公开(公告)号：US06407269B2

公开(公告)日：2002-06-18

申请号：US09885962

申请日：2001-06-22

Applicant: Jun Kaita ,  Taku Mimura ,  Noriaki Fukuoka ,  Yasuyuki Hattori

Inventor： Jun Kaita ,  Taku Mimura ,  Noriaki Fukuoka ,  Yasuyuki Hattori

IPC: C11C100

CPC classification number: C11C3/003 ,  B01J27/16 ,  B01J27/1811 ,  B01J27/1853

Abstract: The present invention provides a heterogeneous catalyst which is highly active, excellent in selectivity and free from elution of its catalyst-components during reaction and which has long lifetime. That is, a phosphate of a metal selected from the group consisting of aluminum, gallium and iron is used as the catalyst for transesterification of the present invention.

Abstract translation: 本发明提供了一种非均相催化剂，它具有高活性，选择性优异，反应期间催化剂组分不溶解，寿命长。 也就是说，使用选自铝，镓和铁的金属的磷酸盐作为本发明的酯交换反应的催化剂。

公开(公告)号：US06383970B1

公开(公告)日：2002-05-07

申请号：US09597536

申请日：2000-06-19

Applicant: Taku Mimura ,  Jun Kaita ,  Noriaki Fukuoka ,  Yasuyuki Hattori

Inventor： Taku Mimura ,  Jun Kaita ,  Noriaki Fukuoka ,  Yasuyuki Hattori

IPC: B01J3100

CPC classification number: C07C67/08 ,  B01J27/16 ,  B01J31/0261 ,  B01J2231/40 ,  B01J2231/49 ,  C07C67/03 ,  C07C69/52 ,  C07C69/24

Abstract: The present invention provides a solid acid catalyst developing high activity and exhibiting high durability in various organic reactions. That is, the present invention provides a solid acid catalyst having the structure (A) in which a hydrogen atom is eliminated from at least one of OH groups contained in an inorganic phosphorus acid, the structure (B) in which a hydrogen atom is eliminated from at least one of OH groups contained in an organic phosphorus acid represented by the formula (1) or (2) and at least one metal atom (C) selected from aluminum, gallium and iron and a method for producing an ester, a ketal or an acetal by using the solid acid catalyst; wherein each of —R1 and —R2 is selected from —R, —OR, —OH and —H in which at least one of —R1 and —R2 is —R or —OR, given that —R is an organic group having 1-22 carbon atoms.

Abstract translation: 本发明提供一种在各种有机反应中显示出高活性和显示高耐久性的固体酸催化剂。 也就是说，本发明提供具有结构（A）的固体酸催化剂，其中从无机磷酸中所含的OH基中的至少一个除去氢原子，其中消除氢原子的结构（B） 由式（1）或（2）表示的有机磷酸中的至少一个OH基和选自铝，镓和铁中的至少一种金属原子（C）和酯的制备方法，缩酮 或通过使用固体酸催化剂的缩醛;其中-R1和-R2各自选自-R，-OR，-OH和-H，其中-R1和-R2中的至少一个是-R或-OR， 假定-R是具有1-22个碳原子的有机基团。

公开(公告)号：US4956326A

公开(公告)日：1990-09-11

申请号：US71964

申请日：1987-07-10

Applicant: Noriyuki Yoneda ,  Toshiji Makabe ,  Jun Kaita ,  Munekazu Nakamura ,  Yoshiko Endoh ,  Hidehiko Kudoh ,  Shunji Higashi

Inventor： Noriyuki Yoneda ,  Toshiji Makabe ,  Jun Kaita ,  Munekazu Nakamura ,  Yoshiko Endoh ,  Hidehiko Kudoh ,  Shunji Higashi

IPC: B01J23/40 ,  B01J27/22 ,  B01J27/24 ,  C01B9/00 ,  C01B33/107 ,  C01G31/04 ,  C01G33/00

CPC classification number: C01G31/04 ,  B01J23/40 ,  B01J27/22 ,  B01J27/24 ,  C01B33/1071 ,  C01B9/00 ,  C01G33/00 ,  C01P2004/32 ,  C01P2006/10 ,  C01P2006/11 ,  C01P2006/12 ,  C01P2006/14 ,  C01P2006/16 ,  C01P2006/17 ,  C01P2006/19 ,  C01P2006/80

Abstract: A catalyst for dehalogenation of a halide comprising a corrosion-resistant ceramic or graphite having a surface area of 5.0 m.sup.2 /g or less and, supported thereon, at least one of a platinum group metal and a silicide thereof, and a method of dehalogenation of a halide using this catalyst.

Abstract translation: 一种卤化物的脱卤催化剂，其包含表面积为5.0m 2 / g以下的耐腐蚀陶瓷或石墨，并且在其上负载有铂族金属及其硅化物中的至少一种，以及脱卤的方法 使用该催化剂的卤化物。