公开(公告)号：US20140209509A1

公开(公告)日：2014-07-31

申请号：US13790693

申请日：2013-03-08

Applicant: H R D CORPORATION

Inventor： Abbas Hassan ,  Aziz Hassan ,  Rayford G. Anthony ,  Gregory G. Borsinger

IPC: C10G45/00 ,  F17D1/00

CPC classification number: C10G45/00 ,  B01F7/00766 ,  B01F13/1016 ,  B01J8/222 ,  B01J10/002 ,  B01J19/0066 ,  B01J19/1806 ,  B01J2219/0004 ,  B01J2219/00189 ,  C10G1/065 ,  C10G45/02 ,  C10G45/16 ,  C10G45/22 ,  C10G47/00 ,  C10G47/26 ,  C10G47/34 ,  C10G49/007 ,  Y10T137/0318

Abstract: Herein disclosed is a method for hydrogenation comprising: supersaturating a hydrocarbonaceous liquid or slurry stream in a high shear device with a gas stream comprising hydrogen and optionally one or more C1-C6 hydrocarbons to form a supersaturated dispersion; and introducing the supersaturated dispersion into a reactor in the presence of a hydrogenation catalyst to generate a product stream. In some embodiments, the catalyst is present as a slurry or a fluidized or fixed bed of catalyst. In some embodiments, the hydrogenation catalyst is mixed with the hydrocarbonaceous liquid or slurry stream and the gas stream in the high shear device. In some embodiments, the method further comprises recycling at least a portion of an off gas from the reactor, recycling at least a portion of the product stream from the reactor, or both. Also disclosed herein is a system for hydrogenation.

Abstract translation: 本文公开了一种氢化方法，其包括：在高剪切装置中用含有氢气和任选的一种或多种C 1 -C 6烃的气流来过饱和烃类液体或浆料流以形成过饱和分散体; 并在加氢催化剂的存在下将过饱和分散体引入反应器中以产生产物流。 在一些实施方案中，催化剂作为浆料或催化剂的流化床或固定床存在。 在一些实施方案中，氢化催化剂与烃类液体或浆料流以及高剪切装置中的气流混合。 在一些实施方案中，该方法还包括将来自反应器的废气的至少一部分再循环至少一部分来自反应器的产物流或两者。 本文还公开了一种用于氢化的体系。

公开(公告)号：US20140154392A1

公开(公告)日：2014-06-05

申请号：US14174589

申请日：2014-02-06

Applicant: H R D Corporation

Inventor： Abbas HASSAN ,  Aziz Hassan ,  Gregory G. Borsinger

IPC: C11C3/12 ,  C09K8/26 ,  A23B7/153 ,  C09D11/06 ,  C09D7/12 ,  C08L95/00 ,  C10L11/04 ,  C09J131/04

CPC classification number: C11C3/12 ,  A23B7/153 ,  C08L95/00 ,  C09D7/63 ,  C09D11/06 ,  C09J131/04 ,  C09K8/265 ,  C10L11/04 ,  C11B13/00 ,  Y02A30/333 ,  Y02W30/74

Abstract: Steps in the processing of oils derived from plants or vegetables include the degumming, deodorizing and bleaching of the oil before it can be used for further applications. By eliminating one or more of these steps from the processing of the oil, followed by hydrogenating the oil to a specified degree of hydrogenation, the resulting upgraded oils can be incorporated into products having commercial applications. The process uses a high shear mixing device and a hydrogenation catalyst. The process can utilize a single or multiple high shear devices, and utilize renewable oils instead of increasingly scarce petroleum based products. The resulting hydrogenated products may then be utilized in a variety of other commercial applications, such as to render cellulosic products water resistant, provide a coating for numerous cellulosic products, adhesive compositions, ink compositions, firelog compositions, drilling muds or asphalt modifiers.

Abstract translation: 来自植物或蔬菜的油的加工步骤包括在将其用于进一步应用之前，油的脱胶，除臭和漂白。 通过从油的处理中除去一个或多个这些步骤，然后将油氢化至指定的氢化程度，所得到的升级油可以掺入具有商业应用的产品中。 该方法使用高剪切混合装置和氢化催化剂。 该方法可以利用单个或多个高剪切装置，并利用可再生油代替日益稀缺的石油基产品。 所得到的氢化产物可用于各种其他商业应用中，例如使纤维素产品具有防水性，为许多纤维素产品，粘合剂组合物，油墨组合物，防火组合物，钻井泥浆或沥青改性剂提供涂层。

公开(公告)号：US08734725B2

公开(公告)日：2014-05-27

申请号：US13874963

申请日：2013-05-01

Applicant: H R D Corporation

Inventor： Abbas Hassan ,  Gregory G. Borsinger ,  Rayford G. Anthony ,  Aziz Hassan

IPC: B01J19/00

CPC classification number: B01J10/007 ,  A23D9/00 ,  B01F7/00766 ,  B01F13/1013 ,  B01F13/1016 ,  B01J8/02 ,  B01J19/0066 ,  B01J19/18 ,  B01J19/1806 ,  C09D191/06 ,  C09J191/06 ,  C11C3/12 ,  C11C5/00 ,  C11C5/008

Abstract: A system for producing enhanced wax alternatives, including a high shear device comprising a rotor and a stator, and configured to process petroleum wax and base oil with a hydrogen-containing gas under shearing conditions to form a feedstock, wherein at least one of the rotor and the stator comprises a toothed surface; and a reactor comprising a reactor inlet and a reactor outlet, and configured for hydrogenation of the feedstock for a time sufficient to produce enhanced hydrogenated products, wherein the high shear device is in fluid communication with the reactor, whereby the feedstock is transferable therebetween.

Abstract translation: 一种用于生产增强蜡替代品的系统，包括包括转子和定子的高剪切装置，并且构造成在剪切条件下用含氢气体处理石油蜡和基础油以形成原料，其中转子中的至少一个 并且所述定子包括齿形表面; 以及反应器，其包括反应器入口和反应器出口，并且被配置用于原料氢化足以产生增强的氢化产物的时间，其中高剪切装置与反应器流体连通，由此原料可在其间转移。

公开(公告)号：US20140128640A1

公开(公告)日：2014-05-08

申请号：US14150454

申请日：2014-01-08

Applicant: H R D CORPORATION

Inventor： Abbas HASSAN ,  EBRAHIM BAGHERZADEH ,  RAYFORD G. ANTHONY ,  GREGORY G. BORSINGER ,  AZIZ HASSAN

IPC: C07C29/04

CPC classification number: C07C29/04 ,  B01F7/00766 ,  B01F13/1013 ,  B01F13/1016 ,  B01J8/025 ,  B01J8/20 ,  B01J19/0066 ,  B01J19/1806 ,  B01J2219/00006 ,  B01J2219/00779 ,  C07C29/48 ,  C07C31/225

Abstract: Method of producing glycerol that includes mixing a peroxide stream with an olefenic alcohol stream to form a feed stream; processing the feed stream in a high shear device to produce a high shear dispersion of peroxide and olefinic alcohol, wherein the high shear device is configured with a rotor and a stator separated by a shear gap; and contacting the high shear dispersion with a catalyst in a reactor to produce glycerol.

Abstract translation: 制备甘油的方法，包括将过氧化物流与烯醇流混合以形成进料流; 在高剪切装置中处理进料流以产生过氧化物和烯烃的高剪切分散体，其中高剪切装置构造有由剪切间隙分开的转子和定子; 并将高剪切分散体与催化剂在反应器中接触以产生甘油。

公开(公告)号：US20140081198A1

公开(公告)日：2014-03-20

申请号：US14085420

申请日：2013-11-20

Applicant: H R D Corporation

Inventor： Abbas HASSAN ,  Aziz HASSAN ,  Rayford G. ANTHONY

IPC: A61J3/00

CPC classification number: A61J3/00 ,  A61K9/0019 ,  A61M5/142 ,  B01F7/00766 ,  B01F7/008 ,  B01F13/1016

Abstract: In this disclosure, a method is described wherein the method comprises mixing a therapeutic gas or a therapeutic liquid or a combination thereof and a liquid carrier in a high shear device to produce a dispersion; and administering the produced dispersion intravenously to a patient; wherein the produced dispersion contains nanobubbles of the therapeutic gas or droplets of the therapeutic liquid with a mean diameter of less than about 1.5 μm. In this disclosure, a system is also described wherein the system comprises a therapeutic gas source or a therapeutic liquid source or a combination thereof; a liquid carrier source; a high shear device (HSD) having an inlet, an outlet, at least one rotor, and at least one stator separated by a shear gap; and a pump configured to control the flow rate and residence time of a fluid passing through the high shear device.

Abstract translation: 在本公开中，描述了一种方法，其中所述方法包括在高剪切装置中混合治疗气体或治疗液体或其组合和液体载体以产生分散体; 并将产生的分散体静脉内施用于患者; 其中所制备的分散体含有平均直径小于约1.5μm的治疗液体的治疗气体或液滴的纳米气泡。 在本公开中，还描述了一种系统，其中所述系统包括治疗气体源或治疗液体源或其组合; 液体载体源; 具有入口，出口，至少一个转子和由剪切间隔分开的至少一个定子的高剪切装置（HSD）; 以及构造成控制通过高剪切装置的流体的流速和停留时间的泵。

公开(公告)号：US20140010725A1

公开(公告)日：2014-01-09

申请号：US14029504

申请日：2013-09-17

Applicant: H R D Corporation

Inventor： Abbas HASSAN ,  Aziz Hassan ,  Rayford G. Anthony

IPC: C11B3/00

CPC classification number: C11B3/001 ,  A23D9/007 ,  A23D9/04 ,  B01F3/00 ,  B01F3/04 ,  B01F3/04099 ,  B01F7/00766 ,  B01F13/1016 ,  C07C51/00 ,  C10G3/00 ,  C10G2300/1011 ,  C10G2300/1014 ,  C10G2300/1018 ,  Y02P30/20

Abstract: Herein disclosed is a method of processing oil, comprising providing a high shear device comprising at least one rotor and at least one complementarily-shaped stator configured to mix a gas with a liquid; contacting a gas with an oil in the high shear device, wherein the gas is an inert gas or a reactive gas; and forming a product, wherein the product is a solution, a dispersion, or combination thereof. Herein also disclosed is a high shear system for processing oil, comprising; at least one high shear device, having an inlet and at least one rotor and at least one complementarily-shaped stator configured to mix a gas with a liquid; a gas source fluidly connected to the inlet; an oil source fluidly connected to the inlet; and a pump positioned upstream of a high shear device, the pump in fluid connection with the inlet and the oil source.

Abstract translation: 本文公开了一种处理油的方法，包括提供高剪切装置，其包括至少一个转子和构造成将气体与液体混合的至少一个互补形定子; 在高剪切装置中使气体与油接触，其中气体是惰性气体或反应气体; 并形成产品，其中产物是溶液，分散体或其组合。 本文还公开了一种用于加工油的高剪切系统，其包括： 至少一个高剪切装置，具有入口和至少一个转子以及构造成将气体与液体混合的至少一个互补形状的定子; 与入口流体连接的气体源; 与入口流体连接的油源; 以及位于高剪切装置上游的泵，该泵与入口和油源流体连接。

公开(公告)号：US20130266703A1

公开(公告)日：2013-10-10

申请号：US13787569

申请日：2013-03-06

Applicant: H R D CORPORATION

Inventor： Abbas HASSAN ,  Aziz Hassan ,  Rayford G. Anthony

IPC: B01F3/04 ,  A23D9/02

CPC classification number: B01F3/04 ,  A23D9/02 ,  B01F3/04531 ,  B01F7/00766 ,  B01F13/1016 ,  C11B1/00 ,  C11B1/02 ,  C11B1/10 ,  C11B3/00 ,  C11B3/14

Abstract: Herein disclosed is a method of processing oil, comprising providing a high shear device comprising at least one rotor and at least one complementarily-shaped stator configured to mix a gas with a liquid; contacting a gas with an oil in the high shear device, wherein the gas is an inert gas or a reactive gas; and forming a product, wherein the product is a solution, a dispersion, or combination thereof. Herein also disclosed is a high shear system for processing oil, comprising; at least one high shear device, having an inlet and at least one rotor and at least one complementarily-shaped stator configured to mix a gas with a liquid; a gas source fluidly connected to the inlet; an oil source fluidly connected to the inlet; and a pump positioned upstream of a high shear device, the pump in fluid connection with the inlet and the oil source.

Abstract translation: 本文公开了一种处理油的方法，包括提供高剪切装置，其包括至少一个转子和构造成将气体与液体混合的至少一个互补形定子; 在高剪切装置中使气体与油接触，其中气体是惰性气体或反应气体; 并形成产品，其中产物是溶液，分散体或其组合。 本文还公开了一种用于加工油的高剪切系统，其包括： 至少一个高剪切装置，具有入口和至少一个转子以及构造成将气体与液体混合的至少一个互补形状的定子; 与入口流体连接的气体源; 与入口流体连接的油源; 以及位于高剪切装置上游的泵，该泵与入口和油源流体连接。

公开(公告)号：US20130251613A1

公开(公告)日：2013-09-26

申请号：US13847355

申请日：2013-03-19

Applicant: H R D CORPORATION

Inventor： Abbas HASSAN ,  Aziz HASSAN ,  Rayford G. ANTHONY ,  Alishah HASSAN

IPC: C01B23/00 ,  G21G5/00

CPC classification number: C01B23/00 ,  B01F7/00766 ,  B01F13/1016 ,  B01J19/1806 ,  G21G5/00

Abstract: A system for converting a first substance into a second substance, the system including a mixing reactor configured to provide a reactant mixture comprising a first reactant, a second reactant, and a solvent; and a high shear device fluidly connected to the mixing reactor, wherein the high shear device comprises at least one rotor/stator set comprising a rotor and a complementarily-shaped stator symmetrically positioned about an axis of rotation and separated by a shear gap, wherein the shear gap is in the range of from about 10 microns to about 250 microns; and a motor configured for rotating the rotor about the axis of rotation, whereby energy can be transferred from the rotor to the reactants thereby inducing reactions between the first reactant and the second reactant to form a product.

公开(公告)号：US20130237717A1

公开(公告)日：2013-09-12

申请号：US13869814

申请日：2013-04-24

Applicant: H R D CORPORATION

Inventor： Abbas HASSAN ,  Aziz Hassan ,  Gregory G. Borsinger

IPC: C07C67/04 ,  C07C67/00 ,  C07C2/06

CPC classification number: C07C67/04 ,  B01F3/0807 ,  B01F3/20 ,  B01F3/2078 ,  B01F5/0451 ,  B01F5/0463 ,  B01F5/0465 ,  B01F7/00766 ,  B01F13/1013 ,  B01F13/1016 ,  C07C2/06 ,  C07C67/00

Abstract: A method and system for producing dispersed waxes, including a high shear mechanical device. In one embodiment, the method comprises forming a dispersion of wax globules in a carrier liquid in a high shear device prior to implementation in a waxy product. In another instance the system for producing waxy products comprises a high shear device for dispersing wax in a carrier liquid.

Abstract translation: 用于生产分散蜡的方法和系统，包括高剪切机械装置。 在一个实施方案中，该方法包括在蜡质产物中实施之前，在高剪切装置中在载体液体中形成蜡球的分散体。 在另一个实例中，用于生产蜡质产品的系统包括用于将蜡分散在载体液体中的高剪切装置。

公开(公告)号：US20130028803A1

公开(公告)日：2013-01-31

申请号：US13631832

申请日：2012-09-28

Applicant: H R D Corporation

Inventor： Abbas Hassan ,  Aziz Hassan ,  Rayford G. Anthony ,  Krishnan Viswanathan ,  Gregory G. Borsinger

IPC: B01J8/10

CPC classification number: B01F7/00766 ,  B01F13/1013 ,  B01F13/1016 ,  B01J8/025 ,  B01J8/20 ,  B01J19/0066 ,  B01J19/1806 ,  B01J2219/00006 ,  B01J2219/00779 ,  C07C29/106 ,  C08G65/2696 ,  C07C31/202 ,  C07C31/205 ,  C07C31/207

Abstract: Herein disclosed is a system for hydrating an alkylene oxide that includes a high shear device configured to form a dispersion of an alkylene oxide and water, the high shear device comprising a rotor, a stator, and a catalytic surface, wherein the dispersion comprises gas bubbles with an average gas bubble diameter of less than about 5 μm; a pump configured for delivering a liquid stream to the high shear device; and a reactor coupled to the high shear device, and configured to receive the dispersion from the high shear device, wherein the alkylene oxide is hydrated in the reactor.

Abstract translation: 本文公开了一种用于水合环氧烷的系统，其包括构造成形成环氧烷和水的分散体的高剪切装置，所述高剪切装置包括转子，定子和催化表面，其中所述分散体包括气泡 平均气泡直径小于约5μm; 构造成用于将液体流输送到高剪切装置的泵; 和耦合到高剪切装置的反应器，并被配置为从高剪切装置接收分散体，其中烯化氧在反应器中水合。