摘要:
ELASTOMERIC SPANDEX FIBERS OF SEGMENTED UREA/URETHANE/ETHER COPOLYMERS WHEREIN THE ETHER PORTION IS DERIVED FROM A POLY(TETRAMETHYLENE) GLYCOL OR A COPOLYMER THEREOF WHICH MAY INCLUDE 1,2-CYCLOHEXYLENEDIMETHYLENEOXY (CALLED OBN) REPEAT UNITS, THE URETHANE PORTION IS DERIVED FROM A FUNCTIONALLY ALIPHATIC NON-HINDERED HYDROCARBON DIISOCYANATE, THE UREA PORTION IS DERIVED BY CHAIN-EXTENSION FROM WATER AND/OR A FUNCTIONALLY ALIPHATIC NON-HINDERED HYDROCARBON DIAMINE, SAID SEGMENTED COPOLYMER HAVING FROM 2 TO 8 PERCENT BY WEIGHT OF UREA SEGMENTS WHEREBY THE SEGMENTED COPOLYMER CAN BE DISSOLVED IN NORMALLY USEFUL SOLVENTS FOR SPINNING SPANDEX FIBERS AND SOLUTIONS CAN BE OBTAINED WHICH POSSESS SUBSTANTIALLY CONSTANT VISCOSITY, ARE STABLE AGAINST GELATION AND CAN BE SPUN INTO TEXTILE FIBERS. WHEN CHAINEXTENSION IS ONLY 70 TO 98 PERCENT COMPLETED BEFORE SPINNING, THE FIBERS SPUN CAN BE IMPROVED BY TREATMENT WITH A WATER MEDIUM SUCH AS STEAM OR HUMIDITY IN THE ATMOSPHERE. WHEN OBN IS PRESENT AS A REPEAT UNIT IN THE COPOLYMER GLYCOL THE LOW TEMPERATURE PROPERTIES OF THE SPANDEX FIBERS ARE ENHANCED.
摘要:
The present invention relates to a phosphorus containing polyol, obtainable or obtained by a process comprising the reaction of at least one polyol with a phosphorus containing compound of the general formula (I) as defined herein, as well as the process for preparing a phosphorus containing polyol, comprising the reaction of at least one polyol with a phosphorus containing compound of the general formula (I). Furthermore, the present invention relates to the use of a phosphorus containing polyol as disclosed herein as a flame retardant, to a process for the preparation of a polyurethane and the polyurethane as such.
摘要:
The invention relates to a process for preparing polyurethanes, which comprises reacting a) polyisocyanates with b) compounds having at least two hydrogen atoms reactive with isocyanate groups, wherein said compounds having at least two hydrogen atoms reactive with isocyanate groups b) comprise at least one polyether alcohol b1) having a functionality of 2-8 and a hydroxyl number of 200-600 mgKOH/g, obtained by addition of an alkylene oxide b1b) onto a compound having at least two hydrogen atoms reactive with alkylene oxides by using an amine b1c) as catalyst.
摘要:
Polyurethanes having improved tear resistance which are the reaction product of the following components: A) a polyol component containing dimer diol and/or trimer triol and/or an OH-terminated polyester produced from polycarboxylic acids, preferably dimer fatty acid and/or trimer fatty acid, and diols and B) an isocyanate component containing prepolymers obtained by reacting polyfunctional isocyanates with dimer diol and/or trimer triol and/or an OH-terminated polyester produced from polycarboxylic acids, preferably dimer fatty acid and/or trimer fatty acid, and diols; and processes for their manufacture.