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    Hydrogenation catalyst composition and method for hydrogenation of conjugated diene polymer
    2.
    发明申请
    Hydrogenation catalyst composition and method for hydrogenation of conjugated diene polymer 有权
    氢化催化剂组合物和共轭二烯聚合物氢化方法

    公开(公告)号：US20080146733A1

    公开(公告)日：2008-06-19

    申请号：US12002812

    申请日：2007-12-19

    Applicant: Chih-Kuang Tsai ,  Chien-Cheng Chen ,  Jung-Sheng Pan

    Inventor： Chih-Kuang Tsai ,  Chien-Cheng Chen ,  Jung-Sheng Pan

    IPC: B01J31/12 ,  C08G63/00

    CPC classification number: B01J31/2295 ,  B01J31/0259 ,  B01J31/0261 ,  B01J31/143 ,  B01J2231/645 ,  B01J2531/46 ,  C08C19/02 ,  C08F8/04 ,  C08F210/00

    Abstract: A method for hydrogenation of a conjugated diene polymer is provided. The conjugated diene polymer in an inert organic solvent is brought into contact with hydrogen in the presence of a hydrogenation catalyst composition to selectively hydrogenate the unsaturated double bonds in the conjugated diene units of the conjugated diene polymer. The hydrogenation catalyst composition includes: (a) a titanium compound; (b) a compound represented by formula (II) or formula (III): wherein R is C1-C12 alkyl, C3-C12 cycloalkyl, aryl or alkyl aryl, M is C1-C12 alkyl, C1-C12 alkoxy, aryl, alkyl aryl, phenoxy or hydroxyl, and n=1˜3; and (c) a alkylaluminum compound.

    Abstract translation: 提供了共轭二烯聚合物的氢化方法。 惰性有机溶剂中的共轭二烯聚合物在氢化催化剂组合物的存在下与氢接触，以选择性氢化共轭二烯聚合物的共轭二烯单元中的不饱和双键。 氢化催化剂组合物包括：（a）钛化合物; （b）由式（II）或式（III）表示的化合物：其中R是C 1 -C 12烷基，C 3〜 C 12环烷基，芳基或烷基芳基，M为C 1 -C 12烷基，C 1〜 C 12烷氧基，芳基，烷基芳基，苯氧基或羟基，n = 1〜3; 和（c）烷基铝化合物。

    Phosphonite-and phosphonite-promoted ruthenium - cobalt catalysts for the dealkoxyhydroxymethylation of acetals to form glycol ethers
    4.
    发明授权
    Phosphonite-and phosphonite-promoted ruthenium - cobalt catalysts for the dealkoxyhydroxymethylation of acetals to form glycol ethers 失效
    亚膦酸酯和亚膦酸盐促进的钌 - 钴催化剂用于缩醛的脱烷基羟甲基化形成二醇醚

    公开(公告)号：US4895987A

    公开(公告)日：1990-01-23

    申请号：US871351

    申请日：1986-06-06

    Applicant: D. Michael Duggan ,  James E. Lyons ,  Harry K. Myers ,  Robert E. Ledley

    Inventor： D. Michael Duggan ,  James E. Lyons ,  Harry K. Myers ,  Robert E. Ledley

    IPC: B01J31/20 ,  B01J31/24 ,  C07C41/30

    CPC classification number: C07C41/30 ,  B01J31/0261 ,  B01J31/0262 ,  B01J31/20 ,  B01J2231/34 ,  B01J2231/641 ,  B01J2531/0211 ,  B01J2531/821 ,  B01J2531/845

    Abstract: Ruthenium-cobalt- or cobalt-containing catalysts which have been promoted with phosphonites or phosphinites effectively catalyze the dealkoxyhydroxymethylation of aldehyde acetals to form glycol monoethers. Methylal, for example, may be reacted with syngas, i.e., CO and H.sub.2, in the presence of these phosphonite- or phosphinite-promoted cobalt or ruthenium- cobalt catalysts to form the monomethyl ether of ethylene glycol. In a like manner acetaldehyde may be converted to the corresponding propylene glycol monoether. The process may advantageously be carried out with high yields and selectivities in the presence of a polar or non-polar organic solvent in combination with the catalyst system of this invention.The invention is also directed to the phosphonite- or phosphonite-promoted cobalt and ruthenium-cobalt catalyst system per se.

    Abstract translation: 已经用亚膦酸盐或次膦酸盐促进的含钌钴或钴的催化剂有效地催化醛缩醛的脱烷基羟甲基化形成二醇单醚。 甲缩醛例如可以在合成气（即CO和H 2）的存在下，在这些亚膦酸盐或次膦酸盐促进的钴或钌 - 钴催化剂的存在下反应以形成乙二醇的单甲基醚。 以类似方式，乙醛可以转化成相应的丙二醇单醚。 在极性或非极性有机溶剂与本发明的催化剂体系的组合下，该方法可以有利地以高产率和选择性进行。 本发明还涉及亚膦酸盐或亚膦酸盐促进的钴和钌 - 钴催化剂体系本身。

    METHOD FOR PRODUCING ALPHA - AMINO ACID INCLUDING PHOSPHORUS AND PRODUCTION INTERMEDIATES THEREOF
    5.
    发明申请
    METHOD FOR PRODUCING ALPHA - AMINO ACID INCLUDING PHOSPHORUS AND PRODUCTION INTERMEDIATES THEREOF 有权
    生产含氨基酸的氨基酸及其生产中间体的方法

    公开(公告)号：US20090270647A1

    公开(公告)日：2009-10-29

    申请号：US12442011

    申请日：2007-09-19

    Applicant: Nobuto Minowa ,  Nozomu Nakanishi ,  Masaaki Mitomi

    Inventor： Nobuto Minowa ,  Nozomu Nakanishi ,  Masaaki Mitomi

    IPC: C07F9/32

    CPC classification number: C07B53/00 ,  B01J31/0207 ,  B01J31/0209 ,  B01J31/0235 ,  B01J31/0237 ,  B01J31/0261 ,  B01J31/0271 ,  B01J2231/341 ,  C07F9/3211 ,  Y02P20/55

    Abstract: A method for efficiently producing L-2-amino-4-(hydroxymethylphosphinyl)-butanoic acid, useful as a herbicide, by a catalytic asymmetric synthesis reaction with a high asymmetric yield. The method includes a step in which a compound represented by the below formula (1) and a benzylamine are reacted in the presence of dehydrating agent, then the resulting mass is reacted with hydrogen cyanide in the presence of an asymmetric catalyst, followed by acid hydrolysis, further followed by elimination of a protective group. [chemical formula 1] (1) (where, R1 represents a C1-4 alkyl group.)

    Abstract translation: 通过具有高不对称产率的催化不对称合成反应有效生产可用作除草剂的L-2-氨基-4-（羟甲基氧膦基） - 丁酸的方法。 该方法包括在脱水剂的存在下使由下式（1）表示的化合物和苄胺反应的步骤，然后将所得物质与氰化氢在不对称催化剂的存在下反应，随后进行酸水解 ，然后除去保护基。 [化学式1]（1）（其中，R 1表示C 1-4烷基）

    Solid acid catalyst
    6.
    发明授权
    Solid acid catalyst 有权
    固体酸催化剂

    公开(公告)号：US06383970B1

    公开(公告)日：2002-05-07

    申请号：US09597536

    申请日：2000-06-19

    Applicant: Taku Mimura ,  Jun Kaita ,  Noriaki Fukuoka ,  Yasuyuki Hattori

    Inventor： Taku Mimura ,  Jun Kaita ,  Noriaki Fukuoka ,  Yasuyuki Hattori

    IPC: B01J3100

    CPC classification number: C07C67/08 ,  B01J27/16 ,  B01J31/0261 ,  B01J2231/40 ,  B01J2231/49 ,  C07C67/03 ,  C07C69/52 ,  C07C69/24

    Abstract: The present invention provides a solid acid catalyst developing high activity and exhibiting high durability in various organic reactions. That is, the present invention provides a solid acid catalyst having the structure (A) in which a hydrogen atom is eliminated from at least one of OH groups contained in an inorganic phosphorus acid, the structure (B) in which a hydrogen atom is eliminated from at least one of OH groups contained in an organic phosphorus acid represented by the formula (1) or (2) and at least one metal atom (C) selected from aluminum, gallium and iron and a method for producing an ester, a ketal or an acetal by using the solid acid catalyst; wherein each of —R1 and —R2 is selected from —R, —OR, —OH and —H in which at least one of —R1 and —R2 is —R or —OR, given that —R is an organic group having 1-22 carbon atoms.

    Abstract translation: 本发明提供一种在各种有机反应中显示出高活性和显示高耐久性的固体酸催化剂。 也就是说，本发明提供具有结构（A）的固体酸催化剂，其中从无机磷酸中所含的OH基中的至少一个除去氢原子，其中消除氢原子的结构（B） 由式（1）或（2）表示的有机磷酸中的至少一个OH基和选自铝，镓和铁中的至少一种金属原子（C）和酯的制备方法，缩酮 或通过使用固体酸催化剂的缩醛;其中-R1和-R2各自选自-R，-OR，-OH和-H，其中-R1和-R2中的至少一个是-R或-OR， 假定-R是具有1-22个碳原子的有机基团。

    Esterification catalysts and processes therefor and therewith
    7.
    发明授权
    Esterification catalysts and processes therefor and therewith 有权
    酯化催化剂及其工艺及其

    公开(公告)号：US6166170A

    公开(公告)日：2000-12-26

    申请号：US453100

    申请日：1999-12-02

    Applicant: Donald Edward Putzig

    Inventor： Donald Edward Putzig

    IPC: B01J31/22 ,  B01J27/16 ,  B01J31/02 ,  B01J31/04 ,  B01J31/16 ,  B01J31/26 ,  B01J37/04 ,  C07B61/00 ,  C07C67/08 ,  C07C69/82 ,  C08G63/85 ,  C08G63/78 ,  B01J31/00

    CPC classification number: B01J31/0261 ,  B01J27/16 ,  B01J31/0212 ,  B01J31/223 ,  B01J31/2243 ,  B01J2231/14 ,  B01J2231/40 ,  B01J2231/49 ,  B01J2531/46 ,  C08G63/85

    Abstract: A catalyst composition is disclosed. The composition comprises a titanium compound, a complexing agent, hypophosphorous acid or its metal salt, water and optionally a solvent. The complexing agent can be hydroxycarboxylic acid, alkanolamines, aminocarboxylic acids, or combinations of two or more thereof. The solvent can be water, ethanol, propanol, isopropanol, butanol, ethylene glycol, propylene glycol, isopropylene glycol, butylene glycol, 1-methyl propylene glycol, pentylene glycol, or combinations of two or more thereof. The titanium compound can be combined with a zirconium compound. Also disclosed is a process for using the composition for producing an ester or a polyester. The process comprises contacting a carbonyl compound, in the presence of the composition, with an alcohol under a condition suitable for esterification, transesterification, polymerization, or combinations of two or more thereof.

    Abstract translation: 公开了一种催化剂组合物。 组合物包含钛化合物，络合剂，次磷酸或其金属盐，水和任选的溶剂。 络合剂可以是羟基羧酸，链烷醇胺，氨基羧酸或其两种或多种的组合。 溶剂可以是水，乙醇，丙醇，异丙醇，丁醇，乙二醇，丙二醇，异丙二醇，丁二醇，1-甲基丙二醇，戊二醇或其两种或多种的组合。 钛化合物可以与锆化合物组合。 还公开了使用该组合物生产酯或聚酯的方法。 该方法包括在适于酯化，酯交换，聚合或其两种或多种的组合的条件下，使组合物存在下的羰基化合物与醇接触。

    Dimerization process
    8.
    发明授权
    Dimerization process 失效
    二进制过程

    公开(公告)号：US4316857A

    公开(公告)日：1982-02-23

    申请号：US86035

    申请日：1979-10-18

    Applicant: Arthur H. Gilbert

    Inventor： Arthur H. Gilbert

    IPC: C07B61/00 ,  B01J31/00 ,  B01J31/02 ,  B01J31/12 ,  C07C67/00 ,  C07C253/00 ,  C07C255/04 ,  C07C255/09 ,  C07C120/00 ,  C07C121/20

    CPC classification number: C07C255/00 ,  B01J31/0259 ,  B01J31/0261

    Abstract: A process for the dimerization of acrylonitrile to dicyanobutene and methylene-glutaronitrile under the influence of a phosphinite or phosphonite catalyst uses as solvent a mixture of proton-donating organic solvent, an aromatic hydrocarbon solvent and an aliphatic hydrocarbon solvent in a specified ratio so facilitating product isolation by phase separation or liquid/liquid extraction.

    Abstract translation: 在亚磷酸盐或亚膦酸盐催化剂的影响下，将丙烯腈二聚成二氰丁烯和亚甲基 - 戊二腈的方法以特定的比例用作质子供体的有机溶剂，芳族烃溶剂和脂族烃溶剂的溶剂作为溶剂，从而便于产物 通过相分离或液/液萃取分离。

    Process for the dimerization of acrylonitrile
    9.
    发明授权
    Process for the dimerization of acrylonitrile 失效
    丙烯腈二聚过程

    公开(公告)号：US4089890A

    公开(公告)日：1978-05-16

    申请号：US811440

    申请日：1977-06-29

    Applicant: James Robert Jennings ,  Lawrence Francis Michael Kelly

    Inventor： James Robert Jennings ,  Lawrence Francis Michael Kelly

    IPC: B01J31/02 ,  B01J31/18 ,  C07C129/00 ,  C07C121/20

    CPC classification number: B01J31/0262 ,  B01J31/0261 ,  B01J31/0264 ,  B01J31/0269 ,  C07C255/00

    Abstract: Catalyst composition for the dimerisation of acrylonitrile comprising an organo-phosphorus compound of formula ##STR1## bonded to a matrix of an inorganic oxide having surface --OH groups, especially of silica or alumina. Groups R and Y are hydrocarbyl. The catalyst compositions are prepared by heating the matrix with an appropriate phosphorus compound having group(s) X which react with --OH groups with the elimination of HX. The invention also relates to a process for the dimerisation of acrylonitrile. Main products are 1,4-dicyanobutene-1 and 2-methylene glutaronitrile.

    Abstract translation: 用于丙烯腈二聚的催化剂组合物，其包含与具有表面-OH基团，特别是二氧化硅或氧化铝的无机氧化物的基体结合的式“IMAGE”的有机磷化合物。 基团R和Y是烃基。 通过用具有与-OH基团反应的基团X的合适的磷化合物加热基质来制备催化剂组合物，同时除去HX。 本发明还涉及丙烯腈二聚化的方法。 主要产品有1,4-二氰丁烯-1和2-亚甲基戊二腈。

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