POWDER COATING COMPOSITIONS CROSS-LINKED WITH NON CYANURATE POLYEPOXIDES
    2.
    发明申请
    POWDER COATING COMPOSITIONS CROSS-LINKED WITH NON CYANURATE POLYEPOXIDES 审中-公开
    与非氰基多羟基氧化物交联的粉末涂料组合物

    公开(公告)号:US20120004373A1

    公开(公告)日:2012-01-05

    申请号:US12063609

    申请日:2008-02-12

    IPC分类号: C09D167/00

    摘要: The present invention relates to powder coating compositions and to components and ingredients for incorporation therein, suitable for fast curing schedule and with excellent resistance to outside aging. Non-isocyanurate polyepoxide cross-linking reagents can be used, provided the nature of the carboxylated polyester resin is formed of at least 30 mole % aromatic acid and the chain of the carboxyl terminated polyester also incorporates a moiety derived from 1,4 cyclohexanedicarboxylic acid. The powder coating composition can be cured for 90 seconds at a temperature of 250° C. or 55 seconds at 270° C. or 20 seconds in an induction oven at a temperature of 300° C. in the presence of a catalyst.

    摘要翻译: 本发明涉及粉末涂料组合物以及用于掺入其中的组分和成分,适用于快速固化时间表和优异的耐老化性。 可以使用非异氰脲酸酯聚环氧化物交联剂,只要羧化聚酯树脂的性质由至少30摩尔%的芳族酸形成,并且羧基封端的聚酯的链也包含衍生自1,4-环己烷二羧酸的部分。 在催化剂存在下,粉末涂料组合物可以在250℃的温度下或在270℃下在55℃下或在感应炉中在300℃的温度下固化20秒。

    HEAT CURABLE POWDER COATING COMPOSITION
    4.
    发明申请
    HEAT CURABLE POWDER COATING COMPOSITION 审中-公开
    热固化粉末涂料组合物

    公开(公告)号:US20090186973A1

    公开(公告)日:2009-07-23

    申请号:US12015763

    申请日:2008-01-17

    IPC分类号: C08K3/10 B05D3/00 C09K3/00

    摘要: The invention is directed to a heat curable powder coating composition comprising a polymer comprising functional groups capable of reacting with a β-hydroxyalkylamide unit, a crosslinker comprising β-hydroxyalkylamide units, a first additive comprising a transition-metal cation and a second additive comprising an halogenide anion selected from a iodide or a bromide anion or a combination thereof wherein the halogenide anion is present in a molar excess relative to the transition-metal cation.Under elevated heat conditions a coating obtained from such a composition shows less yellowing. The invention also relates to a process for manufacturing a coated substrate, to a coated substrate and to the use of the first and second additive. The invention further relates to a crosslinker composition and to a polymer composition.

    摘要翻译: 本发明涉及一种可热固化的粉末涂料组合物,其包括含有能与β-羟基烷基酰胺单元反应的官能团的聚合物,包含β-羟烷基酰胺单元的交联剂,包含过渡金属阳离子的第一添加剂和第二添加剂, 选自碘化物或溴化阴离子的卤化物阴离子或其组合,其中卤化物阴离子相对于过渡金属阳离子以摩尔过量存在。 在升高的热条件下,由这种组合物获得的涂层显示较少的黄化。 本发明还涉及一种用于制造涂覆的基材,涂覆的基材以及第一和第二添加剂的使用的方法。 本发明还涉及交联剂组合物和聚合物组合物。

    Production of Coated Substrates
    5.
    发明申请
    Production of Coated Substrates 有权
    涂层基材的生产

    公开(公告)号:US20080292799A1

    公开(公告)日:2008-11-27

    申请号:US12092084

    申请日:2006-08-10

    IPC分类号: B05D3/02

    摘要: The present invention relates to a process for coating substrates, which comprises the steps: a) provision of a substrate, b) application of a composition to at least one surface of the substrate, the composition comprising a silane of the general formula (Z1)Si(OR3), where Z1 is OR or Gly (Gly=3-glycidyloxypropyl) and R is an alkyl radical having from 1 to 6 carbon atoms and all radicals R can be identical or different, an inert solvent and an initiator and the inert solvent having a boiling point under the drying conditions of step c) which is in a range from 50° C. above to 50° C. below the drying temperature of step c) and the boiling point of the inert solvent under the drying conditions of step c) being at least 80° C., and c) drying of the composition applied in step b) at a drying temperature of from 100° C. to 250° C., and also to a coated substrate obtainable by means of the abovementioned process.

    摘要翻译: 本发明涉及一种用于涂覆基材的方法,其包括以下步骤:a)提供基材,b)将组合物施用于基材的至少一个表面,所述组合物包含通式(Z1)的硅烷, Si(OR 3),其中Z 1为OR或Gly(Gly = 3-缩水甘油氧基丙基),R为具有1至6个碳原子的烷基,所有基团R可以相同或不同,惰性溶剂和引发剂和惰性 在步骤c)的干燥条件下具有沸点的溶剂在低于步骤c)的干燥温度的50℃以上至50℃的范围内,并且在干燥条件下的惰性溶剂的沸点 步骤c)为至少80℃,和c)在100℃至250℃的干燥温度下干燥步骤b)中所用的组合物,并且还可以通过使用 上述过程。

    Two-component coating composition and method of preparation
    6.
    发明授权
    Two-component coating composition and method of preparation 失效
    双组分涂料组合物及其制备方法

    公开(公告)号:US07396891B2

    公开(公告)日:2008-07-08

    申请号:US11050271

    申请日:2005-02-03

    IPC分类号: C08F20/06

    摘要: Aqueous coating compositions containing (1) a first polymer containing reactive functional groups with a selected level of carboxylic acid functionality and (2) a polyfunctional crosslinker agent containing functional groups that are reactive with appropriate functional groups of the first polymer, are disclosed. The two-component polymer compositions provide a combination of durability and ready removability of the final coating after curing. Two-component polymer compositions based on the first polymer containing hydroxyl functionality in addition to carboxylic acid functionality and use of a polyisocyanate as the polyfunctional crosslinker agent are especially useful as floor polish compositions.

    摘要翻译: 公开了含有(1)含有选定水平的羧酸官能团的反应性官能团的第一聚合物的水性涂料组合物和(2)含有与第一聚合物的适当官能团反应的官能团的多官能交联剂。 双组分聚合物组合物提供固化后的最终涂层的耐久性和即时可除去性的组合。 除了羧酸官能团之外,基于含有羟基官能团的第一聚合物和使用多异氰酸酯作为多官能交联剂的双组分聚合物组合物特别可用作地板抛光组合物。

    Method of providing cured coating films free of popping defects
    7.
    发明授权
    Method of providing cured coating films free of popping defects 有权
    提供没有突出缺陷的固化涂膜的方法

    公开(公告)号:US07205029B2

    公开(公告)日:2007-04-17

    申请号:US10261888

    申请日:2002-09-30

    IPC分类号: B05D3/00

    摘要: A method for providing cured coating films free of popping defects. The method requires the application to a substrate of at least 2.0 mils/50.8 microns of a uncured curable coating composition comprising an anti-popping component (a), a film-forming component (b), and a crosslinking component (c), wherein anti-popping component (a) has from 12 to 72 carbon atoms, is substantially free of any heteroatoms, is not a crystalline solid at room temperature and comprises a mixture of two or more structures selected from the group consisting of aliphatic structures for anti-popping component (a), aromatic-containing structures for anti-popping component (a), cycloaliphatic-containing structures for anti-popping component (a), and mixtures thereof, at least one of the two or more structures being a cycloaliphatic-containing structure or an aromatic-containing structure. The coated uncured substrate is cured to provide a cured film free of popping defects with an average film build of at least 2.0 mils/50.8 microns.

    摘要翻译: 提供没有突出缺陷的固化涂膜的方法。 该方法需要施用至少2.0密耳/ 50.8微米的包含抗爆组分(a),成膜组分(b)和交联组分(c)的未固化的可固化涂料组合物的基材,其中 抗突起组分(a)具有12至72个碳原子,基本上不含任何杂原子,在室温下不是结晶固体,并且包含两种或更多种选自以下的结构的混合物:脂肪族结构, 弹性组分(a),用于抗爆组分(a)的含芳族化合物的结构,用于抗爆组分(a)的含脂环族的结构及其混合物,所述两种或多种结构中的至少一种是含脂环族的 结构或含芳族结构。 固化涂覆的未固化基底以提供没有突出缺陷的固化膜,其平均膜构成为至少2.0密耳/ 50.8微米。

    Curable compositions comprising reactive beta-hydroxyamides from lactones
    8.
    发明申请
    Curable compositions comprising reactive beta-hydroxyamides from lactones 审中-公开
    包含来自内酯的反应性β-羟基酰胺的可固化组合物

    公开(公告)号:US20070010651A1

    公开(公告)日:2007-01-11

    申请号:US11480739

    申请日:2006-07-03

    IPC分类号: C08G69/08

    摘要: According to the present invention, curable compositions comprising (i) one or more polyacid containing at least two carboxylic acid groups, anhydride groups, or salts thereof; (ii), optionally, one or more polyol containing at least two hydroxyl groups; and (iii) one or more reactive β-hydroxyamide group containing polyol, which is the reaction product of a lactone or cyclic ester and an alkanolamine, of the following formula (I): in which, R and R″ independently represent H, or any monovalent C1 to C18 linear or branched alkyl radical, which radical may comprise one or two aryl or cycloalkyl group, one or more hydroxyl, amine, thiol, amide, carboxyl or alkenyl group, or combinations thereof; R′ represents either a covalent bond or a divalent C1 to C5 alkylene radical where the alkylene radical may bear alkyl group substituents; y is the integer 1 or 2; x is 0 or 1, such that (x+y)=2; wherein the ratio of the number of equivalents of said carboxylic acid groups, anhydride groups, or salts thereof to the number of equivalents of said hydroxyl groups is from 1/0.01 to 1/3. The curable compositions of the present invention provide less corrosive, low energy curing binders. Further, the present invention provides methods to use the compositions as aqueous binders for composites, nonwoven and woven substrates, and the products produced thereby.

    摘要翻译: 根据本发明,可固化组合物包含(i)一种或多种含有至少两个羧酸基团的多酸,酸酐基团或其盐; (ii)任选的一种或多种含有至少两个羟基的多元醇; 和(iii)一种或多种下式(I)的含有内酯或环酯与链烷醇胺的反应产物的反应性β-羟基酰胺基多元醇:其中R和R'独立地表示H, 或任何一价C 1至C 18直链或支链烷基,该基团可以包含一个或两个芳基或环烷基,一个或多个羟基,胺,硫醇,酰胺 ,羧基或烯基,或它们的组合; R'表示亚烷基可以具有烷基取代基的共价键或二价C 1至C 5亚烷基; y是整数1或2; x为0或1,使得(x + y)= 2; 其中所述羧酸基团,酸酐基团或其盐的当量数与所述羟基的当量数之比为1 / 0.01至1/3。 本发明的可固化组合物提供较少腐蚀性的低能量固化粘合剂。 此外,本发明提供了将组合物用作复合材料,无纺布和编织基材的水性粘合剂的方法,以及由此制备的产品。

    CATIONIC EMULSION COMPOSITION OF HIGH POLYMERIC ORGANOSILOXANE AND PREPARATION THEREOF
    9.
    发明申请
    CATIONIC EMULSION COMPOSITION OF HIGH POLYMERIC ORGANOSILOXANE AND PREPARATION THEREOF 有权
    高分子有机硅氧烷的阳离子乳液组合物及其制备方法

    公开(公告)号:US20060270789A1

    公开(公告)日:2006-11-30

    申请号:US11421218

    申请日:2006-05-31

    申请人: Yoshihito OSAWA

    发明人: Yoshihito OSAWA

    IPC分类号: C08G77/06

    摘要: A high polymeric organosiloxane cationic emulsion composition comprising (A) a polydiorganosiloxane of formula: HO-[R2SiO]n-H wherein R is an organic group and n is a number to give a viscosity of at least 300 Pa-s at 25° C., (B) a cationic surfactant of formula: Q3(CH3)N+.X−wherein Q is an organic group and X is halogen or carboxyl, and (C) water is fully stable. It is prepared by dispersing a corresponding organosiloxane and the cationic surfactant in water to form an emulsion, polymerizing in the presence of an alkali catalyst at 0-90° C. for 10-150 hours, and neutralizing with an acidic compound.

    摘要翻译: 一种高聚合有机硅氧烷阳离子乳液组合物,其包含(A)如下式的聚二有机硅氧烷:HO- [R 2 SiO] n -H 数量,以在25℃下产生至少300Pa·s的粘度,(B)式:Q 3(CH 3 3)N SUP的阳离子表面活性剂 其中Q是有机基团,X是卤素或羧基,(C)水是完全稳定的。 通过将相应的有机硅氧烷和阳离子表面活性剂分散在水中以形成乳液,在0-90℃下在碱催化剂存在下聚合10-150小时,并用酸性化合物中和而制备。

    FLAME RETARDANT ADHESIVE COMPOSITION, AND ADHESIVE SHEET, COVERLAY FILM AND FLEXIBLE COPPER-CLAD LAMINATE USING SAME
    10.
    发明申请
    FLAME RETARDANT ADHESIVE COMPOSITION, AND ADHESIVE SHEET, COVERLAY FILM AND FLEXIBLE COPPER-CLAD LAMINATE USING SAME 审中-公开
    阻燃粘合剂组合物,粘合片,覆盖膜和使用相同的柔性铜箔层压板

    公开(公告)号:US20060264538A1

    公开(公告)日:2006-11-23

    申请号:US11419648

    申请日:2006-05-22

    IPC分类号: C08L63/00 C08K5/51

    摘要: Provided is a flame retardant adhesive composition including (A) a halogen-free epoxy resin, (B) a thermoplastic resin and/or a synthetic rubber, (C) a curing agent, (D) an organophosphinate compound, (E) a curing accelerator, and (F) a nitrogen-containing organophosphate compound represented by a general formula (1) shown below: (wherein, R1 to R4 each represent a hydrogen atom or an alkyl group, and X represents a nitrogen-containing bivalent organic group) Also provided are an adhesive sheet having a layer comprising the above composition, and a protective layer for covering the layer comprising the composition; a coverlay film having an electrically insulating film, and a layer comprising the above composition provided on top of the film; and a flexible copper-clad laminate having an electrically insulating film, a layer comprising the above composition provided on top of the film, and a copper foil provided on top of the layer comprising the composition. Further provided are a process for producing the adhesive sheet, a process for producing the coverlay film, and a process for producing the flexible copper-clad laminate. The halogen-free adhesive composition yields a cured product, on curing, that exhibits excellent flame retardancy and electrical characteristics (anti-migration properties). The composition can be used for producing an adhesive sheet, a coverlay film, and a flexible copper-clad laminate.

    摘要翻译: 本发明提供阻燃性粘合剂组合物,其包含(A)无卤环氧树脂,(B)热塑性树脂和/或合成橡胶,(C)固化剂,(D)有机基膦酸盐化合物,(E) 促进剂,和(F)由下述通式(1)表示的含氮有机磷酸酯化合物:其中R 1至R 4各自表示氢原子 或烷基,X表示含氮二价有机基团)还提供了具有包含上述组成的层的粘合片和用于覆盖包含该组合物的层的保护层; 具有电绝缘膜的覆盖层膜和设置在膜顶部的包含上述组成的层; 以及具有电绝缘膜的柔性覆铜层压板,设置在膜顶部的上述组成的层和设置在包含该组合物的层的顶部上的铜箔。 还提供了粘合片的制造方法,覆盖膜的制造方法以及制造柔性覆铜层压体的方法。 无卤粘合剂组合物在固化时产生固化产物,其表现出优异的阻燃性和电特性(抗迁移性)。 该组合物可用于生产粘合片,覆盖膜和柔性覆铜层压板。