公开(公告)号：US09296714B2

公开(公告)日：2016-03-29

申请号：US13759663

申请日：2013-02-05

申请人： BASF SE

发明人： Andrei-Nicolae Parvulescu ,  Ulrich Mueller ,  Joaquim Henrique Teles ,  Bianca Seelig ,  Philip Kampe ,  Markus Weber ,  Robert Bayer ,  Karsten Seidel ,  Peter Resch

IPC分类号： C01B39/12 ,  B01J29/70 ,  C07D301/12 ,  B01J29/04 ,  B01J35/00 ,  B01J35/02 ,  B01J37/00 ,  C01B37/00 ,  C01B39/02 ,  C01B39/06 ,  B01J29/89

CPC分类号： C07D301/12 ,  B01J29/041 ,  B01J29/7088 ,  B01J29/89 ,  B01J35/002 ,  B01J35/023 ,  B01J37/0009 ,  B01J37/0045 ,  B01J2229/18 ,  B01J2229/37 ,  B01J2229/42 ,  C01B37/005 ,  C01B39/026 ,  C01B39/065 ,  C01B39/12

摘要： The present invention relates to a micropowder, wherein the particles of the micropowder have a Dv10 value of at least 2 micrometer and the micropowder comprises mesopores which have an average pore diameter in the range of from 2 to 50 nm and comprise, based on the weight of the micropowder, at least 95 weight-% of a microporous aluminum-free zeolitic material of structure type MWW containing titanium and zinc.

摘要翻译： 本发明涉及一种微粉，其中微粉的颗粒具有至少2微米的Dv10值，并且该微粉包括平均孔径在2至50nm范围内的介孔，并基于重量 的微粉末，至少95重量％的含有钛和锌的结构型MWW的微孔无铝沸石材料。

公开(公告)号：US20150105479A1

公开(公告)日：2015-04-16

申请号：US14396396

申请日：2013-04-15

申请人： BASF SE

发明人： Alexander Schäfer ,  Mathias Feyen ,  Andrei-Nicolae Parvulescu ,  Ulrich Müller ,  Bernd Bastian Schaack

IPC分类号： B01J29/76 ,  C07C41/09 ,  B01J29/46

CPC分类号： B01J29/76 ,  B01J23/80 ,  B01J29/06 ,  B01J29/40 ,  B01J29/46 ,  C07C41/01 ,  C07C41/09 ,  C07C43/043

摘要： The invention relates to a catalytically active body for the synthesis of dimethyl ether from synthesis gas. In particular, the invention relates to an improved catalytically active body for the synthesis of dimethyl ether, whereby the components of the active body comprise a methanol active component and an acid component comprising a zeolitic material being crystallized by means of one or more alkenyltrialkylammonium cation R1R2R3R4N+-containing compounds as structure directing agent. Furthermore, the present invention concerns a method for the preparation of a catalytically active body, the use of the catalytically active body and a method for the preparation of dimethyl ether from synthesis gas.

摘要翻译： 本发明涉及用于从合成气合成二甲醚的催化活性体。 特别地，本发明涉及用于合成二甲醚的改进的催化活性体，其中活性体的组分包含甲醇活性组分和酸组分，该组分包含通过一个或多个烯基三烷基铵阳离子R1R2R3R4N +结晶的沸石材料， 作为结构导向剂的化合物。 此外，本发明涉及制备催化活性体的方法，催化活性体的用途以及从合成气中制备二甲醚的方法。

公开(公告)号：US20140142361A1

公开(公告)日：2014-05-22

申请号：US14076723

申请日：2013-11-11

申请人： BASF SE

发明人： Manuela Gaab ,  Ulrich Müller ,  Milan Kostur ,  Kirsten Spannhoff ,  Kerem Bay ,  Andrei-Nicolae Parvulescu

IPC分类号： C07C1/22

CPC分类号： C07C1/20 ,  C07C2529/40 ,  C07C11/02

摘要： The present invention relates to a process for the conversion of oxygenates to olefins comprising (i) providing a gas stream comprising one or more oxygenates; and (ii) contacting the gas stream with a catalyst; wherein the catalyst comprises a zeolitic material having an MFI, MEL, and/or MWW-type framework structure comprising YO2 and X2O3, wherein Y is a tetravalent element, and X is a trivalent element, said zeolitic material being obtainable and/or obtained according to a method comprising (1) preparing a mixture comprising one or more sources for YO2, one or more sources for X2O3, and one or more solvents; and (2) crystallizing the mixture obtained in step (1) to obtain a zeolitic material having an MFI, MEL and/or MWW-type framework structure; wherein the mixture crystallized in step (2) contains 3 wt.-% or less of the one or more elements M based on 100 wt.-% of YO2, wherein M stands for sodium.

摘要翻译： 本发明涉及一种将含氧化合物转化为烯烃的方法，包括（i）提供包含一种或多种含氧化合物的气流; 和（ii）使气流与催化剂接触; 其中所述催化剂包含具有包含YO 2和X 2 O 3的MFI，MEL和/或MWW型骨架结构的沸石材料，其中Y是四价元素，X是三价元素，所述沸石材料可根据 涉及一种方法，包括（1）制备包含一种或多种YO源的混合物，一种或多种X 2 O 3源和一种或多种溶剂的混合物; 和（2）使步骤（1）中获得的混合物结晶，得到具有MFI，MEL和/或MWW型骨架结构的沸石材料; 其中在步骤（2）中结晶的混合物含有基于100重量％的YO 2的一种或多种元素M的3重量％或更少，其中M代表钠。

公开(公告)号：US20230150827A1

公开(公告)日：2023-05-18

申请号：US17917331

申请日：2021-03-23

申请人： BASF SE

发明人： Andrei-Nicolae Parvulescu ,  Ulrich Mueller ,  Tress Maria De Baerdemaeker ,  Ute Kolb ,  Bernd Marler ,  Feng-Shou Xiao ,  Toshiyuki Yokoi ,  Weiping Zhang ,  Dirk De Vos ,  Xiangju Meng

IPC分类号： C01B39/12 ,  C01B39/04

CPC分类号： C01B39/12 ,  C01B39/04 ,  C01P2002/77 ,  C01P2002/76 ,  C01P2002/72

摘要： The present invention relates to a crystalline material having a framework structure comprising O and one or more tetravalent elements Y, and optionally comprising one or more trivalent elements X, wherein the crystalline material displays a crystallographic unit cell of the monoclinic space group C2, wherein the unit cell parameter a is in the range of from 14.5 to 20.5 Å, the M unit cell parameter b is in the range of from 14.5 to 20.5 Å, the unit cell parameter c in the range of from 11.5 to 17.5 Å and the unit cell parameter β is in the range of from 109 to 118°, wherein the framework density is in the range of from 11 to 23 T-atoms/1000 Å3 wherein the framework structure comprises 12 membered rings, and wherein the framework structure displays a 2-dimensional channel e dimensionality of 12 membered ring channels. The present invention further relates to a process for the production of said material, as N well as to its use, in particular as a catalyst or catalyst component.

公开(公告)号：US11291980B2

公开(公告)日：2022-04-05

申请号：US16461134

申请日：2017-12-20

申请人： BASF SE

发明人： Andrei-Nicolae Parvulescu ,  Ulrich Mueller ,  Hans-Juergen Luetzel ,  Georg Uhl ,  Joaquim Henrique Teles ,  Dominic Riedel ,  Daniel Urbanczyk ,  Ulrike Wegerle ,  Markus Weber ,  Nicolai Tonio Woerz ,  Christian Mueller

IPC分类号： B01J29/89 ,  B01J35/10 ,  B01J37/00 ,  C01B37/00

摘要： A process for preparing an extrudable composition comprising a titanium-containing zeolitic material having framework type MWW, the process comprising providing a titanium-containing zeolitic material having framework type MWW, having a water absorption capacity of at least 11 weight-%, subjecting the titanium-containing zeolitic material having framework type MWW an acid treatment, optionally incorporating zinc in the acid-treated titanium-containing zeolitic material having framework type MWW; preparing a composition comprising the titanium-containing zeolitic material having framework type MWW obtained from (ii) or (iii), a precursor of a silica binder, water, and a kneading agent, wherein the composition does not comprise a polyethylene oxide.

公开(公告)号：US10981796B2

公开(公告)日：2021-04-20

申请号：US16349364

申请日：2017-12-12

申请人： BASF SE

发明人： Andrei-Nicolae Parvulescu ,  Ulrich Mueller ,  Regina Vogelsang ,  Nicole Sabine Bruns ,  Jan-Oliver Weidert

IPC分类号： C01B37/00 ,  C01B39/00 ,  B01J29/70 ,  B01J29/89 ,  B01D3/06 ,  B01J29/86 ,  B01J35/10 ,  C01B39/02 ,  C01B39/06

摘要： A process comprising hydrothermally synthesizing a titanium-containing zeolitic material having framework type MWW in the presence of an MWW template compound, obtaining a mother liquor comprising water, a first portion of the MWW template compound and a titanium-containing zeolitic material having framework type MWW comprising a second portion of the MWW template compound, separating the first portion of the MWW template compound from the mother liquor and recycling the first portion of the MWW template compound into a hydrothermal synthesis of a titanium-containing zeolitic material having framework type MWW.

公开(公告)号：US10793443B2

公开(公告)日：2020-10-06

申请号：US16202918

申请日：2018-11-28

申请人： BASF SE

发明人： Stefan Maurer ,  Andrei-Nicolae Parvulescu ,  Ulrich Mueller ,  Xiangju Meng ,  Feng-Shou Xiao ,  Yeqing Wang

IPC分类号： C01B39/12 ,  C01B39/48 ,  B01J29/86 ,  B01J20/18 ,  B01D15/36 ,  B01D53/86

摘要： The present invention relates to a process for the production of a boron-containing zeolitic material having an MWW framework structure comprising YO2 and B2O3, wherein Y stands for a tetravalent element, wherein said process comprises(a) providing a mixture comprising one or more sources for YO2, one or more sources for B2O3, one or more organotemplates, and seed crystals,(b) crystallizing the mixture obtained in (a) for obtaining a layered precursor of the boron-containing MWW-type zeolitic material,(c) calcining the layered precursor obtained in (b) for obtaining the boron-containing zeolitic material having an MWW framework structure,wherein the one or more organotemplates have the formula (I) R1R2R3N  (I) wherein R1 is (C5-C8)cycloalkyl, and wherein R2 and R3 are independently from each other H or alkyl, as well as to a synthetic boron-containing zeolite which is obtainable and/or obtained according to the inventive process as well as to its use.

公开(公告)号：US10780432B2

公开(公告)日：2020-09-22

申请号：US16470834

申请日：2018-01-18

申请人： BASF SE

发明人： Andrei-Nicolae Parvulescu ,  Ulrich Mueller ,  Hans-Juergen Luetzel ,  Joaquim Henrique Teles ,  Dominic Riedel ,  Daniel Urbanczyk ,  Ulrike Wegerle ,  Markus Weber ,  Nicolai Tonio Woerz ,  Christian Mueller

IPC分类号： B01J29/89 ,  B01J29/70 ,  B01J35/02 ,  B01J35/10 ,  B01J37/00 ,  C01B39/02 ,  C01B39/06 ,  C01B39/12 ,  C07D301/12 ,  B01J37/08

摘要： A process for preparing a molding comprising zinc and a titanium-containing zeolitic material having framework type MWW, comprising (i) providing a molding comprising a titanium-containing zeolitic material having framework type MWW; (ii) preparing an aqueous suspension comprising a zinc source and the molding comprising a titanium-containing zeolitic material having framework type MWW prepared in (i); (iii) heating the aqueous suspension prepared in (ii) under autogenous pressure to a temperature of the liquid phase of the aqueous suspension in the range of from 100 to 200° C., obtaining an aqueous suspension comprising a molding comprising zinc and a titanium-containing zeolitic material having framework type MWW; (iv) separating the molding comprising zinc and a titanium-containing zeolitic material having framework type MWW from the liquid phase of the suspension obtained in (iii).

公开(公告)号：US10774034B2

公开(公告)日：2020-09-15

申请号：US16610131

申请日：2018-05-03

申请人： BASF SE

发明人： Alvaro Gordillo ,  Andrei-Nicolae Parvulescu ,  Armin Lange De Oliveira ,  Andreas Kuschel ,  Juergen Bechtel ,  Johannes Lieberknecht ,  Ulrich Müller ,  Johann-Peter Melder ,  Christian Gruenanger

IPC分类号： C07C213/04 ,  B01J29/24 ,  B01J29/40 ,  B01J29/70 ,  C07C215/08 ,  B01J37/30 ,  C01B39/26 ,  C01B39/38 ,  C07C211/10 ,  B01J37/08

摘要： The present invention relates to a process for the conversion of ethylene oxide to 2-aminoethanol and/or ethane-1,2-diamine and/or linear polyethylenimines of the formula H2N—(CH2CH2NH)n—CH2CH2—NH2 wherein n≥1 comprising (i) providing a catalyst comprising a zeolitic material comprising YO2 and X2O3, wherein Y is a tetravalent element and X is a trivalent element; (ii) providing a gas stream comprising ethylene oxide and ammonia; (iii) contacting the catalyst provided in (i) with the gas stream provided in (ii) for converting ethylene oxide to 2-aminoethanol and/or ethane-1,2-diamine and/or linear polyethylenimines.

公开(公告)号：US10737944B2

公开(公告)日：2020-08-11

申请号：US16060260

申请日：2016-12-07

申请人： BASF SE

发明人： Nicolas Vautravers ,  Joaquim Henrique Teles ,  Ralf Pelzer ,  Daniel Schneider ,  Florian Garlichs ,  Andreas Keller ,  Andrei-Nicolae Parvulescu ,  Ulrich Müller ,  Sumana Roy

IPC分类号： C01B39/12 ,  B01J29/86 ,  C01B39/02 ,  C07C45/54 ,  C07C67/39 ,  C01B39/06 ,  B01J29/70 ,  B01J37/02 ,  B01J35/10

摘要： An incipient wetness impregnation method for preparing a tin-containing zeolitic material having framework type BEA, a novel tin-containing zeolitic material having framework type BEA and its use.