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    Catalyst comprising nitrogen-containing heterocyclic compound, and process for producing organic compound using the catalyst
    31.
    发明授权
    Catalyst comprising nitrogen-containing heterocyclic compound, and process for producing organic compound using the catalyst 失效
    包含含氮杂环化合物的催化剂，以及使用该催化剂制备有机化合物的方法

    公开(公告)号：US06403521B1

    公开(公告)日：2002-06-11

    申请号：US09653953

    申请日：2000-09-01

    申请人： Yasutaka Ishii ,  Tatsuya Nakano

    发明人： Yasutaka Ishii ,  Tatsuya Nakano

    IPC分类号： B01J3100

    CPC分类号： C07D253/08 ,  B01J31/006 ,  B01J31/0247 ,  B01J2231/70 ,  B01J2231/72 ,  C07D249/18

    摘要： A catalyst is for use in a reaction using an oxygen-atom-containing reactant and includes a nitrogen-containing heterocyclic compound of the following formula (1): wherein each of R1 and R2 is, identical to or different from each other, a hydrogen atom, a halogen atom, an alkyl group, a haloalkyl group, an aryl group, a cycloalkyl group, a hydroxyl group, an alkoxy group, a carboxyl group, an alkoxycarbonyl group, or an acyl group, and R1 and R2 may be combined to form a double bond or to form an aromatic or non-aromatic ring with the adjacent two carbon atoms, where one or two of heterocyclic ring containing three nitrogen atoms indicated in the formula may be further formed on the R1 or R2, or on the double bond or aromatic or non-aromatic ring formed by R1 and R2; X is an oxygen atom or a hydroxyl group; and Y is a single bond, a methylene group, or a carbonyl group. This catalyst can introduce an oxygen-atom-containing group into an organic substrate under mild conditions.

    摘要翻译： 催化剂用于使用含氧原子反应物的反应中，并且包括下式（1）的含氮杂环化合物：其中R 1和R 2各自彼此相同或不同，为氢 原子，卤素原子，烷基，卤代烷基，芳基，环烷基，羟基，烷氧基，羧基，烷氧基羰基或酰基，R1和R2可以组合 形成双键或与相邻的两个碳原子形成芳族或非芳香族环，其中可以在R1或R2上进一步形成式中所示的含有三个氮原子的一个或两个杂环，或在 由R1和R2形成的双键或芳香或非芳香环; X是氧原子或羟基; Y是单键，亚甲基或羰基。 该催化剂可以在温和条件下将含氧原子的基团引入有机底物。

    Process for producing 1,3-oxazolidine derivatives
    32.
    发明授权
    Process for producing 1,3-oxazolidine derivatives 失效
    1,3-恶唑烷衍生物的制备方法

    公开(公告)号：US06271387B1

    公开(公告)日：2001-08-07

    申请号：US09492318

    申请日：2000-01-27

    申请人： Yasutaka Ishii ,  Tatsuya Nakano

    发明人： Yasutaka Ishii ,  Tatsuya Nakano

    IPC分类号： C07D26352

    CPC分类号： C07D263/04 ,  C07D263/52

    摘要： A process produces 1,3-oxazolidine derivatives by reacting an imine derivative of the following formula (1): with an epoxy compound of the following formula (2): to yield an oxazolidine derivative of the following formula (3):

    摘要翻译： 通过使下式（1）的亚胺衍生物与下式（2）的环氧化合物反应，得到1,3-恶唑烷衍生物：得到下式（3）的恶唑烷衍生物：

    Process for cooxidizing organic compounds, process for producing epoxy compounds and process for producing esters or lactones
    33.
    发明授权
    Process for cooxidizing organic compounds, process for producing epoxy compounds and process for producing esters or lactones 有权
    共氧化有机化合物的方法，生产环氧化合物的方法和生产酯或内酯的方法

    公开(公告)号：US06229023B1

    公开(公告)日：2001-05-08

    申请号：US09424315

    申请日：1999-11-22

    申请人： Yasutaka Ishii ,  Tatsuya Nakano

    发明人： Yasutaka Ishii ,  Tatsuya Nakano

    IPC分类号： C07D31300

    CPC分类号： C07B41/12 ,  B01J31/006 ,  B01J31/0231 ,  B01J31/0247 ,  B01J31/0271 ,  B01J31/20 ,  B01J31/2208 ,  B01J2231/70 ,  B01J2231/72 ,  B01J2531/64 ,  B01J2531/845 ,  C07D315/00

    摘要： According to the inventive co-oxidation process of organic compounds, (A) a compound selected from (A1) a compound having a non-aromatic ethylenic bond and (A2) a ketone or an alcohol corresponding to the ketone is oxidized by molecular oxygen in the presence of N-hydroxyphthalimide or another imide compound and in the coexistence of (B) a compound oxidizable by the imide compound and oxygen and different from the compound (A). As the compound (B), (a) primary or secondary alcohols (e.g., benzhydrol, cyclohexanol), (b) compounds each having a carbon-hydrogen bond at the adjacent position to an unsaturated bond (e.g., tetralin, ethylbenzene) and the like can be used. According to this process, a corresponding epoxy compound from the compound (A1) having a non-aromatic ethylenic bond, and a corresponding ester or lactone from the ketone or its corresponding alcohol (A2) can be obtained in satisfactory yields.

    摘要翻译： 根据本发明的有机化合物的共氧化方法，（A）选自（A1）具有非芳香族烯键的化合物和（A2）酮或与该酮对应的醇的化合物被分子氧氧化 存在N-羟基邻苯二甲酰亚胺或其它酰亚胺化合物，并且（B）可由酰亚胺化合物和氧可氧化并且不同于化合物（A）的化合物共存。 作为化合物（B），（a）伯或仲醇（例如二苯基甲醇，环己醇），（b）在与不饱和键相邻位置具有碳 - 氢键的化合物（例如四氢化萘，乙苯）和 喜欢可以使用。 根据该方法，可以以令人满意的产率获得来自具有非芳香族烯键的化合物（A1）和来自酮或其相应的醇（A2）的相应的酯或内酯的相应的环氧化合物。

    Process for producing organic sulfur acids or salts thereof
    34.
    发明授权
    Process for producing organic sulfur acids or salts thereof 有权
    生产有机硫酸或其盐的方法

    公开(公告)号：US06143924A

    公开(公告)日：2000-11-07

    申请号：US522140

    申请日：2000-03-09

    申请人： Yasutaka Ishii ,  Tatsuya Nakano

    发明人： Yasutaka Ishii ,  Tatsuya Nakano

    IPC分类号： B01J31/02 ,  B01J31/20 ,  C07B61/00 ,  C07C303/02 ,  C07C303/14 ,  C07C303/32 ,  C07C307/00 ,  C07C309/25 ,  C07C309/00

    CPC分类号： C07C303/14 ,  C07C2103/74

    摘要： In the presence of an imide compound of the following formula (1), a sulfur oxide is reacted with an organic substrate to yield a corresponding sulfur acid or its salt. This process can efficiently produce an organic sulfur acid or its salt under relatively mild conditions. ##STR1## wherein each of R.sup.1 and R.sup.2 is, identical to or different from each other, a hydrogen atom, a halogen atom, an alkyl group, an aryl group, a cycloalkyl group, a hydroxyl group, an alkoxy group, a carboxyl group, an alkoxycarbonyl group, or an acyl group, where R.sup.1 and R.sup.2 may be combined to form a double bond or an aromatic or non-aromatic ring; X is an oxygen atom or a hydroxyl group, where one or two N-substituted cyclic imido groups indicated in the formula (1) may be further bonded to the aforementioned R.sup.1, R.sup.2 or to the double bond or aromatic or non-aromatic ring formed together by R.sup.1 and R.sup.2.

    摘要翻译： 在下式（1）的酰亚胺化合物存在下，使硫氧化物与有机底物反应，得到相应的硫酸或其盐。 该方法可以在相对温和的条件下有效地产生有机硫酸或其盐。 其中R 1和R 2各自相同或不同，为氢原子，卤素原子，烷基，芳基，环烷基，羟基，烷氧基，羧基，烷氧基羰基 基团或酰基，其中R 1和R 2可以结合形成双键或芳族或非芳族环; X是氧原子或羟基，其中式（1）中所示的一个或两个N-取代的环亚胺基可以进一步键合到上述R 1，R 2或形成双键或芳族或非芳族环 由R1和R2组合。

    Processes for producing .alpha.-aminonitrile derivatives and .alpha.-amino acids
    35.
    发明授权
    Processes for producing .alpha.-aminonitrile derivatives and .alpha.-amino acids 失效
    制备α-氨基腈衍生物和α-氨基酸的方法

    公开(公告)号：US6100419A

    公开(公告)日：2000-08-08

    申请号：US213904

    申请日：1998-12-17

    申请人： Yasutaka Ishii ,  Tatsuya Nakano

    发明人： Yasutaka Ishii ,  Tatsuya Nakano

    IPC分类号： B01J27/135 ,  B01J31/22 ,  C07B61/00 ,  C07C227/18 ,  C07C227/20 ,  C07C229/28 ,  C07C229/48 ,  C07C253/08 ,  C07C255/46 ,  C07C255/64 ,  C07C253/10 ,  C07C249/08

    CPC分类号： C07C253/08 ,  C07C227/20

    摘要： In the presence of a metal catalyst such as a samarium compound, an oxime ester compound shown by the formula (1): ##STR1## wherein R.sup.1, R.sup.2, and R.sup.3 are the same or different from each other, and each represents a non-reactive atom or a non-reactive organic group; and R.sup.2 and R.sup.3, together with the adjacent carbon atom, may bond together to form a ringis reacted with a cyanogenation agent such as an .alpha.-cyanohydrin compound (e.g., acetone cyanohydrin)to form an .alpha.-aminonitrile derivative. By hydrolyzing the .alpha.-aminonitrile derivative, the corresponding .alpha.-amino acid or a salt thereof can be obtained. According to the above processes, an .alpha.-aminonitrile derivative and an .alpha.-amino acid can be obtained in high yields.

    摘要翻译： 在诸如钐化合物的金属催化剂存在下，由式（1）表示的肟酯化合物：其中R1，R2和R3彼此相同或不同，并且各自表示非反应性原子或 非反应性有机基团; 并且R2和R3与相邻碳原子一起可以键合在一起形成环，与氰化剂如α-氰基醇化合物（例如丙酮氰醇）反应形成α-氨基腈衍生物。 通过水解α-氨基腈衍生物，可以得到相应的α-氨基酸或其盐。 根据上述方法，可以高产率获得α-氨基腈衍生物和α-氨基酸。

    Process for producing amide or lactam
    39.
    发明授权
    Process for producing amide or lactam 有权
    生产酰胺或内酰胺的方法

    公开(公告)号：US08680267B2

    公开(公告)日：2014-03-25

    申请号：US12997287

    申请日：2009-06-10

    申请人： Takahiro Iwahama ,  Tatsuya Nakano ,  Yasutaka Ishii

    发明人： Takahiro Iwahama ,  Tatsuya Nakano ,  Yasutaka Ishii

    IPC分类号： C07D201/04 ,  C07D223/10 ,  C07B61/00 ,  C07D251/54

    CPC分类号： C07D201/04 ,  C07D223/10 ,  Y02P20/52

    摘要： A process produces an amide or lactam by subjecting an oxime compound to rearrangement in a solvent in the presence of: at least one catalyst selected from the group consisting of an aromatic compound (A1) containing a leaving group bound to a carbon atom constituting the aromatic ring, the aromatic ring including, as a constitutive atom thereof, a heteroatom or including, as a constitutive atom thereof, a carbon atom bound to an electron-withdrawing group, and a compound (A2) containing a structure of Formula (1): -G-LA (1) wherein G represents P, N, S, B or Si atom; and LA represents a leaving group, wherein G is bound to one or more atoms or groups in addition to LA; and a co-catalyst including a halogen-containing organic acid, to give the corresponding amide or lactam, wherein, when the aromatic compound (A1) alone is used as the catalyst, the solvent is at least one solvent selected typically from hydrocarbon solvents. The production process can yield amides or lactams simply in high yields without causing large amounts of by-products such as ammonium sulfate.

    摘要翻译： 一种方法是通过使肟化合物在溶剂中进行重排来生成酰胺或内酰胺：在至少一种选自包含与构成芳香族的碳原子结合的离去基团的芳族化合物（A1）的催化剂的存在下， 芳环包括作为其组成原子的杂原子或其包含作为其组成原子的与吸电子基团结合的碳原子，和包含式（1）结构的化合物（A2）： -G-LA（1）其中G表示P，N，S，B或Si原子; 并且LA表示离去基团，其中除了LA之外，G与一个或多个原子或基团结合; 和包含含卤素的有机酸的助催化剂，得到相应的酰胺或内酰胺，其中当单独使用芳族化合物（A1）作为催化剂时，溶剂是通常选自烃溶剂的至少一种溶剂。 生产过程可以简单地以高产率产生酰胺或内酰胺，而不会引起大量副产物如硫酸铵。

    Process for the preparation of vinyl- or allyl-containing compounds
    40.
    发明授权
    Process for the preparation of vinyl- or allyl-containing compounds 有权
    制备含乙烯基或含烯丙基化合物的方法

    公开(公告)号：US07745654B2

    公开(公告)日：2010-06-29

    申请号：US11713024

    申请日：2007-03-02

    申请人： Yasutaka Ishii ,  Tatsuya Nakano ,  Takahiro Iwahama

    发明人： Yasutaka Ishii ,  Tatsuya Nakano ,  Takahiro Iwahama

    IPC分类号： C07F7/04

    CPC分类号： C07C209/66 ,  C07F7/1804 ,  C07F7/1892 ,  C07C211/21 ,  C07C211/27 ,  C07C211/45

    摘要： A vinyl- or allyl-containing compound represented by following Formula (3): wherein R2, R3, R4, R5, and R6 each represent hydrogen atom or a nonmetallic atom-containing group; R7 represents a nonmetallic atom-containing group; Y represents a group selected from the group consisting of —Si(R8)(R9)—, —Si(R10)(R11)—O—, the left hand of which is combined with R7, and —NR12—, wherein R8, R9, R10, R11, and R12 each represent hydrogen atom or a nonmetallic atom-containing group; and “n” represents 0 or 1, is prepared by reacting a vinyl or allyl ester compound represented by following Formula (1): wherein R1 represents hydrogen atom or a nonmetallic atom-containing group; R2, R3, R4, R5, R6, and “n” are as defined above, with a compound represented by following Formula (2): R7—Y—H   (2) wherein R7 and Y are as defined above, in the presence of a transition element compound.

    摘要翻译： 由下式（3）表示的含乙烯基或烯丙基的化合物：其中R2，R3，R4，R5和R6各自表示氢原子或含非金属原子的基团; R7代表非金属原子基团; Y表示选自-Si（R8）（R9） - ，-Si（R10）（R11）-O-，其左手与R7结合的基团和-NR 12 - ，其中R 8， R9，R10，R11和R12各自表示氢原子或含非金属原子的基团; “1”表示的乙烯基或烯丙基酯化合物：其中R1表示氢原子或含非金属原子的基团，并且“n”表示0或1。 R 2，R 3，R 4，R 5，R 6和“n”如上所定义，与下式（2）表示的化合物：其中R 7和Y如上所定义的R7-Y-H（2） 的过渡元素化合物。