FLAME RETARDANT ADHESIVE COMPOSITION, AND ADHESIVE SHEET, COVERLAY FILM AND FLEXIBLE COPPER-CLAD LAMINATE USING SAME
    4.
    发明申请
    FLAME RETARDANT ADHESIVE COMPOSITION, AND ADHESIVE SHEET, COVERLAY FILM AND FLEXIBLE COPPER-CLAD LAMINATE USING SAME 审中-公开
    阻燃粘合剂组合物,粘合片,覆盖膜和使用相同的柔性铜箔层压板

    公开(公告)号:US20060264538A1

    公开(公告)日:2006-11-23

    申请号:US11419648

    申请日:2006-05-22

    IPC分类号: C08L63/00 C08K5/51

    摘要: Provided is a flame retardant adhesive composition including (A) a halogen-free epoxy resin, (B) a thermoplastic resin and/or a synthetic rubber, (C) a curing agent, (D) an organophosphinate compound, (E) a curing accelerator, and (F) a nitrogen-containing organophosphate compound represented by a general formula (1) shown below: (wherein, R1 to R4 each represent a hydrogen atom or an alkyl group, and X represents a nitrogen-containing bivalent organic group) Also provided are an adhesive sheet having a layer comprising the above composition, and a protective layer for covering the layer comprising the composition; a coverlay film having an electrically insulating film, and a layer comprising the above composition provided on top of the film; and a flexible copper-clad laminate having an electrically insulating film, a layer comprising the above composition provided on top of the film, and a copper foil provided on top of the layer comprising the composition. Further provided are a process for producing the adhesive sheet, a process for producing the coverlay film, and a process for producing the flexible copper-clad laminate. The halogen-free adhesive composition yields a cured product, on curing, that exhibits excellent flame retardancy and electrical characteristics (anti-migration properties). The composition can be used for producing an adhesive sheet, a coverlay film, and a flexible copper-clad laminate.

    摘要翻译: 本发明提供阻燃性粘合剂组合物,其包含(A)无卤环氧树脂,(B)热塑性树脂和/或合成橡胶,(C)固化剂,(D)有机基膦酸盐化合物,(E) 促进剂,和(F)由下述通式(1)表示的含氮有机磷酸酯化合物:其中R 1至R 4各自表示氢原子 或烷基,X表示含氮二价有机基团)还提供了具有包含上述组成的层的粘合片和用于覆盖包含该组合物的层的保护层; 具有电绝缘膜的覆盖层膜和设置在膜顶部的包含上述组成的层; 以及具有电绝缘膜的柔性覆铜层压板,设置在膜顶部的上述组成的层和设置在包含该组合物的层的顶部上的铜箔。 还提供了粘合片的制造方法,覆盖膜的制造方法以及制造柔性覆铜层压体的方法。 无卤粘合剂组合物在固化时产生固化产物,其表现出优异的阻燃性和电特性(抗迁移性)。 该组合物可用于生产粘合片,覆盖膜和柔性覆铜层压板。

    Flame retardant adhesive composition, and adhesive sheet, coverlay film and flexible copper-clad laminate using same
    5.
    发明申请
    Flame retardant adhesive composition, and adhesive sheet, coverlay film and flexible copper-clad laminate using same 审中-公开
    阻燃粘合剂组合物,粘合片,覆盖膜和使用其的柔性覆铜层压板

    公开(公告)号:US20060234045A1

    公开(公告)日:2006-10-19

    申请号:US11402063

    申请日:2006-04-12

    IPC分类号: B32B7/12 B32B3/00

    摘要: Provided is a flame retardant adhesive composition including (A) a halogen-free epoxy resin, (B) a thermoplastic resin and/or a synthetic rubber, (C) a curing agent, (D) an organophosphinate compound, and (E) a curing accelerator. Also provided are an adhesive sheet having a layer including the above composition, and a protective layer for covering the layer including the composition; a coverlay film having an electrically insulating film, and a layer including the above composition provided on top of the film; and a flexible copper-clad laminate having an electrically insulating film, a layer including the above composition provided on top of the film, and copper foil. Further provided are a process for producing the adhesive sheet, a process for producing the coverlay film, and a process for producing the flexible copper-clad laminate. The halogen-free adhesive composition yields a cured product, on curing, that exhibits excellent flame retardancy and electrical characteristics (anti-migration properties). The composition can be used for producing an adhesive sheet, a coverlay film, and a flexible copper-clad laminate.

    摘要翻译: 本发明提供一种阻燃性粘合剂组合物,其包含(A)无卤素环氧树脂,(B)热塑性树脂和/或合成橡胶,(C)固化剂,(D)有机亚磷酸盐化合物和(E) 固化促进剂。 还提供了具有包含上述组合物的层的粘合片和用于覆盖包含该组合物的层的保护层; 具有电绝缘膜的覆盖层膜和设置在膜顶部的包含上述组合物的层; 以及具有电绝缘膜的柔性覆铜层压板,设置在膜顶部的上述组成的层和铜箔。 还提供了粘合片的制造方法,覆盖膜的制造方法以及制造柔性覆铜层压体的方法。 无卤粘合剂组合物在固化时产生固化产物,其表现出优异的阻燃性和电特性(抗迁移性)。 该组合物可用于生产粘合片,覆盖膜和柔性覆铜层压板。

    Acrylic flame retardant adhesive composition and acrylic flame retardant adhesive sheet
    7.
    发明申请
    Acrylic flame retardant adhesive composition and acrylic flame retardant adhesive sheet 审中-公开
    丙烯酸阻燃胶组合物和丙烯酸阻燃胶粘片

    公开(公告)号:US20060069201A1

    公开(公告)日:2006-03-30

    申请号:US11236525

    申请日:2005-09-28

    IPC分类号: C09B67/00

    摘要: Provided is an acrylic flame retardant adhesive composition, including: (A) 100 parts by mass of an acrylic polymer containing a carboxyl group, with a glass transition temperature of 5 to 30° C., (B) 1 to 20 parts by mass of a resol-type phenol resin, (C) 1 to 20 parts by mass of an epoxy resin, (D) 0.1 to 5 parts by mass of a curing accelerator, (E) a bromine-based flame retardant, in sufficient quantity to produce a bromine content within the entire composition, excluding the component (F), of 15 to 40% by mass, and (F) 10 to 100 parts by mass of an inorganic filler. Also provided are an acrylic adhesive sheet that contains an adhesive layer including this composition and a method of bonding two substrates using this acrylic adhesive sheet. The acrylic adhesive sheet exhibits excellent adhesiveness, heat resistance, workability, handling properties and flame retardancy, and the acrylic adhesive composition is useful in the production of such an adhesive sheet.

    摘要翻译: 本发明提供一种丙烯酸类阻燃剂粘合剂组合物,其包含:(A)100质量份含有羧基的丙烯酸类聚合物,玻璃化转变温度为5〜30℃,(B)1〜20质量份 (C)1〜20质量份环氧树脂,(D)0.1〜5质量份固化促进剂,(E)溴类阻燃剂,以足够的量生产 (F)以外的组合物中的溴含量为15〜40质量%,(F)10〜100质量份无机填料。 还提供了含有包含该组合物的粘合剂层的丙烯酸粘合片和使用该丙烯酸类粘合片粘接两片基板的方法。 丙烯酸粘合片表现出优异的粘合性,耐热性,可加工性,操作性和阻燃性,并且丙烯酸粘合剂组合物可用于生产这种粘合片。

    Acrylic adhesive composition and acrylic adhesive sheet
    8.
    发明申请
    Acrylic adhesive composition and acrylic adhesive sheet 审中-公开
    丙烯酸粘合剂组合物和丙烯酸粘合片

    公开(公告)号:US20060069200A1

    公开(公告)日:2006-03-30

    申请号:US11236515

    申请日:2005-09-28

    IPC分类号: C09B67/00

    CPC分类号: H05K3/386 H05K1/0393

    摘要: Provided is an acrylic adhesive composition, including: (A) 100 parts by mass of an acrylic polymer containing a carboxyl group, with a glass transition temperature of 5 to 30° C., (B) 1 to 20 parts by mass of a resol-type phenol resin, (C) 1 to 20 parts by mass of an epoxy resin, and (D) 10 to 100 parts by mass of an inorganic filler, the composition optionally including 0 to 0.5 parts by mass of a curing accelerator per 100 parts by mass of the component (A). Also provided are an acrylic adhesive sheet that contains an adhesive layer including this composition and a method of bonding two substrates using this acrylic adhesive sheet. The acrylic adhesive sheet exhibits excellent adhesiveness, heat resistance, workability, handling properties and storage stability, and the acrylic adhesive composition is useful in the production of such an adhesive sheet.

    摘要翻译: 本发明提供一种丙烯酸类粘合剂组合物,其包括:(A)100质量份含有羧基的丙烯酸类聚合物,玻璃化转变温度为5〜30℃,(B)1〜20质量份的甲阶酚醛树脂 型酚醛树脂,(C)1〜20质量份环氧树脂,(D)10〜100质量份无机填料,组合物任选地包含0〜0.5质量份固化促进剂/ 100 质量份的(A)成分。 还提供了含有包含该组合物的粘合剂层的丙烯酸粘合片和使用该丙烯酸类粘合片粘接两片基板的方法。 丙烯酸粘合片表现出优异的粘合性,耐热性,可加工性,操作性能和储存稳定性,并且丙烯酸粘合剂组合物可用于生产这种粘合片。

    Flame retardant adhesive composition, and adhesive sheet, coverlay film and flexible copper-clad laminate using same
    9.
    发明授权
    Flame retardant adhesive composition, and adhesive sheet, coverlay film and flexible copper-clad laminate using same 失效
    阻燃粘合剂组合物,粘合片,覆盖膜和使用其的柔性覆铜层压板

    公开(公告)号:US07820741B2

    公开(公告)日:2010-10-26

    申请号:US11865355

    申请日:2007-10-01

    IPC分类号: H01B3/40

    摘要: The present invention provides a halogen-free, flame retardant adhesive composition that exhibits excellent anti-migration properties, not only within single layer structures, but also within multilayer structures of much higher density. The flame retardant adhesive composition according to the present invention comprises: (A) a halogen-free epoxy resin, (B) a carboxyl group-containing acrylic resin and/or a carboxyl group-containing acrylonitrile-butadiene rubber, (C) a curing agent, (E) a specific polyphosphoric acid-melamine-based compound salt and/or polyphosphoric acid-diamine compound salt, and (F) an ion scavenger and/or a heavy metal deactivator.

    摘要翻译: 本发明提供了一种无卤阻燃粘合剂组合物,其不仅在单层结构内,而且在高密度的多层结构内表现出优异的抗迁移性能。 根据本发明的阻燃粘合剂组合物包括:(A)无卤环氧树脂,(B)含羧基的丙烯酸树脂和/或含羧基的丙烯腈 - 丁二烯橡胶,(C)固化 试剂,(E)特定的多磷酸 - 三聚氰胺类化合物盐和/或多磷酸 - 二胺化合物盐,和(F)离子清除剂和/或重金属钝化剂。