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    Polycarbonates exhibiting improved heat resistance
    33.
    发明授权
    Polycarbonates exhibiting improved heat resistance 失效
    表现出改善的耐热性的聚碳酸酯

    公开(公告)号：US4663434A

    公开(公告)日：1987-05-05

    申请号：US707450

    申请日：1985-03-01

    Applicant: Victor Mark ,  Charles V. Hedges

    Inventor： Victor Mark ,  Charles V. Hedges

    IPC: C07C37/20 ,  C07C39/16 ,  C07C39/17 ,  C08G63/64 ,  C08G64/06 ,  C08L69/00 ,  C07C43/20

    CPC classification number: C08L69/00 ,  C07C37/20 ,  C07C39/16 ,  C07C39/17 ,  C08G63/64 ,  C08G64/06 ,  C08L69/005 ,  C07C2101/14

    Abstract: Novel heat resistant polycarbonates are provided which are the polymerized reaction products of:(i) a carbonate precursor; and(ii) at least one dihydric phenol selected from dihydric phenols represented by the general formulae ##STR1## wherein: each R.sup.1 is independently selected from halogen radicals, monovalent hydrocarbon radicals, and monovalent hydrocarbonoxy radicals;each R.sup.2 is independently selected from halogen radicals, monovalent hydrocarbon radicals, and monovalent hydrocarbonoxy radicals;R.sup.4 and R.sup.5 are independently selected from monovalent hydrocarbon radicals;R.sup.3 is selected from hydrogen and monovalent hydrocarbon radicals, with the proviso that if R.sup.3 is a hydrogen radical than at least one of the monovalent hydrocarbon radicals represented by R.sup.4 and R.sup.5 contains at least two carbon atoms;R.sup.7 is selected from hydrogen and monovalent hydrocarbon radicals;R.sup.6 is a divalent hydrocarbon radicals; andn and n' are independently selected from whole numbers having a value of from 0 to 4 inclusive.

    Abstract translation: 提供了新的耐热聚碳酸酯，它们是以下的聚合反应产物：（i）碳酸酯前体; 和（ii）至少一种选自由通式“IMAGE”和“IMAGE”表示的二元酚的二元酚，其中：每个R 1独立地选自卤素基，一价烃基和一价烃氧基; 每个R 2独立地选自卤素基，一价烃基和一价烃氧基; R4和R5独立地选自一价烃基; R 3选自氢和一价烃基，条件是如果R 3是比由R 4和R 5表示的至少一个一价烃基含有至少两个碳原子的氢原子; R7选自氢和一价烃基; R6是二价烃基; n和n'独立地选自0〜4的整数，包括0和4。

    Polycarbonate exhibiting improved heat resistance from halogenated cycloalkylidene diphenol
    34.
    发明授权
    Polycarbonate exhibiting improved heat resistance from halogenated cycloalkylidene diphenol 失效
    表现出从卤代环亚烷基二酚改善的耐热性的聚碳酸酯

    公开(公告)号：US4638036A

    公开(公告)日：1987-01-20

    申请号：US773138

    申请日：1985-09-06

    Applicant: Victor Mark ,  Charles V. Hedges

    Inventor： Victor Mark ,  Charles V. Hedges

    IPC: C08G64/06 ,  C08G63/64

    CPC classification number: C08G64/06

    Abstract: Linear thermoplastic polycarbonates derived from:(i) a carbonate precursor; and(ii) at least one dihydric phenol represented by the general formula ##STR1## wherein R is independently selected from hydrogen and lower alkyl radicals,X is selected from monocyclic cycloalkylidene radicals containing from 8 to about 16 ring carbon atoms, andn and n' are independently selected from whole numbers having a value of from 0 to 2 inclusive, with the proviso that the sum of n plus n' is at least one.

    Abstract translation: 线性热塑性聚碳酸酯衍生自：（i）碳酸酯前体; 和（ii）由通式“IMAGE”表示的至少一种二元酚，其中R独立地选自氢和低级烷基，X选自含有8至约16个环碳原子的单环亚环烷基，n和n '独立地选自具有0至2的值的整数，其中n + n'的和为至少1。

    Polycarbonate from cycloalkylidene tetra alkyl substituted diphenol
    35.
    发明授权
    Polycarbonate from cycloalkylidene tetra alkyl substituted diphenol 失效
    环烷基四烷基取代二酚的聚碳酸酯

    公开(公告)号：US4554309A

    公开(公告)日：1985-11-19

    申请号：US620712

    申请日：1984-06-14

    Applicant: Victor Mark ,  Charles V. Hedges

    Inventor： Victor Mark ,  Charles V. Hedges

    IPC: C08L69/00 ,  C08G63/64 ,  C08G64/00 ,  C08G64/06 ,  C08K5/36 ,  C08K5/42 ,  C08G63/62

    CPC classification number: C08G64/06

    Abstract: Thermoplastic polymer exhibiting improved heat resistance comprised of the polymerized reaction products of (i) a carbonate precursor, and (ii) at least one dihydric phenol represented by the general formula ##STR1## wherein: R is independently selected from alkyl radicals;R.sup.1 is independently selected from monovalent hydrocarbon radicals;X is selected from cycloalkylidene radicals containing from 8 to about 16 ring carbon atoms;each n is two; andm represents a whole number having a value of from 0 up to the number of replaceable hydrogen atoms present on X.

    Abstract translation: 表现出改善的耐热性的热塑性聚合物包括（i）碳酸酯前体的聚合反应产物和（ii）由通式表示的至少一种二元酚，其中：R独立地选自烷基; R1独立地选自一价烃基; X选自含有8至约16个环碳原子的环烷叉基; 每个n是两个; 并且m表示具有从0直到存在于X上的可替代氢原子数的整数。

    Polyarylate resin of thiodiphenols and isophthalic acid or derivatives thereof
    36.
    发明授权
    Polyarylate resin of thiodiphenols and isophthalic acid or derivatives thereof 失效
    硫代二酚和间苯二甲酸或其衍生物的聚芳酯树脂

    公开(公告)号：US4477647A

    公开(公告)日：1984-10-16

    申请号：US527743

    申请日：1983-08-30

    Applicant: Victor Mark ,  Charles V. Hedges

    Inventor： Victor Mark ,  Charles V. Hedges

    IPC: C08G63/00 ,  C08G63/18 ,  C08G63/19 ,  C08G63/68 ,  C08G63/688 ,  C08G75/26

    CPC classification number: C08G63/6886

    Abstract: Polyarylate resin compositions exhibiting flame retardancy comprised of at least one polyarylate resin derived from:(i) at least one aromatic dicarboxylic acid or a reactive derivative thereof; and(ii) from about 1 to 100 weight percent of at least one thiodiphenol and from 0 to about 99 weight percent of at least one dihydric phenol, based on the total amount of thiodiphenol and dihydric phenol.

    Abstract translation: 表现出阻燃性的聚芳酯树脂组合物由至少一种衍生自以下的多芳基化合物树脂组成：（i）至少一种芳族二羧酸或其活性衍生物; 和（ii）基于硫代二酚和二元酚的总量，约1至100重量％的至少一种硫代二酚和0至约99重量％的至少一种二元酚。

    Polyarylate compositions
    37.
    发明授权
    Polyarylate compositions 失效
    聚芳酯组合物

    公开(公告)号：US4463161A

    公开(公告)日：1984-07-31

    申请号：US452906

    申请日：1982-12-27

    Applicant: Victor Mark ,  Charles V. Hedges

    Inventor： Victor Mark ,  Charles V. Hedges

    IPC: C08G63/00 ,  C08G63/19 ,  C08G63/193 ,  C08G63/682 ,  C08G63/18

    CPC classification number: C08G63/193

    Abstract: Polyarylate resins derived from (i) an aromatic dicarboxylic acid; and (ii) a branched alkylidene dihydric phenol, wherein branching occurs on a carbon atom of the alkylidene radical which is at least one carbon atom removed from the benzylic carbon atom bridging the two phenolic residues.

    Abstract translation: 衍生自（i）芳族二羧酸的聚芳酯树脂; 和（ii）支链亚烷基二元酚，其中分支发生在亚烷基自由基的碳原子上，所述亚烷基是从桥连两个酚残基的苄基碳原子中除去的至少一个碳原子。

    Fluorinated diphenols and method for their preparation
    38.
    发明授权
    Fluorinated diphenols and method for their preparation 失效
    氟化二酚及其制备方法

    公开(公告)号：US4365098A

    公开(公告)日：1982-12-21

    申请号：US221884

    申请日：1980-12-31

    Applicant: Victor Mark ,  Charles V. Hedges

    Inventor： Victor Mark ,  Charles V. Hedges

    IPC: C07C27/00 ,  C07C37/11 ,  C07C37/20 ,  C07C39/367 ,  C07C67/00 ,  C07C39/16

    CPC classification number: C07C37/115 ,  C07C37/16 ,  C07C37/20 ,  C07C39/367

    Abstract: Fluorinated bisphenols having a fluorinated alkyl group and a hydrogen atom upon the methylene carbon atom are prepared at atmospheric pressure or at low pressures from a phenol reactant and a fluorinated aldehyde compound in the presence of gaseous hydrogen chloride or gaseous hydrogen bromide catalyst. The fluroinated bisphenols having the fluorinated alkyl group and a hydrogen atom upon the methylene carbon atom are produced in excellent yields and are used for making flame-retardant polycarbonates and polyester-carbonate copolymers.

    Abstract translation: 在气态氯化氢或溴化氢气体气体催化剂存在下，在大气压或低压下由苯酚反应物和氟化醛化合物制备具有氟代烷基和亚甲基碳原子上的氢原子的氟化双酚。 在亚甲基碳原子上具有氟化烷基和氢原子的氟化双酚以优异的收率生产，并用于制备阻燃聚碳酸酯和聚酯 - 碳酸酯共聚物。

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