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公开(公告)号：US12023655B2
公开(公告)日：2024-07-02
申请号：US18108810
申请日：2023-02-13
申请人： EcoCatalytic Inc.
发明人： John A. Sofranko
IPC分类号： C07C5/48 , B01J8/18 , B01J8/26 , B01J21/08 , B01J23/34 , B01J27/055 , B01J27/25 , B01J29/08 , B01J37/02 , B01J37/08
CPC分类号： B01J27/055 , B01J8/1827 , B01J8/26 , B01J21/08 , B01J23/34 , B01J27/25 , B01J29/084 , B01J37/0213 , B01J37/08 , C07C5/48 , C07C2521/08 , C07C2523/34 , C07C2527/055 , C07C2527/25 , C07C2529/08
摘要： An oxide of sulfur oxygen transfer reagent is provided. A method of producing olefins from hydrocarbons with a concomitant production of water (oxidative dehydrogenation), using the oxide of sulfur oxygen transfer reagent is also provided. The sulfur oxygen transfer reagent can be used as an oxygen transfer reagent, and therefore acts as a non-metal carrier, for oxygen in a redox looping reactor for an oxidative dehydrogenation process such as the conversion of ethane to ethylene. The reduced forms of oxides of sulfur, formed in in this oxidative dehydrogenation process, can be re-oxidized with air and generate useful process heat. Also provided are methods of using the oxide of sulfur oxygen transfer reagent, and an apparatus for effecting the oxidative dehydrogenation of the hydrocarbon feed. Methods of producing the oxide of sulfur oxygen transfer reagent are also provided.
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公开(公告)号：US20240075426A1
公开(公告)日：2024-03-07
申请号：US18307835
申请日：2023-04-27
IPC分类号： B01D53/86 , B01D53/52 , B01D53/80 , B01J27/055 , B01J27/122 , B01J27/25 , C10L3/10
CPC分类号： B01D53/8612 , B01D53/52 , B01D53/80 , B01J27/055 , B01J27/122 , B01J27/25 , C10L3/103 , B01D2255/20761 , B01D2257/304 , B01J21/04 , B01J2523/17
摘要： A two or particularly three-phase process, and corresponding apparatus, desulfurizes sour hydrocarbon gas, e.g., natural gas, generally better than known, using a fixed-bed, two-phase processes in terms of the amount of H2S scavenged and the breakthrough time of H2S. The three-phase process is effective in scavenging H2S at ambient temperature and pressure, using a copper salt catalyst impregnated on alumina or other generally inert support, which is regenerable.
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公开(公告)号：US11906157B2
公开(公告)日：2024-02-20
申请号：US17393058
申请日：2021-08-03
发明人： Roger K. Young
CPC分类号： F21V9/32 , B01J21/063 , B01J23/002 , B01J27/25 , B01J35/004 , B01J37/0215 , B01J37/0236 , B01J37/08
摘要： An apparatus includes a substrate having a surface, and a transparent semiconductor photocatalyst layer secured to the surface of the substrate, wherein the photocatalyst layer includes titanium oxide and a component selected from a fluorescent dye, ultra-fine glitter, indium tin oxide, aluminum zinc oxide, silver nitrate, and combinations thereof. The photocatalyst coating may be formed on a substrate using a formulation that includes an aqueous mixture of titanium oxide and amorphous titanium peroxide, wherein the aqueous mixture may further include one of the components. A method of forming the photocatalyst coating may include applying an aqueous mixture of titanium oxide and amorphous titanium peroxide to a surface of the substrate, wherein the photocatalyst coating includes a fluorescent dye, ultra-fine glitter, indium tin oxide, aluminum zinc oxide, and/or silver nitrate. The aqueous mixture may then be dried and heated to 100 degrees Celsius or greater.
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公开(公告)号：US20230182125A1
公开(公告)日：2023-06-15
申请号：US17791643
申请日：2021-01-05
CPC分类号： B01J37/0205 , B01J37/0236 , B01J37/08 , B01J35/08 , B01J35/1014 , B01J27/25 , B01J23/755 , C10G47/12 , C10G2300/703 , C10G2300/807
摘要： The present invention addresses to a method of preparing steam reforming catalysts, of the eggshell type, using a solution of glycerin, in polar solvent, preferably water, to occupy the pores of a support. Next, the solvent is removed and the support is impregnated with a nickel salt solution, which may contain promoters such as rare earths. The steps can be repeated until the desired content of the active phase and promoters is reached.
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公开(公告)号：US20210147331A1
公开(公告)日：2021-05-20
申请号：US17253779
申请日：2018-06-28
发明人： Shengjun HUANG , Dazhi ZHANG
IPC分类号： C07C51/31 , C07C67/04 , B01J31/08 , B01J27/25 , B01J23/22 , B01J27/188 , B01J21/08 , B01J27/19 , B01J29/08 , B01J29/40 , B01J27/125
摘要： A method for producing dicarboxylic acid. The method includes: subjecting a raw material system including a cyclic olefin and a lower monocarboxylic acid to an addition reaction in the presence of an addition reaction catalyst to generate an intermediate product system including cyclic carboxylic acid ester; and subjecting the intermediate product system including cyclic carboxylic acid ester to a ring-opening and oxidation reaction in the presence of an oxidant and an oxidation catalyst to generate a corresponding dicarboxylic acid product. The addition reaction in the dicarboxylic acid synthesis route achieves a high single-pass conversion rate, and the selectivity of the corresponding cyclic carboxylic acid ester is high. The addition-oxidation synthesis route achieves faster reaction rates for both the addition reaction and oxidation reaction, and high yield of corresponding dicarboxylic acid product. The addition-oxidation based synthesis route is suitable for continuous, stable and large-scale production of corresponding dicarboxylic acid product.
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公开(公告)号：US20200347026A1
公开(公告)日：2020-11-05
申请号：US16931542
申请日：2020-07-17
IPC分类号： C07D333/40 , B01J27/25 , B01J23/75 , B01J23/889 , B01J23/74 , C07D413/04 , B01J27/20 , C07D271/06
摘要： Provided herein are processes for the preparation of heteroaryl carboxylic acids.
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公开(公告)号：US10040695B2
公开(公告)日：2018-08-07
申请号：US15129137
申请日：2015-03-25
IPC分类号： B01J20/08 , B01J21/10 , B01J23/06 , B01J37/08 , B01J27/138 , B01J27/053 , B01J27/232 , B01J37/04 , B01J20/30 , B01J27/25 , C01F11/18 , B01J27/236 , B01J31/26 , B01J31/28 , B01J31/02 , B01J35/10 , B01J35/02 , B01J37/03 , B01J37/02 , B01J20/22 , B01J20/04 , B01J20/28 , C09D1/00 , C01F11/46 , C01F11/36 , C01G53/00 , C01G51/00 , C01G3/00
摘要： Layered double hydroxides having a high surface area (at least 125 m2/g) and the formula (I) [Mz+1−xM′y+x(OH)2]a+(Xn−)a/n+bH2O.c(AMO-solvent) (I) wherein M and M′ are different and each is a charged metal cation (and must be present), z=1 or 2; y=3 or 4, 0
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公开(公告)号：US20180127348A1
公开(公告)日：2018-05-10
申请号：US15861702
申请日：2018-01-04
发明人： Jane Ellen Godlewski , Janette Villalobos Lingoes , Juan Esteban Velasquez , Dimitris Ioannis Collias
IPC分类号： C07C51/48 , C08F2/10 , C07C57/04 , A61F13/534 , B01J27/16 , C07C51/44 , C07C51/377 , C07C51/09 , B01J37/08 , B01J37/04 , B01J37/00 , B01J35/02 , B01J27/25 , B01J27/198 , B01J27/195 , B01J27/188 , B01J27/187 , B01J27/186 , B01J27/185 , B01J27/18 , A61F13/53
CPC分类号： B01J27/1806 , A61F13/53 , A61F13/534 , A61F2013/530489 , A61F2013/530496 , B01J27/16 , B01J27/1811 , B01J27/1817 , B01J27/1853 , B01J27/1856 , B01J27/186 , B01J27/187 , B01J27/188 , B01J27/195 , B01J27/198 , B01J27/25 , B01J35/023 , B01J37/0036 , B01J37/04 , B01J37/08 , C07C51/09 , C07C51/377 , C07C51/44 , C07C51/48 , C07C57/04 , C08F2/10
摘要： Processes for the purification of bio-based acrylic acid to crude and glacial acrylic acid are provided. The bio-based acrylic acid is produced from hydroxypropionic acid, hydroxypropionic acid derivatives, or mixtures thereof. The purification includes some or all of the following processes: extraction, drying, distillation, and melt crystallization. The produced glacial or crude acrylic acid contains hydroxypropionic, hydroxypropionic acid derivatives, or mixtures thereof as an impurity.
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公开(公告)号：US09718695B2
公开(公告)日：2017-08-01
申请号：US13517766
申请日：2012-06-14
申请人： Tae-gon Kim , Tae-hyung Kim , Seoung-jae Im
发明人： Tae-gon Kim , Tae-hyung Kim , Seoung-jae Im
IPC分类号： C01B33/20 , B01J19/12 , B01J23/66 , B01J23/50 , B01J35/00 , B01J37/30 , C25B1/00 , B01J23/72 , B01J37/08 , B01J37/02 , B01J23/52 , B01J27/25 , B01J37/00
CPC分类号： C01B33/20 , B01J19/123 , B01J23/50 , B01J23/52 , B01J23/66 , B01J23/72 , B01J27/25 , B01J35/004 , B01J37/0081 , B01J37/0215 , B01J37/08 , B01J37/30 , B01J2219/0877 , B01J2219/0892 , C02F2305/10 , C25B1/003 , Y02W10/37
摘要： A visible light sensitive photocatalyst including a compound represented by Formula 1: Aa-xM1xSib-yM2yOc Formula 1 wherein A is one or more metals selected from Ag, Cu, and Au; M1 is one or more metals selected from Li, Na, K, Rb, and Cs; M2 is one or more metals selected from Ge, Sn, Ti, Zr, and Hf, and 1.7≦a≦2.3, 0.7≦b≦1.3, 2.7≦c≦3.3, 0≦x
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10.发明授权公开(公告)号：US09714208B2
公开(公告)日：2017-07-25
申请号：US13760472
申请日：2013-02-06
IPC分类号： C07C51/377 , C07C51/48 , B01J27/18 , B01J27/187 , B01J27/25 , C07C51/09 , C07C57/04 , A61F13/534 , C08F2/10 , B01J27/16 , B01J27/185 , B01J27/186 , B01J27/188 , B01J27/195 , B01J27/198 , B01J35/02 , B01J37/00 , B01J37/04 , B01J37/08 , C07C51/44 , A61F13/53
CPC分类号： C07C51/48 , A61F13/53 , A61F13/534 , A61F2013/530489 , A61F2013/530496 , B01J27/16 , B01J27/1806 , B01J27/1811 , B01J27/1817 , B01J27/1853 , B01J27/1856 , B01J27/186 , B01J27/187 , B01J27/188 , B01J27/195 , B01J27/198 , B01J27/25 , B01J35/023 , B01J37/0036 , B01J37/04 , B01J37/08 , C07C51/09 , C07C51/377 , C07C51/44 , C07C57/04 , C08F2/10
摘要： Methods for catalytically dehydrating hydroxypropionic acid, hydroxypropionic acid derivatives, or mixtures thereof to acrylic acid, acrylic acid derivatives, or mixtures thereof with high yield and selectivity and without significant conversion to undesired side products, such as, acetaldehyde, propionic acid, and acetic acid, are provided. The catalysts are mixed condensed phosphates.
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