Method for producing resin for optical component, resin for optical component, spectacle lens, and spectacles

    公开(公告)号:US11479654B2

    公开(公告)日:2022-10-25

    申请号:US16367698

    申请日:2019-03-28

    发明人: Masahisa Kousaka

    摘要: A method for producing an optical component resin, suppressing yellowing due to addition of an ultraviolet absorber, an optical component resin, a spectacle lens, and spectacles. A method for producing an optical component resin, including a step of polymerizing a polymerizable composition containing a polythiol component, a polyisocyanate component, and an ultraviolet absorber, in which the ultraviolet absorber has a Hazen color number (APHA) of 40 or less in a toluene solution thereof having a concentration of 10% by mass, an optical component resin obtained by the producing method, an optical component formed of the optical component resin, a spectacle lens including a lens substrate formed of the optical component resin, and spectacles including the spectacle lens.

    POLY(THIOKETAL-URETHANE) SCAFFOLDS AND METHODS OF USE
    3.
    发明申请
    POLY(THIOKETAL-URETHANE) SCAFFOLDS AND METHODS OF USE 有权
    POLY(THIOKETAL-URETHANE)SCAFFOLDS AND METHODS OF USE

    公开(公告)号:US20150231302A1

    公开(公告)日:2015-08-20

    申请号:US14430130

    申请日:2013-09-20

    摘要: The presently-disclosed subject matter includes biodegradable scaffolds. Exemplary biodegradable scaffolds comprise a plurality of polythioketal polymers, and a plurality of polyisocyanates, where at least one polyisocyanate is linked to at least one polymer to form the scaffold. Thus, certain embodiments of scaffolds comprise a cross-linked network of the polythioketal polymers and the polyisocyanates. The presently-disclosed subject matter also includes methods for treating tissue, such as skin or bone tissue, in a subject in need thereof. Treatment methods comprise contacting the tissue with an effective amount of the biodegradable scaffold. Furthermore, the presently-disclosed subject matter includes methods for making the present biodegradable scaffolds.

    摘要翻译: 目前公开的主题包括可生物降解的支架。 示例性的可生物降解的支架包含多个聚硫酮缩酮聚合物和多个多异氰酸酯,其中至少一种多异氰酸酯与至少一种聚合物连接以形成支架。 因此,支架的某些实施方案包括聚硫酮缩酮聚合物和多异氰酸酯的交联网络。 目前公开的主题还包括在有需要的受试者中治疗组织如皮肤或骨组织的方法。 治疗方法包括使组织与有效量的可生物降解的支架接触。 此外,目前公开的主题包括制备本发明的可生物降解支架的方法。

    Antioxidants And Recording Media By Using The Same
    4.
    发明申请
    Antioxidants And Recording Media By Using The Same 有权
    抗氧化剂和记录媒体使用它

    公开(公告)号:US20070273716A1

    公开(公告)日:2007-11-29

    申请号:US11578243

    申请日:2005-04-28

    摘要: “A high-molecular compound or high-molecular antioxidant obtained by reacting at least three compounds of (A) a sulfur-containing organic compound having at least two active hydrogen atoms, (B) a polyisocyanate compound having at least two isocyanate groups and (C) an amine compound having at least two active hydrogen atoms and then cationizing with an acid at least some of amino groups in a resultant reaction product” or “a high-molecular antioxidant obtained by reacting at least three compounds of (A) a sulfur-containing organic compound having at least two active hydrogen atoms, (B) a polyisocyanate compound having at least two isocyanate groups and (E) a nonionic polyol compound having at least two active hydrogen atoms” and a recording medium obtained by using the high-molecular antioxidant. The present invention provides a recording medium, which effectively prevents discoloration or color fading of images by acidic gas in the atmosphere and light and also migration of the images at high temperature and high humidity, and therefore, is suited for the long-term storage of the images.

    摘要翻译: “(A)具有至少两个活性氢原子的含硫有机化合物的至少三种化合物,(B)具有至少两个异氰酸酯基的多异氰酸酯化合物和( C)具有至少两个活性氢原子的胺化合物,然后在所得反应产物中用酸至少一些氨基进行阳离子化“或”通过使至少三种(A)硫化合物反应获得的高分子量抗氧化剂 (B)具有至少两个异氰酸酯基的多异氰酸酯化合物和(E)具有至少两个活性氢原子的非离子多元醇化合物,以及通过使用高分子量聚合物获得的记录介质, 分子抗氧化剂。 本发明提供了一种记录介质,其有效地防止了大气中的酸性气体和光的图像的变色或褪色以及图像在高温和高湿度下的迁移,因此适用于长期储存 图像。

    Plastic lenses for spectacles
    5.
    发明授权
    Plastic lenses for spectacles 有权
    眼镜塑料镜片

    公开(公告)号:US07091301B2

    公开(公告)日:2006-08-15

    申请号:US10854639

    申请日:2004-05-27

    申请人: Masahisa Kosaka

    发明人: Masahisa Kosaka

    IPC分类号: C08G18/52

    摘要: Plastic lenses for spectacles having a high refractive index and a high Abbe's number, and having good transparency, heat resistance, mechanical strength and impact resistance are produced. Plastic lenses for spectacles are produced through polymerization of an epithio group-having compound (a), a polythiol compound (b) and a polyisocyanate compound (c) whereby the ratio (by mol) of the polythiol compound (b) to the polyisocyanate compound (c) is at least 1.2 calculated on the basis of —SH and —NCO groups. The invention also provides a process for preparing such lenses and a catalyst for use in said process.

    摘要翻译: 制造具有高折射率和高阿贝数的眼镜的塑料透镜,并且具有良好的透明性,耐热性,机械强度和抗冲击性。 用于眼镜的塑料镜片是通过具有环硫基的化合物(a),多硫醇化合物(b)和多异氰酸酯化合物(c)的聚合制备的,其中多硫醇化合物(b)与多异氰酸酯化合物 (c)基于-SH和-NCO基计算为至少1.2。 本发明还提供了制备这种透镜的方法和用于所述方法的催化剂。

    Clear coating composition for clear coat/color coat finish
    8.
    发明授权
    Clear coating composition for clear coat/color coat finish 失效
    透明涂层组合物用于透明涂层/彩涂层

    公开(公告)号:US5314953A

    公开(公告)日:1994-05-24

    申请号:US115851

    申请日:1993-09-08

    摘要: A improved process for applying a clear coat/color coat composition to a substrate in which a color coat is applied to a substrate and then a clear coat is applied over the color coat; the improvement used therewith is a clear coating composition having a film forming binder solids content of about 30-70% by weight and an organic liquid carrier, wherein the binder contains about(A) 50-80% by weight, based on the weight of the binder, of an acrylic polymer of polymerized monomers of styrene, a methacrylate monomer from the group of methyl methacrylate, isobornyl methacrylate, cyclohexyl methacrylate or any mixtures thereof, a second methacrylate monomer from the group of n-butyl methacrylate, isobutyl methacrylate or ethyl hexyl methacrylate or any mixtures thereof and a hydroxy alkyl methacrylate or acrylate each having 1-4 carbon atoms in the alkyl group, where the polymer has a number average molecular weight of about 5,000-20,000 determined by gel permeation chromatography and a calculated Tg of at least 40.degree. C. and correspondingly,(B) 20-50% by weight, based on the weight of the binder, of an organic polyisocyanate;wherein the clear coating composition on curing is in a tack free state within 3 hours after application and has a Persoz hardness of at least 30 counts.

    摘要翻译: 将透明涂层/彩色涂层组合物施加到基材上的改进方法,其中将彩色涂层施加到基材上,然后在彩色涂层上施加透明涂层; 使用的改进是具有约30-70重量%的成膜粘合剂固含量的有机液体载体的透明涂料组合物,其中粘合剂含有约(A)50-80重量%,基于 苯乙烯聚合单体的丙烯酸聚合物,甲基丙烯酸甲酯的甲基丙烯酸酯单体,甲基丙烯酸异冰片酯,甲基丙烯酸环己酯或其任何混合物的丙烯酸类聚合物的粘合剂,来自甲基丙烯酸正丁酯,甲基丙烯酸异丁酯或甲基丙烯酸异丁酯 甲基丙烯酸己酯或其任何混合物和在烷基中各自具有1-4个碳原子的甲基丙烯酸羟烷基酯或丙烯酸酯,其中聚合物通过凝胶渗透色谱测定的数均分子量为约5,000-20,000,计算出的Tg在 至少40℃,相应地,(B)基于粘合剂重量的20-50重量%的有机多异氰酸酯; 其中固化后的透明涂料组合物在施用后3小时内处于无粘性状态,并且具有至少30个计数的Persoz硬度。

    Isocyanate cured polysulphide polymers
    9.
    发明授权
    Isocyanate cured polysulphide polymers 失效
    异氰酸酯固化聚硅氧烷聚合物

    公开(公告)号:US5212231A

    公开(公告)日:1993-05-18

    申请号:US839517

    申请日:1992-02-20

    申请人: Clive Woollard

    发明人: Clive Woollard

    摘要: A polysulphide resin composition is cured by reacting a liquid polysulphide resin with an isocyanate curing agent in the presence of an organometallic or metal salt catalyst, preferably an organotin catalyst such as dibutyltin laurate (DBTL). The compositions have utility in thin films and coatings, and in the bonding, sealing and coating of polycarbonates. Aliphatic isocyanates are preferred for applications where clear coatings are required, the more reactive aromatic isocyanates being preferred for other applications.