公开(公告)号：US20180065860A1

公开(公告)日：2018-03-08

申请号：US15798367

申请日：2017-10-30

申请人： UOP LLC

发明人： Christopher P. Nicholas ,  Mark A. Miller ,  Lisa M. Knight ,  Susan M. Wojnicki

IPC分类号： C01B39/48 ,  B01J29/70 ,  B01J37/00 ,  B01J37/04 ,  B01J37/10 ,  C07C2/12

CPC分类号： C01B39/48 ,  B01J29/7046 ,  B01J37/0018 ,  B01J37/04 ,  B01J37/10 ,  C01P2002/72 ,  C01P2002/74 ,  C01P2002/76 ,  C01P2002/86 ,  C01P2004/03 ,  C07C2/12 ,  C07C2521/04 ,  C07C2529/70

摘要： A new crystalline aluminosilicate zeolite comprising a MTT framework has been synthesized that has been designated UZM-53. This zeolite is represented by the empirical formula: M+mRrAl1−xExSiyOz where M represents sodium, potassium or a combination of sodium and potassium cations, R is the organic structure directing agent or agents derived from reactants R1 and R2 where R1 is diisopropanolamine and R2 is a chelating diamine, and E is an element selected from the group consisting of gallium, iron, boron and mixtures thereof. Catalysts made from UZM-53 have utility in various hydrocarbon conversion reactions such as oligomerization.

公开(公告)号：US09815706B2

公开(公告)日：2017-11-14

申请号：US14561112

申请日：2014-12-04

申请人： UOP LLC

发明人： Christopher P. Nicholas ,  Mark A. Miller ,  Melissa M. Galey

IPC分类号： C01B39/04 ,  B01J29/60 ,  C01B39/32 ,  B01J37/00

CPC分类号： C01B39/32 ,  B01J29/60 ,  B01J37/0018 ,  C01B39/04 ,  C01B39/48

摘要： A method for synthesizing a zeolite is described. The method may include the steps of: (a) preparing an aqueous mixture comprising water, a substituted hydrocarbon, and a 1-oxa-4-azacyclohexane derivative; (b) reacting the aqueous mixture; (c) obtaining a solution comprising an organo-1-oxa-4-azoniumcyclohexane compound; (d)) forming a reaction mixture comprising reactive sources of Al, and Si, and the solution; and (e) heating the reaction mixture to form the zeolite.

公开(公告)号：US09522896B2

公开(公告)日：2016-12-20

申请号：US14561132

申请日：2014-12-04

申请人： UOP LLC

发明人： Christopher P. Nicholas ,  Mark A. Miller ,  Melissa M. Galey ,  Benjamin D. Yuhas ,  Sesh Prabhakar

IPC分类号： C07D295/027 ,  C07D295/023

CPC分类号： C07D295/037 ,  C07D295/023 ,  C07D295/027

摘要： Novel 1-oxa-4-azonium cyclohexane salts are described. These compounds can be used as structure directing agents, and they overcome many of the typical problems associated with OSDA synthesis and subsequent zeolite synthesis. Methods for synthesis of the 1-oxa-4-azonium cyclohexane salts from a variety of starting materials are also described. A substituted hydrocarbon is added to water to form a mixture, and a 1-oxa-4-azacyclohexane derivative is then added. The reaction mixture stirred until a solution containing the 1-oxa-4-azonium cyclohexane salt is obtained.

摘要翻译： 描述了新的1-氧杂-4-氮鎓环己烷盐。 这些化合物可以用作结构导向剂，并且它们克服了与OSDA合成和随后的沸石合成相关的许多典型问题。 还描述了用于从各种原料合成1-氧杂-4-氮鎓环己烷盐的方法。 将取代的烃加入到水中以形成混合物，然后加入1-氧杂-4-氮杂环己烷衍生物。 将反应混合物搅拌直到获得含有1-氧杂-4-氮鎓环己烷盐的溶液。

公开(公告)号：US20160159760A1

公开(公告)日：2016-06-09

申请号：US14561132

申请日：2014-12-04

申请人： UOP LLC

发明人： Christopher P. Nicholas ,  Mark A. Miller ,  Melissa M. Galey ,  Benjamin D. Yuhas ,  Sesh Prabhakar

IPC分类号： C07D295/027 ,  C07D295/023

CPC分类号： C07D295/037 ,  C07D295/023 ,  C07D295/027

摘要： Novel 1-oxa-4-azonium cyclohexane salts are described. These compounds can be used as structure directing agents, and they overcome many of the typical problems associated with OSDA synthesis and subsequent zeolite synthesis. Methods for synthesis of the 1-oxa-4-azonium cyclohexane salts from a variety of starting materials are also described.A substituted hydrocarbon is added to water to form a mixture, and a 1-oxa-4-azacyclohexane derivative is then added. The reaction mixture stirred until a solution containing the 1-oxa-4-azonium cyclohexane salt is obtained.

摘要翻译： 描述了新的1-氧杂-4-氮鎓环己烷盐。 这些化合物可以用作结构导向剂，并且它们克服了与OSDA合成和随后的沸石合成相关的许多典型问题。 还描述了用于从各种原料合成1-氧杂-4-氮鎓环己烷盐的方法。 将取代的烃加入到水中以形成混合物，然后加入1-氧杂-4-氮杂环己烷衍生物。 将反应混合物搅拌直到获得含有1-氧杂-4-氮鎓环己烷盐的溶液。

公开(公告)号：US09233856B2

公开(公告)日：2016-01-12

申请号：US14186741

申请日：2014-02-21

申请人： UOP LLC

发明人： Gregory J. Lewis ,  Paulina Jakubczak ,  Julio C. Marte ,  Susan C. Koster ,  Mark A. Miller ,  Lisa M. Knight ,  Jaime G. Moscoso

IPC分类号： C02F1/42 ,  C02F1/28 ,  B01J20/18 ,  C02F101/20

CPC分类号： C02F1/281 ,  B01J20/186 ,  C02F2001/425 ,  C02F2101/20

摘要： A process for removing Hg2+ ions from a liquid stream is disclosed. The process involves contacting the liquid stream with specified UOP Zeolitic Materials. These molecular sieves are particularly effective in removing Hg2+ ions from aqueous streams even in the presence of Mg2+ and Ca2+ ions. The effective molecular sieves have an intermediate range of Si/Al ratios between about 2 and 20 and preferably between 3 and 10.

摘要翻译： 公开了从液体流中除去Hg 2+离子的方法。 该方法包括使液体流与指定的UOP沸石材料接触。 即使在Mg2 +和Ca2 +离子存在下，这些分子筛也能从水流中去除Hg2 +离子。 有效分子筛的Si / Al比例介于约2与20之间，优选3至10之间。

公开(公告)号：US09005573B2

公开(公告)日：2015-04-14

申请号：US13714504

申请日：2012-12-14

申请人： UOP LLC

发明人： Christopher P. Nicholas ,  Mark A. Miller

IPC分类号： C01B39/46 ,  C01B39/48 ,  B01J29/80 ,  B01J29/88 ,  B01J29/86 ,  B01J29/87 ,  B01J29/70 ,  B01J35/00 ,  C01B39/02

CPC分类号： B01J29/88 ,  B01J29/70 ,  B01J29/80 ,  B01J29/86 ,  B01J29/87 ,  B01J35/002 ,  C01B39/023 ,  C01B39/46 ,  C01B39/48

摘要： A new synthesis technique has been developed to prepare a family of coherently grown composites of at least two zeotypes. Examples of these composites are represented by the empirical formula. NanMmk+TtAl1-xExSiyOz where “n” is the mole ratio of Na to (Al+E), M represents at least one metal of zinc, Group 1, Group 2, Group 3 and the lanthanide series of the periodic table, and any combination thereof, “m” is the mole ratio of M to (Al+E), “k” is the average charge of the metal or metals M, T is the organic structure directing agent or agents, “t” is the mole ratio of N from the organic structure directing agent or agents to (Al+E), and E is a framework element such as gallium. The synthesis technique is the Layered Conversion Synthesis technique.

摘要翻译： 已经开发了一种新的合成技术来制备至少两种类型的相干生长复合材料的家族。 这些复合材料的实例由经验公式表示。 NanMmk + TtAl1-xExSiyOz其中“n”是Na与（Al + E）的摩尔比，M表示锌，第1族，第2族，第3族和周期表的镧系元素中的至少一种金属，以及任何 其组合“m”是M与（Al + E）的摩尔比，“k”是金属或金属M的平均电荷，T是有机结构导向剂或试剂，“t”是摩尔比 的N从有机结构导向剂或试剂转变为（Al + E），E是诸如镓的骨架元素。 合成技术是分层转化合成技术。

公开(公告)号：US08992885B2

公开(公告)日：2015-03-31

申请号：US13714486

申请日：2012-12-14

申请人： UOP LLC

发明人： Christopher P. Nicholas ,  Mark A. Miller ,  Robert W. Broach ,  Wharton Sinkler

IPC分类号： C01B39/46 ,  C01B39/48 ,  B01J29/80 ,  B01J43/00 ,  B01J29/70 ,  B01D15/08 ,  B01J20/18 ,  B01J29/86 ,  B01J29/87 ,  B01J29/88 ,  C07C2/66 ,  B01J35/00 ,  C07C2/76 ,  C10G47/20 ,  C07C7/13

CPC分类号： B01J43/00 ,  B01D15/08 ,  B01J20/18 ,  B01J29/70 ,  B01J29/80 ,  B01J29/86 ,  B01J29/87 ,  B01J29/88 ,  B01J35/002 ,  C01B39/023 ,  C01B39/46 ,  C01B39/48 ,  C07C2/66 ,  C07C2/76 ,  C07C7/13 ,  C07C2529/70 ,  C10G47/20

摘要： A new family of coherently grown composites of TUN and IMF zeotypes have been synthesized. These zeolites are represented by the empirical formula. NanMmk+TtAl1−xExSiyOz where “n” is the mole ratio of Na to (Al+E), M represents a metal or metals from zinc, Group 1, Group 2, Group 3 and or the lanthanide series of the periodic table, “m” is the mole ratio of M to (Al+E), “k” is the average charge of the metal or metals M, T is the organic structure directing agent or agents, and E is a framework element such as gallium. These zeolites are similar to TNU-9 and IM-5 but are characterized by unique compositions and synthesis procedures and have catalytic properties for carrying out various hydrocarbon conversion processes and separation properties for carrying out various separations.

摘要翻译： 已经合成了一系列连续生长的TUN和IMF染色体型复合物。 这些沸石由经验公式表示。 NanMmk + TtAl1-xExSiyOz其中“n”是Na与（Al + E）的摩尔比，M表示来自锌，第1族，第2族，第3族和/或周期表的镧系的金属或金属， m“是M与（Al + E）的摩尔比，”k“是金属或金属M的平均电荷，T是有机结构导向剂或试剂，E是骨架元素如镓。 这些沸石类似于TNU-9和IM-5，但是其特征在于独特的组成和合成方法，并且具有用于进行各种烃转化方法和用于进行各种分离的分离性能的催化性能。

公开(公告)号：US08921634B2

公开(公告)日：2014-12-30

申请号：US14102524

申请日：2013-12-11

申请人： UOP LLC

发明人： Timur V. Voskoboynikov ,  Lisa M. King ,  Vincent G. Mezera ,  Christopher P. Nicholas ,  Mark A. Miller

IPC分类号： C07C2/76

CPC分类号： C07C2/76 ,  B01J29/70 ,  B01J29/90 ,  B01J35/002 ,  B01J35/1019 ,  B01J35/1038 ,  B01J35/108 ,  C01B39/48 ,  C07C2529/70 ,  Y02P20/584 ,  C07C15/02

摘要： A new family of aluminosilicate zeolites designated UZM-44 has been synthesized. These zeolites are represented by the empirical formula. NanMmk+TtAl1-xExSiyOz where “n” is the mole ratio of Na to (Al+E), M represents a metal or metals from zinc, Group 1, Group 2, Group 3 and or the lanthanide series of the periodic table, “m” is the mole ratio of M to (Al+E), “k” is the average charge of the metal or metals M, T is the organic structure directing agent or agents, and E is a framework element such as gallium. UZM-44 has catalytic properties for carrying processes involving contacting at least one low carbon number aliphatic hydrocarbon having from 1 to about 4 carbon atoms per molecule with the catalytic composite comprising UZM-44 to produce at least one aromatic hydrocarbon.

摘要翻译： 已经合成了一系列名为UZM-44的硅铝酸盐沸石。 这些沸石由经验公式表示。 NanMmk + TtAl1-xExSiyOz其中“n”是Na与（Al + E）的摩尔比，M表示来自锌，第1族，第2族，第3族和/或周期表的镧系的金属或金属， m“是M与（Al + E）的摩尔比，”k“是金属或金属M的平均电荷，T是有机结构导向剂或试剂，E是骨架元素如镓。 UZM-44具有催化性能，用于承载使每分子具有1至约4个碳原子的至少一个低碳数脂族烃与包含UZM-44的催化复合物接触以产生至少一种芳族烃。

公开(公告)号：US20140171719A1

公开(公告)日：2014-06-19

申请号：US14074741

申请日：2013-11-08

申请人： UOP LLC

发明人： Christopher P. Nicholas ,  Mark A. Miller

IPC分类号： B01J43/00 ,  C07C7/13

CPC分类号： B01J43/00 ,  B01D15/08 ,  B01J20/18 ,  B01J29/70 ,  B01J29/80 ,  B01J29/86 ,  B01J29/87 ,  B01J29/88 ,  B01J35/002 ,  C01B39/023 ,  C01B39/46 ,  C01B39/48 ,  C07C2/66 ,  C07C2/76 ,  C07C7/13 ,  C07C2529/70 ,  C10G47/20

摘要： A new family of coherently grown composites of TUN and IMF zeotypes have been synthesized. These zeolites are represented by the empirical formula. NanMmk+TtAl1-xExSiyOz where “n” is the mole ratio of Na to (Al+E), M represents a metal or metals from zinc, Group 1, Group 2, Group 3 and or the lanthanide series of the periodic table, “m” is the mole ratio of M to (Al+E), “k” is the average charge of the metal or metals M, T is the organic structure directing agent or agents, and E is a framework element such as gallium. These zeolites are similar to TNU-9 and IM-5 but are characterized by unique compositions and synthesis procedures and have catalytic properties for carrying out various hydrocarbon conversion processes and separation properties for carrying out various separations.

摘要翻译： 已经合成了一系列连续生长的TUN和IMF染色体型复合物。 这些沸石由经验公式表示。 NanMmk + TtAl1-xExSiyOz其中“n”是Na与（Al + E）的摩尔比，M表示来自锌，第1族，第2族，第3族和/或周期表的镧系的金属或金属， m“是M与（Al + E）的摩尔比，”k“是金属或金属M的平均电荷，T是有机结构导向剂或试剂，E是骨架元素如镓。 这些沸石类似于TNU-9和IM-5，但是其特征在于独特的组成和合成方法，并且具有用于进行各种烃转化方法和用于进行各种分离的分离性能的催化性能。

公开(公告)号：US20140163284A1

公开(公告)日：2014-06-12

申请号：US14102525

申请日：2013-12-11

申请人： UOP LLC

发明人： Mark A. Miller ,  Christopher P. Nicholas ,  Stephen T. Wilson

IPC分类号： C07C2/66

CPC分类号： C07C7/13 ,  B01J29/70 ,  C01B39/48 ,  C07C2/66 ,  C07C2/76 ,  C07C15/067 ,  C07C15/073 ,  C07C15/08 ,  C07C2529/70 ,  Y02P20/52

摘要： A new family of aluminosilicate zeolites designated UZM-44 has been synthesized. These zeolites are represented by the empirical formula. NanMmk+TtAl1-xExSiyOz where “n” is the mole ratio of Na to (Al+E), M represents a metal or metals from zinc, Group 1, Group 2, Group 3 and or the lanthanide series of the periodic table, “m” is the mole ratio of M to (Al+E), “k” is the average charge of the metal or metals M, T is the organic structure directing agent or agents, and E is a framework element such as gallium. These zeolites are similar to IM-5 but are characterized by unique compositions and synthesis procedures and have catalytic properties for carrying out various hydrocarbon conversion processes and separation properties for carrying out various separations.

摘要翻译： 已经合成了一系列名为UZM-44的硅铝酸盐沸石。 这些沸石由经验公式表示。 NanMmk + TtAl1-xExSiyOz其中“n”是Na与（Al + E）的摩尔比，M表示来自锌，第1族，第2族，第3族和/或周期表的镧系的金属或金属， m“是M与（Al + E）的摩尔比，”k“是金属或金属M的平均电荷，T是有机结构导向剂或试剂，E是骨架元素如镓。 这些沸石类似于IM-5，但其特征在于独特的组合物和合成方法，并且具有用于进行各种烃转化方法和用于进行各种分离的分离性能的催化性能。