Melt spun thermoplastic polyurethanes useful as textile fibers
    3.
    发明授权
    Melt spun thermoplastic polyurethanes useful as textile fibers 失效
    用作纺织纤维的熔融热塑性聚氨酯

    公开(公告)号:US07015299B2

    公开(公告)日:2006-03-21

    申请号:US09843749

    申请日:2001-04-30

    摘要: Melt spun thermoplastic polyurethane polymers useful as textile fibers and having good tenacity and recovery and substantially no gelation are disclosed. The polymers are prepared by a three-step polymerization process including: preparation of “hard” segment oligomer, preparation of “soft” segment oligomer and final reaction of “hard” segment with “soft” segment in a twin-screw reaction extruder to obtain a final polyurethane product having relatively uniform distances between the “hard” segments. The “soft” segment oligomer comprises blocks of polymeric glycol (poly) urethanes end capped with isocyanate groups. The “hard” segment oligomer comprises blocks of low molecular weight C2–C6 glycol (poly) urethanes.

    摘要翻译: 可用作纺织纤维的熔融热塑性聚氨酯聚合物并且具有良好的韧性和回收率并且基本上没有凝胶化。 通过三步聚合方法制备聚合物,包括:制备“硬”链段低聚物,在双螺杆反应挤出机中制备“软”链段低聚物和“硬”链段与“软”链段的最终反应以获得 最终的聚氨酯产品在“硬”段之间具有相对均匀的距离。 “软”链段低聚物包含用异氰酸酯基封端的聚合二醇(聚)聚氨酯嵌段。 “硬”段低聚物包含低分子量C 2 -C 6 - 二醇(聚)氨基甲酸酯的嵌段。

    Spandex of a particular composition and process for making same
    4.
    发明授权
    Spandex of a particular composition and process for making same 有权
    特定组合物的氨纶和其制造方法

    公开(公告)号:US06984708B2

    公开(公告)日:2006-01-10

    申请号:US10264742

    申请日:2002-10-04

    IPC分类号: C08G18/65

    摘要: The invention provides spandex having improved hysteresis and a method for making such spandex. The spandex of the invention comprises the polyurethaneurea reaction product of: (a) poly(tetramethylene ether) glycol (b) 1-isocyanato-4-[(4-isocyanatophenyl)methyl]benzene wherein the mole ratio of diisocyanate to glycol is from about 1.52 to about 2.04; and (c) a mixture of chain extenders comprising: from about 35 to about 55 mole percent ethylene diamine; and from about 45 to about 65 mole percent 1,2-propanediamine.

    摘要翻译: 本发明提供具有改善的滞后的氨纶和制造这种氨纶的方法。 本发明的氨纶包含聚氨酯脲反应产物:(a)聚(四亚甲基醚)二醇(b)1-异氰酸酯基-4 - [(4-异氰酸基苯基)甲基]苯,其中二异氰酸酯与二醇的摩尔比为约 1.52至约2.04; 和(c)增链剂的混合物,其包含:约35至约55摩尔%的乙二胺; 和约45至约65摩尔%的1,2-丙二胺。

    Polyurethane composition
    5.
    发明授权
    Polyurethane composition 失效
    聚氨酯组合物

    公开(公告)号:US06956074B1

    公开(公告)日:2005-10-18

    申请号:US09529717

    申请日:1999-08-19

    摘要: There is a provided a polyurethane composition, which exhibits an excellent property of preventing discoloring or coloring not only by oxidized nitrogen gases but also by heat, characterized in that (A) a hindered phenol antioxidant, and (B) an amide represented by the following general formula (I): R1—CONH2  (I) wherein R1 represents an alkyl group having 12 to 21 carbon atoms is compounded in the polyurethane.

    摘要翻译: 提供了一种聚氨酯组合物,其不仅通过氧化氮气而且通过加热表现出优异的防变色性,其特征在于(A)受阻酚抗氧化剂和(B)由下列物质表示的酰胺 通式(I):<?in-line-formula description =“In-line Formulas”end =“lead”?> R&lt; 1&gt; -CONH 2(I) 其中R 1表示具有12〜21个碳原子的烷基,在聚氨酯中配合<?in-line-formula description =“In-line Formulas”end =“tail”?

    Polyester diol, polyurethane obtained therefrom and spandex filament thereof and a novel dialkylamino group-contained acrylic-based copolymer, polyurethane composition and spandex composition
    7.
    发明申请
    Polyester diol, polyurethane obtained therefrom and spandex filament thereof and a novel dialkylamino group-contained acrylic-based copolymer, polyurethane composition and spandex composition 审中-公开
    聚酯二醇,由其获得的聚氨酯和氨纶丝以及新的含二烷基氨基的丙烯酸类共聚物,聚氨酯组合物和氨纶组合物

    公开(公告)号:US20040171768A1

    公开(公告)日:2004-09-02

    申请号:US10799405

    申请日:2004-03-11

    发明人: Takuya Miho

    IPC分类号: C08G071/04

    摘要: The present invention Nos. 1-3 provide a spandex filament which is excellent in view of a recovering ability of elasticity, high tensile strength, and hydrolysis resistance, and a polyurethane which can provide thereof and, further, a polyester polyester diol obtained from a specified diol. Further, the present invention No. 4 provides a polyester polyol containing a polyol having an ultraviolet ray-absorbable group, a lactone-modified polyol therefrom, and a polyester polyol containing other polyol components and adipic acid as constructing component units, and provides a polyurethane having washing resistance obtained therefrom and, further provides a spandex filament comprising the polyurethane. The present invention No. 5 provides a dialkyl amino group-contained additive having a high solubility to a DMAc solvent which protects a spandex polymer from deterioration or discoloration, and which is employed for a spandex polymer having an improved permanent extension property, and a polyurethane composition and a spandex composition having an improved permanent extension property. Still further, the present invention No. 6 provides a polyurethane having a soft feeling, an excellent hydrolysis resistance, a wrinkle resistance, and an adhesive property, and which is particularly excellent as an artificial leather.

    摘要翻译: 本发明1-3中提供了一种氨纶丝,其具有弹性回复性,抗拉强度和耐水解性的优异性和可以提供聚氨酯的氨基甲酸酯,此外,还提供了由 指定的二醇。 此外,本发明4提供了含有具有紫外线吸收基团的多元醇,其内酯改性多元醇和含有其它多元醇成分的聚酯多元醇和己二酸作为构成成分单元的聚酯多元醇,并提供聚氨酯 具有由其获得的耐洗涤性,并且还提供包含聚氨酯的氨纶丝。 本发明No.5提供了对DMAc溶剂具有高溶解性的二烷基氨基添加剂,其保护氨纶聚合物不会劣化或变色,并且其用于具有改善的永久延伸性能的氨纶聚合物和聚氨酯 组合物和具有改进的永久延伸性质的氨纶组合物。 此外,本发明6提供了具有柔软感,耐水解性,耐皱纹性和粘合性的聚氨酯,并且作为人造革特别优异。

    Polyurethane/ureas useful for the production of spandex and a process for their production
    8.
    发明申请
    Polyurethane/ureas useful for the production of spandex and a process for their production 失效
    用于生产氨纶的聚氨酯/尿素及其生产工艺

    公开(公告)号:US20030225241A1

    公开(公告)日:2003-12-04

    申请号:US10158762

    申请日:2002-05-30

    IPC分类号: C08G018/00 C08G018/10

    摘要: Segmented polyurethane/ureas useful in the production of spandex are produced by chain extending an isocyanate-terminated prepolymer with a diamine chain extender that includes: (1) from about 7 to 25 equivalent percent of an asymmetric aliphatic and/or cycloaliphatic diamine and (2) a linear diamine such as ethylene diamine in the presence of a solvent. The isocyanate-terminated prepolymer is produced by reacting a stoichiometric excess of an isocyanate with an isocyanate-reactive component that includes: (1) from about 10 to about 70 equivalent percent of a polyoxypropylene diol having a molecular weight in excess of 1500 Da and an average unsaturation level no greater than about 0.03 meq/g and (2) from about 30 to about 90 equivalent percent of a polytetramethylene ether glycol having a molecular weight of at least 600 Da.

    摘要翻译: 用于生产氨纶的分段聚氨酯/尿素是通过用二胺扩链剂链延伸异氰酸酯封端的预聚物来制备的,其包括:(1)约7至25当量%的不对称脂族和/或脂环族二胺和(2 )线性二胺如乙二胺在溶剂存在下进行。 异氰酸酯封端的预聚物通过使化学计量过量的异氰酸酯与异氰酸酯反应性组分反应而制备,所述组分包括:(1)约10至约70当量的分子量超过1500Da的聚氧丙烯二醇和 平均不饱和度不大于约0.03meq / g,(2)约30至约90当量分子量至少为600Da的聚四亚甲基醚二醇。

    Polyurethane/ureas useful for the production of spandex and a process for their production
    9.
    发明授权
    Polyurethane/ureas useful for the production of spandex and a process for their production 失效
    用于生产氨纶的聚氨酯/尿素及其生产工艺

    公开(公告)号:US06624281B1

    公开(公告)日:2003-09-23

    申请号:US10158616

    申请日:2002-05-30

    申请人: Bruce D. Lawrey

    发明人: Bruce D. Lawrey

    IPC分类号: C08G1810

    摘要: Segmented polyurethane/ureas useful for the production of spandex are produced by chain extending, in the presence of a solvent, an isocyanate-terminated prepolymer prepared by reacting a stoichiometric excess of an isocyanate with an isocyanate-reactive component which includes: (1) from about 5 to about 30 equivalent percent of a polyoxy-propylene diol having a molecular weight of at least 1500 Da and an unsaturation level less than or equal to 0.03 meq/g; (2) from about 20 to about 60 equivalent percent of a polytetramethylene ether glycol having a molecular weight less than 1000 Da; and (3) from about 25 to about 65 equivalent percent of a polytetramethylene ether glycol having a molecular weight greater than or equal to 1000 Da.

    摘要翻译: 可用于生产氨纶的分段聚氨酯/尿素通过在溶剂存在下通过使化学计量过量的异氰酸酯与异氰酸酯反应性组分反应制备的异氰酸酯封端的预聚物链延伸生产,所述异氰酸酯封端的预聚物包括:(1) 约5至约30当量的分子量至少为1500Da且不饱和度小于或等于0.03meq / g的聚氧丙烯二醇; (2)约20至约60当量%的分子量小于1000Da的聚四亚甲基醚二醇; 和(3)约25至约65当量%的分子量大于或等于1000Da的聚四亚甲基醚二醇。