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21.发明授权公开(公告)号：US09809527B2
公开(公告)日：2017-11-07
申请号：US14511195
申请日：2014-10-10
IPC分类号： C07C51/377 , C07C51/48 , B01J27/18 , B01J27/187 , B01J27/25 , C07C51/09 , C07C57/04 , A61F13/534 , C08F2/10 , B01J27/16 , B01J27/185 , B01J27/186 , B01J27/188 , B01J27/195 , B01J27/198 , B01J35/02 , B01J37/00 , B01J37/04 , B01J37/08 , C07C51/44 , A61F13/53
CPC分类号： C07C51/48 , A61F13/53 , A61F13/534 , A61F2013/530489 , A61F2013/530496 , B01J27/16 , B01J27/1806 , B01J27/1811 , B01J27/1817 , B01J27/1853 , B01J27/1856 , B01J27/186 , B01J27/187 , B01J27/188 , B01J27/195 , B01J27/198 , B01J27/25 , B01J35/023 , B01J37/0036 , B01J37/04 , B01J37/08 , C07C51/09 , C07C51/377 , C07C51/44 , C07C57/04 , C08F2/10
摘要： Processes for the catalytic dehydration of hydroxypropionic acid, hydroxypropionic acid derivatives, or mixtures thereof to acrylic acid, acrylic acid derivatives, or mixtures thereof with high yield and selectivity and without significant conversion to undesired side products, such as, acetaldehyde, propanoic acid, and acetic acid, are provided.
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22.发明授权公开(公告)号：US09516881B2
公开(公告)日：2016-12-13
申请号：US14000507
申请日：2012-12-17
申请人： SHOWA DENKO K.K.
发明人： So Miyaishi , Yasushi Kuroda , Yasuhiro Hosogi , Ding Li
IPC分类号： A01N59/16 , B01J27/122 , A01N59/20 , B01J21/06 , B01J23/72 , B01J37/03 , B01J35/00 , A01N55/02 , A61L9/01 , B01J27/055 , B01J27/135 , B01J27/25 , B01J31/38
CPC分类号： A01N59/16 , A01N55/02 , A01N59/20 , A61L9/01 , B01J21/063 , B01J23/72 , B01J27/055 , B01J27/122 , B01J27/135 , B01J27/25 , B01J31/38 , B01J35/004 , B01J37/033 , A01N25/08 , A01N2300/00
摘要： The Cu- and Ti-containing composition of the present invention contains titanium oxide having a rutile-type titanium oxide content of 15 mol % or more, and at least one divalent copper compound represented by the following formula (1). The Cu- and Ti-containing composition production method of the present invention is characterized by including stirring a mixture containing titanium oxide having a rutile-type titanium oxide content of 15 mol % or more, a divalent copper compound raw material represented by formula (2), water, and an alkaline compound, to thereby cause precipitation. The composition of the present invention exhibits excellent anti-viral property under light and in the dark, and excellent organic compound decomposition activity under light.
摘要翻译： 本发明的含有Cu和Ti的组合物含有金红石型氧化钛含量为15摩尔％以上的氧化钛和由下式（1）表示的至少一种二价铜化合物。 本发明的含有Cu和Ti的组合物的制造方法的特征在于，将含有金红石型氧化钛含量为15摩尔％以上的氧化钛的混合物，由式（2）表示的二价铜化合物原料 ），水和碱性化合物，从而引起沉淀。 本发明的组合物在光和黑暗下表现出优异的抗病毒性能，并且在光照下具有优异的有机化合物分解活性。
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公开(公告)号：US09505697B2
公开(公告)日：2016-11-29
申请号：US13839986
申请日：2013-03-15
发明人： Juan Esteban Velasquez , Janette Villalobos Lingoes , Dimitris Ioannis Collias , Jane Ellen Godlewski
IPC分类号： C07C51/02 , C07C51/48 , B01J27/18 , B01J27/187 , B01J27/25 , C07C51/377 , C07C51/09 , C07C57/04 , A61F13/534 , C08F2/10 , B01J27/16 , B01J27/185 , B01J27/186 , B01J27/188 , B01J27/195 , B01J27/198 , B01J35/02 , B01J37/00 , B01J37/04 , B01J37/08 , C07C51/44
CPC分类号： C07C51/48 , A61F13/53 , A61F13/534 , A61F2013/530489 , A61F2013/530496 , B01J27/16 , B01J27/1806 , B01J27/1811 , B01J27/1817 , B01J27/1853 , B01J27/1856 , B01J27/186 , B01J27/187 , B01J27/188 , B01J27/195 , B01J27/198 , B01J27/25 , B01J35/023 , B01J37/0036 , B01J37/04 , B01J37/08 , C07C51/09 , C07C51/377 , C07C51/44 , C07C57/04 , C08F2/10
摘要： Methods for catalytically dehydrating hydroxypropionic acid, hydroxypropionic acid derivatives, or mixtures thereof to acrylic acid, acrylic acid derivatives, or mixtures thereof with high yield and selectivity and without significant conversion to undesired side products, such as, acetaldehyde, propionic acid, and acetic acid, are provided. The catalysts are mixed monophosphates.
摘要翻译： 以高产率和选择性将羟基丙酸，羟基丙酸衍生物或其混合物催化脱水成丙烯酸，丙烯酸衍生物或其混合物的方法，并且不显着转化为不期望的副产物，例如乙醛，丙酸和乙酸 ，提供。 催化剂是混合的单磷酸盐。
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公开(公告)号：US20160074844A1
公开(公告)日：2016-03-17
申请号：US14856177
申请日：2015-09-16
发明人： Erik M. Freer , Wayne P. Schammel , Fabio R. Zurcher , Joel M. Cizeron , Jin Ki Hong , Anja Rumplecker , Sam Maurer , Joel Gamoras , Daniel Rosenberg , Erik C. Scher
IPC分类号： B01J27/25 , B01J23/10 , C07C2/84 , B01J37/08 , B01J37/00 , C07C5/48 , B01J27/232 , B01J23/30
CPC分类号： B01J27/25 , B01J23/002 , B01J23/10 , B01J23/30 , B01J27/232 , B01J35/0006 , B01J35/026 , B01J35/06 , B01J35/12 , B01J37/0009 , B01J37/0036 , B01J37/04 , B01J37/08 , C07C2/84 , C07C5/48 , C07C2521/06 , C07C2523/02 , C07C2523/10 , C07C2523/30 , C07C2527/25 , Y02P20/52 , C07C11/04
摘要： Catalysts, catalytic forms and formulations, and catalytic methods are provided. The catalysts and catalytic forms and formulations are useful in a variety of catalytic reactions, for example, the oxidative coupling of methane. Related methods for use and manufacture of the same are also disclosed.
摘要翻译： 提供催化剂，催化剂形式和配方以及催化方法。 催化剂和催化剂形式和配方可用于各种催化反应，例如甲烷的氧化偶联。 还公开了相关的使用和制造方法。
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公开(公告)号：US08946112B2
公开(公告)日：2015-02-03
申请号：US12638154
申请日：2009-12-15
IPC分类号： B01J27/22 , B01J27/232 , B01J27/25 , B01J35/00 , B01D53/32 , B01D53/86 , B01D53/88 , B01J20/04 , B01J21/06 , B01J23/00 , B01J23/02 , B01J23/30 , B01J27/24 , B01J37/00 , B01J37/02 , B01J37/04 , C03C17/34
CPC分类号： B01D53/007 , B01D53/32 , B01D53/864 , B01D53/8671 , B01D53/885 , B01D2251/304 , B01D2251/402 , B01D2251/404 , B01D2255/1021 , B01D2255/1023 , B01D2255/1026 , B01D2255/2027 , B01D2255/2045 , B01D2255/2047 , B01D2255/20707 , B01D2255/20776 , B01D2255/2094 , B01D2255/802 , B01D2257/502 , B01D2257/504 , B01D2259/802 , B01J20/043 , B01J21/063 , B01J23/007 , B01J23/02 , B01J23/30 , B01J27/22 , B01J27/232 , B01J27/24 , B01J27/25 , B01J35/0006 , B01J35/004 , B01J37/0045 , B01J37/0232 , B01J37/0244 , B01J37/04 , B01J2220/42 , C03C17/3417 , C03C2217/71 , C03C2217/948 , C03C2218/112 , Y02C10/08
摘要： An embodiment relates to a photocatalytic composite material comprising (a) a first component that generates a photoexcited electron and has at least a certain minimum bandgap to absorb visible light and a structure that substantially prevents the recombination of the photoexcited electron and a hole; (b) a second component that adsorbs/absorbs an oxide of carbon; and (c) a third component that splits the oxide of carbon into carbon and oxygen using the photoexcited electron.
摘要翻译： 一个实施方案涉及光催化复合材料，其包含（a）产生光激发电子并具有至少一定的最小带隙以吸收可见光的第一组分和基本上防止光激发电子和孔复合的结构; （b）吸附/吸收碳氧化物的第二成分; 和（c）使用光电子将碳分解成碳和氧的第三组分。
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公开(公告)号：US20130274518A1
公开(公告)日：2013-10-17
申请号：US13760505
申请日：2013-02-06
CPC分类号： B01J27/1806 , A61F13/53 , A61F13/534 , A61F2013/530489 , A61F2013/530496 , B01J27/16 , B01J27/1811 , B01J27/1817 , B01J27/1853 , B01J27/1856 , B01J27/186 , B01J27/187 , B01J27/188 , B01J27/195 , B01J27/198 , B01J27/25 , B01J35/023 , B01J37/0036 , B01J37/04 , B01J37/08 , C07C51/09 , C07C51/377 , C07C51/44 , C07C51/48 , C07C57/04 , C08F2/10
摘要： Processes for the purification of bio-based acrylic acid to crude and glacial acrylic acid are provided. The bio-based acrylic acid is produced from hydroxypropionic acid, hydroxypropionic acid derivatives, or mixtures thereof. The purification includes some or all of the following processes: extraction, drying, distillation, and melt crystallization. The produced glacial or crude acrylic acid contains hydroxypropionic, hydroxypropionic acid derivatives, or mixtures thereof as an impurity.
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公开(公告)号：US20130274516A1
公开(公告)日：2013-10-17
申请号：US13839986
申请日：2013-03-15
发明人： Juan Estaban Velasquez , Janette Villalobos Lingoes , Dimitris Ioannis Collis , Jane Ellen Godlewski
IPC分类号： C07C51/377
CPC分类号： C07C51/48 , A61F13/53 , A61F13/534 , A61F2013/530489 , A61F2013/530496 , B01J27/16 , B01J27/1806 , B01J27/1811 , B01J27/1817 , B01J27/1853 , B01J27/1856 , B01J27/186 , B01J27/187 , B01J27/188 , B01J27/195 , B01J27/198 , B01J27/25 , B01J35/023 , B01J37/0036 , B01J37/04 , B01J37/08 , C07C51/09 , C07C51/377 , C07C51/44 , C07C57/04 , C08F2/10
摘要： Methods for catalytically dehydrating hydroxypropionic acid, hydroxypropionic acid derivatives, or mixtures thereof to acrylic acid, acrylic acid derivatives, or mixtures thereof with high yield and selectivity and without significant conversion to undesired side products, such as, acetaldehyde, propionic acid, and acetic acid, are provided. The catalysts are mixed monophosphates.
摘要翻译： 以高产率和选择性将羟基丙酸，羟基丙酸衍生物或其混合物催化脱水成丙烯酸，丙烯酸衍生物或其混合物的方法，并且不显着转化为不期望的副产物，例如乙醛，丙酸和乙酸 ，提供。 催化剂是混合的单磷酸盐。
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公开(公告)号：US20130274514A1
公开(公告)日：2013-10-17
申请号：US13835187
申请日：2013-03-15
IPC分类号： B01J27/18 , C07C51/377
CPC分类号： C07C51/48 , A61F13/53 , A61F13/534 , A61F2013/530489 , A61F2013/530496 , B01J27/16 , B01J27/1806 , B01J27/1811 , B01J27/1817 , B01J27/1853 , B01J27/1856 , B01J27/186 , B01J27/187 , B01J27/188 , B01J27/195 , B01J27/198 , B01J27/25 , B01J35/023 , B01J37/0036 , B01J37/04 , B01J37/08 , C07C51/09 , C07C51/377 , C07C51/44 , C07C57/04 , C08F2/10
摘要： Disclosed herein is the catalytic dehydration of lactic acid to acrylic acid, which is characterized by a high conversion of lactic acid, a high selectivity for acrylic acid, a high yield of acrylic acid, and correspondingly low selectivity and molar yields for undesired by-products. This is achieved with a particular class of catalysts defined by a mixture of metal-containing phosphate salts that together provide the catalyst with a very high basicity density and low acidity density. Further, the catalyst is believed to be stable and active for lengthy periods heretofore unseen in the art for such dehydration processes.
摘要翻译： 本文公开了乳酸到丙烯酸的催化脱水，其特征在于乳酸的高转化率，丙烯酸的高选择性，高产率的丙烯酸，以及相应地低选择性和不希望的副产物的摩尔收率 。 这通过由含金属的磷酸盐的混合物限定的特定类别的催化剂来实现，这些催化剂一起提供了非常高的碱度密度和低酸度密度的催化剂。 此外，据信这种催化剂在本领域中对于这种脱水方法来说在长时间内是稳定的和活性的。
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公开(公告)号：US20130274095A1
公开(公告)日：2013-10-17
申请号：US13840192
申请日：2013-03-15
发明人： Juan Estaban Velasquez , Janette Villalobos Lingoes , Dimitris Ioannis Collis , Jane Ellen Godlewski , Marc Andrew Mamak
IPC分类号： B01J27/18
CPC分类号： C07C51/48 , A61F13/53 , A61F13/534 , A61F2013/530489 , A61F2013/530496 , B01J27/16 , B01J27/1806 , B01J27/1811 , B01J27/1817 , B01J27/1853 , B01J27/1856 , B01J27/186 , B01J27/187 , B01J27/188 , B01J27/195 , B01J27/198 , B01J27/25 , B01J35/023 , B01J37/0036 , B01J37/04 , B01J37/08 , C07C51/09 , C07C51/377 , C07C51/44 , C07C57/04 , C08F2/10
摘要： Catalysts for dehydrating hydroxypropionic acid, hydroxypropionic acid derivatives, or mixtures thereof to acrylic acid, acrylic acid derivatives, or mixtures thereof with high yield and selectivity, short residence time, and without significant conversion to undesired side products, such as, for example, acetaldehyde, propionic acid, and acetic acid, are provided. The catalysts are mixed protonated monophosphates. Methods of preparing the catalysts are also provided.
摘要翻译： 用于将羟基丙酸，羟基丙酸衍生物或其混合物脱氢至丙烯酸，丙烯酸衍生物或其混合物的高产率和选择性，短停留时间并且不显着转化为不需要的副产物例如乙醛的催化剂 ，丙酸和乙酸。 催化剂是混合的质子化单磷酸盐。 还提供了制备催化剂的方法。
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公开(公告)号：US20120115715A1
公开(公告)日：2012-05-10
申请号：US13258846
申请日：2010-03-11
申请人： Mariska Wolters , Peter Munnik , Johannes Hendrik Bitter , Petra Elisabeth De Jongh , Krijn Pieter De Jong
发明人： Mariska Wolters , Peter Munnik , Johannes Hendrik Bitter , Petra Elisabeth De Jongh , Krijn Pieter De Jong
IPC分类号： B01J37/08 , B01J37/16 , B01J37/18 , B01J20/02 , B01J23/72 , B01J23/755 , B01J23/75 , B01J20/32 , B01J21/08 , B01J35/02
CPC分类号： B01J23/72 , B01J23/40 , B01J23/74 , B01J23/75 , B01J23/755 , B01J27/25 , B01J29/0333 , B01J35/006 , B01J37/0201 , B01J37/08 , B01J37/088 , B01J37/18 , C01G3/00 , C01G49/00 , C01G51/00 , C01G53/00 , C01G55/00 , C01P2002/60 , C01P2002/72 , C01P2004/04 , C01P2004/51 , C01P2004/61 , C01P2006/12 , C01P2006/16
摘要： A method for the preparation of a supported metal nitrate, suitable as a precursor for a catalyst or sorbent, includes the steps of: (i) impregnating a support material with a metal nitrate, (ii) optionally drying the impregnated material at low temperature, and (iii) exposing the impregnated material to a gas mixture comprising nitric oxide at a temperature in the range 0-150° C., to form a dispersed supported metal nitrate. The metal nitrate may subsequently be converted to the corresponding oxide by calcining the metal nitrate to effect its decomposition. Preferred metals are iron, ruthenium, cobalt, rhodium, iridium, nickel, palladium, platinum, copper or a mixture thereof.
摘要翻译： 用于制备适合作为催化剂或吸附剂前体的负载型金属硝酸盐的方法包括以下步骤：（i）用金属硝酸盐浸渍载体材料，（ii）任选地在低温下干燥浸渍的材料， 和（iii）将浸渍的材料暴露于含有一氧化氮的气体混合物中，温度范围为0-150℃，以形成分散的负载金属硝酸盐。 随后可以通过煅烧金属硝酸盐来将金属硝酸盐转化成相应的氧化物以进行其分解。 优选的金属是铁，钌，钴，铑，铱，镍，钯，铂，铜或它们的混合物。
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