Pressure-Sensitive Adhesives with High Molar Masses and Narrow Molar Mass Distribution and Process for Preparing them
    11.
    发明申请
    Pressure-Sensitive Adhesives with High Molar Masses and Narrow Molar Mass Distribution and Process for Preparing them 有权
    具有高摩尔质量和窄摩尔​​质量分布的压敏粘合剂及其制备方法

    公开(公告)号:US20130165606A1

    公开(公告)日:2013-06-27

    申请号:US13720487

    申请日:2012-12-19

    申请人: TESA SE

    发明人: Alexander Prenzel

    IPC分类号: C09J141/00

    摘要: The invention relates to a process for preparing pressure-sensitive adhesives (PSAs) which have high molar masses in combination with a narrow molar mass distribution, and also to PSAs, especially polyacrylate-based PSAs, prepared accordingly.It has been found that, surprisingly, polymers with high molar masses and a narrow molar mass distribution, more particularly polyacrylates with high molar masses and a narrow molar mass distribution, can be prepared outstandingly in particular by means of RAFT processes in the presence of a diradical initiator which undergoes thermal cyclization to form a diradical, these polymers being suitable for use as high-shear-strength PSAs.

    摘要翻译: 本发明涉及一种制备具有高摩尔质量并且结合窄摩尔质量分布的压敏粘合剂(PSA)的方法,以及相应制备的PSA,特别是基于聚丙烯酸酯的PSA。 已经发现令人惊奇的是,具有高摩尔质量和较低摩尔质量分布的聚合物,更特别是具有高摩尔质量和较窄摩尔质量分布的聚丙烯酸酯,可以特别通过RAFT方法在存在 经历热环化以形成双向的双基引发剂,这些聚合物适合用作高剪切强度的PSA。

    WATER-BORNE ADHESIVES
    17.
    发明申请
    WATER-BORNE ADHESIVES 审中-公开
    水性粘合剂

    公开(公告)号:US20140072820A1

    公开(公告)日:2014-03-13

    申请号:US14116148

    申请日:2012-05-14

    申请人: Mai Chen

    发明人: Mai Chen

    IPC分类号: C09J141/00

    摘要: There is provided a waterborne adhesive composition comprising a vinyl polymer that comprises a) 0 to 0.4% polymerized units of carboxyl functional monomer, by weight based on the weight of said vinyl polymer, and (b) 0.1% to 10% polymerized units of sulfonic acid functional monomer, by weight based on the weight of said vinyl polymer. Also provided is a method of bonding substrates with such a composition and a bonded article made by such a method.

    摘要翻译: 提供一种水性粘合剂组合物,其包含乙烯基聚合物,其包含a)基于所述乙烯基聚合物的重量计的0至0.4%的羧基官能单体的聚合单元,和(b)0.1%至10%的聚合单元的磺酸 酸官能单体,基于所述乙烯基聚合物的重量计。 还提供了用这种组合物粘接基材的方法和通过这种方法制成的粘合物。

    Process for improving water-whitening resistance of pressure sensitive adhesives
    18.
    发明授权
    Process for improving water-whitening resistance of pressure sensitive adhesives 有权
    提高压敏粘合剂耐水白度的工艺

    公开(公告)号:US07169846B2

    公开(公告)日:2007-01-30

    申请号:US10142455

    申请日:2002-05-10

    摘要: Pressure sensitive adhesive compositions having enhanced resistance to water-whitening comprising an aqueous emulsion polymer are disclosed. The polymer comprises the polymerization reaction product of a polymerizable aqueous emulsion comprising: (i) at least one hydrophobic alkyl acrylate or alkyl methacrylate ester of an alcohol, (ii) at least about 1 wt. % of at least one hydrophilic monomer, (iii) at least about 5 wt. % of at least one partially hydrophilic alkyl acrylate or alkyl methacrylate ester of an alcohol, and (iv) a water-soluble or water-dispersible polymerizable surfactant selected from compounds having a terminal allyl amine moiety, substituted phenyl compounds having at least one alkenyl substituent, polyoxyalkylene-1-(allyloxymethyl) alkyl ether sulfate salts, or mixtures thereof, and the average particle size of the polymer is less than or equal to 200 nm. Also disclosed are processes for preparing same.

    摘要翻译: 公开了具有增强的耐水性的含水乳液聚合物的压敏粘合剂组合物。 该聚合物包括可聚合水乳液的聚合反应产物,其包含:(i)至少一种疏水性烷基丙烯酸酯或醇的甲基丙烯酸烷基酯酯,(ii)至少约1wt。 %的至少一种亲水性单体,(iii)至少约5wt。 %的至少一种部分亲水的丙烯酸烷基酯或甲基丙烯酸烷基酯酯,和(iv)选自具有末端烯丙基胺部分的化合物的水溶性或水分散性可聚合表面活性剂,具有至少一个链烯基取代基的取代苯基化合物 ,聚氧化烯-1-(烯丙氧基甲基)烷基醚硫酸盐或其混合物,聚合物的平均粒度小于或等于200nm。 还公开了制备方法。