reaction products including cross-linking polymeric resin chains having beta-keto ester functions using a source of aldehyde and a source of ammonia or a primary amine to form a permanent dihydropyridine bond between the beta-keto ester functions. The novel cross-linking reaction can occur at lower temperatures compared to typical cross-linking reactions and can occur in aqueous solutions that have a neutral to mildly alkaline pH of from 6 to 11. The novel cross-linking reaction provides many advantages to performing cross-linking of polymeric chains in coating resins.
摘要翻译： 公开了用于在涂料组合物中交联聚合物链的交联方法。 在一个实施方案中，该方法利用汉氏二氢吡啶反应形成反应产物，包括具有β-酮酸酯官能团的交联聚合物树脂链，其使用醛源和氨源或伯胺以形成β-酮酸酯官能团之间的永久二氢吡啶键 酮酯功能。 与典型的交联反应相比，新的交联反应可以在较低的温度下进行，并且可以发生在中性至弱碱性pH为6至11的水溶液中。新的交联反应提供了许多优点， 聚合物链在涂料树脂中的连接。
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7.发明授权Autodeposited coating of epoxy and OH groups-containing resin with NCO lower T crosslinker and higher T crosslinker 失效环氧树脂和含OH基树脂的自沉积涂层与NCO低T交联剂和较高T交联剂公开(公告)号：US06723765B2
公开(公告)日：2004-04-20
申请号：US10339823
申请日：2003-01-10
申请人： Brian D. Bammel
发明人： Brian D. Bammel
IPC分类号： C08K320
CPC分类号： C08G18/8074 , C08G18/581 , C08G18/798 , C09D5/088 , Y10T428/31511
摘要： Autodeposition compositions for polymeric coatings of reduced gloss are prepared using resins having at least one hydroxy group and at least one epoxy group per molecule, a low temperature crosslinker and a high temperature crosslinker. The low temperature crosslinker forms a reactive prepolymer that may be subsequently mixed or emulsified with a high temperature crosslinker to form an autodeposition composition. Alternatively, a hybrid crosslinking agent may be utilized which contains both free isocyanate groups reactive at a relatively low temperature with the resin and at least one functional group capable of reacting with the resin only at a relatively elevated temperature. When deposited and cured, the resulting coating has a matte finish that is resistant to surface defects.
摘要翻译： 使用具有至少一个羟基和每分子至少一个环氧基的树脂，低温交联剂和高温交联剂来制备光泽降低的聚合物涂层的自沉积组合物。 低温交联剂形成可随后与高温交联剂混合或乳化以形成自沉积组合物的反应性预聚物。 或者，可以使用混合交联剂，其包含在相对低的温度下与树脂反应的游离异氰酸酯基团和仅在相对高的温度下能与树脂反应的至少一个官能团。 当沉积和固化时，所得到的涂层具有耐表面缺陷的无光饰面。
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公开(公告)号：US06423788B1
公开(公告)日：2002-07-23
申请号：US08686929
申请日：1995-10-06
申请人： Brian D. Bammel , John D. McGee , Walter H. Ohrbom , Todd A. Seaver , Paul J. Harris , John W. Rehfuss
发明人： Brian D. Bammel , John D. McGee , Walter H. Ohrbom , Todd A. Seaver , Paul J. Harris , John W. Rehfuss
IPC分类号： C09D17300
CPC分类号： C09D201/02 , C08G71/00 , C09D167/04 , C09D201/025 , Y10T428/31551
摘要： A curable coating composition is described comprising (A) a carbamate- or urea-functional compound that is the reaction product of a mixture comprising (1) a compound comprising a carbamate or urea group or a group that can be converted to carbamate or urea, and a hydroxyl functional group that is the reaction product of (a) a compound comprising a carbamate or urea group or a group that can be converted to a carbamate or urea group, and an active hydrogen group that is reactive with a lactone ring or a hydroxy carboxylic acid, and (b) a lactone or a hydroxy carboxylic acid, and (2) a compound that is reactive with hydroxyl groups on a plurality of molecules of compound (A)(1), but that is not reactive with the carbamate or urea groups on compound (A)(1), (B) a compound comprising a plurality of groups that are reactive with carbamate or urea.
摘要翻译： 描述了可固化涂料组合物，其包含（A）氨基甲酸酯或脲官能化合物，其为包含（1）包含氨基甲酸酯或脲基团的化合物或可转化为氨基甲酸酯或脲的基团的混合物的反应产物， 和作为（a）包含氨基甲酸酯或脲基的化合物或可以转化为氨基甲酸酯或脲基的基团的反应产物的羟基官能团以及与内酯环或 羟基羧酸和（b）内酯或羟基羧酸，和（2）与多个化合物（A）（1）分子上的羟基反应但不与氨基甲酸酯反应的化合物 或化合物（A）（1）上的脲基，（B）包含与氨基甲酸酯或脲反应的多个基团的化合物。
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公开(公告)号：US5639554A
公开(公告)日：1997-06-17
申请号：US434966
申请日：1995-05-04
申请人： John D. McGee , Brian D. Bammel , John W. Rehfuss
发明人： John D. McGee , Brian D. Bammel , John W. Rehfuss
IPC分类号： C09D4/02 , B05D7/00 , C08L33/06 , C09D133/06 , C09D157/04 , C09D201/02 , C09D201/08 , B05D1/36 , B05D7/24
CPC分类号： B05D7/53 , C09D133/062 , C09D157/04 , C09D201/025 , C08L2205/02 , C08L33/062 , Y10T428/31551
摘要： A coating composition including a first component comprising a compound having appended thereto more than one carbamate functional group, and further including a second component reactive with said carbamate groups, which is a substituted acrylamide compound. The composition is useful as a clearcoating composition in a color-plus-clear composite coating.
摘要翻译： 一种涂料组合物，其包含第一组分，其包含具有多于一个氨基甲酸酯官能团的化合物，并且还包含与作为取代的丙烯酰胺化合物的所述氨基甲酸酯基反应的第二组分。 该组合物可用作彩色 - 透明复合涂层中的透明涂层组合物。
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10.发明授权Coating composition containing carbamate functional and acrylamide functional components 失效含有氨基甲酸酯官能和丙烯酰胺功能组分的涂料组合物
公开(公告)号：US5559195A
公开(公告)日：1996-09-24
申请号：US361273
申请日：1994-12-21
申请人： John D. McGee , Brian D. Bammel , John W. Rehfuss
发明人： John D. McGee , Brian D. Bammel , John W. Rehfuss
IPC分类号： C09D4/02 , B05D7/00 , C08L33/06 , C09D133/06 , C09D157/04 , C09D201/02 , C09D201/08 , G08F8/00
CPC分类号： B05D7/53 , C09D133/062 , C09D157/04 , C09D201/025 , C08L2205/02 , C08L33/062 , Y10T428/31551
摘要： A coating composition including a first component comprising a compound having appended thereto more than one carbamate functional group, and further including a second component reactive with said carbamate groups, which is a substituted acrylamide compound. The composition is useful as a clearcoating composition in a color-plus-clear composite coating.
摘要翻译： 一种涂料组合物，其包含第一组分，其包含具有多于一个氨基甲酸酯官能团的化合物，并且还包含与作为取代的丙烯酰胺化合物的所述氨基甲酸酯基反应的第二组分。 该组合物可用作彩色 - 透明复合涂层中的透明涂层组合物。
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