公开(公告)号：US07985706B2

公开(公告)日：2011-07-26

申请号：US11922462

申请日：2006-06-19

申请人： Yoshimi Okada ,  Toshiji Makabe ,  Masashi Saito ,  Takako Nishijima

发明人： Yoshimi Okada ,  Toshiji Makabe ,  Masashi Saito ,  Takako Nishijima

IPC分类号： B01J27/02 ,  B01J27/053 ,  B01J27/055 ,  B01J27/049 ,  B01J27/043 ,  B01J27/045 ,  B01J23/00 ,  B01J23/40 ,  B01J23/42 ,  B01J23/60 ,  B01J23/72 ,  C07C4/02 ,  C07C5/00 ,  C07C5/09 ,  C07C5/327 ,  C07C5/373

CPC分类号： B01J27/053 ,  B01J21/04 ,  B01J23/42 ,  B01J23/464 ,  B01J27/045 ,  B01J35/008 ,  B01J35/0093 ,  B01J35/1019 ,  B01J35/1038 ,  B01J35/1061 ,  B01J37/0201 ,  B01J37/18 ,  B01J37/20 ,  C07C5/367 ,  Y02P20/52 ,  C07C15/06 ,  C07C15/24 ,  C07C15/02 ,  C07C15/27

摘要： Provided are: a uniformly, highly dispersed metal catalyst including a catalyst carrier and a catalyst metal being loaded thereon dispersed throughout the carrier, the uniformly, highly dispersed metal catalyst having excellent performances with respect to catalytic activity, selectivity, life, etc.; and a method of producing the same. The uniformly, highly dispersed metal catalyst includes a catalyst carrier made of a metal oxide and a catalyst metal having catalytic activity, the catalyst metal being loaded on the catalyst carrier, in which the catalyst carrier is a sulfur-containing catalyst carrier having sulfur or a sulfur compound almost evenly distributed throughout the carrier and the catalyst metal is loaded on the sulfur-containing catalyst carrier in a substantially evenly dispersed manner over the entire carrier substantially according to the distribution of the sulfur or the sulfur compound.

摘要翻译： 提供：均匀高度分散的金属催化剂，其包含分散在整个载体上的催化剂载体和催化剂金属，均匀高度分散的金属催化剂在催化活性，选择性，寿命等方面具有优异的性能; 及其制造方法。 均匀，高度分散的金属催化剂包括由金属氧化物制成的催化剂载体和具有催化活性的催化剂金属，催化剂金属负载在催化剂载体上，其中催化剂载体是具有硫或硫的催化剂载体 硫化合物几乎均匀分布在整个载体上，催化剂金属基本上按照硫或硫化合物的分布，以基本上均匀分散的方式载于整个载体上。

公开(公告)号：US5362696A

公开(公告)日：1994-11-08

申请号：US849346

申请日：1992-03-11

申请人： Kazuo Takahashi ,  Fumio Kumata ,  Hitoshi Nozaki ,  Shinichi Inoue ,  Toshiji Makabe

发明人： Kazuo Takahashi ,  Fumio Kumata ,  Hitoshi Nozaki ,  Shinichi Inoue ,  Toshiji Makabe

IPC分类号： B01J29/06 ,  B01J29/40 ,  B01J35/08 ,  B01J20/18

CPC分类号： B01J29/06 ,  B01J29/40 ,  B01J35/08 ,  B01J2229/42

摘要： A process for producing a spherical zeolite catalyst is disclosed, which comprises dropping a zeolite-containing alumina sol into a surfactant-containing oil phase from a dropping opening directly or through air to thereby form spherical droplets of the sol, and then allowing the droplets to gel in an aqueous alkaline solution phase underlying the oil phase and withdrawing the thus gelled droplets, said dropping of the sol being conducted while the dropping opening is being impulsed to thereby impart a spherical and uniform shape to the resulting zeolite particles containing alumina as a binder, and a novel apparatus therefor.

摘要翻译： 公开了一种制备球形沸石催化剂的方法，其包括将含沸石的氧化铝溶胶直接或通过空气从滴入口滴入含表面活性剂的油相中，从而形成溶胶的球形液滴，然后使液滴 凝胶在水相下面的碱性溶液相中并且抽出如此凝胶化的液滴，当滴下的开口被冲击时，所述溶胶的滴下被引导，从而赋予所得到的含有氧化铝作为粘合剂的沸石颗粒的球形和均匀形状 ，及其新颖的装置。

公开(公告)号：US4956326A

公开(公告)日：1990-09-11

申请号：US71964

申请日：1987-07-10

申请人： Noriyuki Yoneda ,  Toshiji Makabe ,  Jun Kaita ,  Munekazu Nakamura ,  Yoshiko Endoh ,  Hidehiko Kudoh ,  Shunji Higashi

发明人： Noriyuki Yoneda ,  Toshiji Makabe ,  Jun Kaita ,  Munekazu Nakamura ,  Yoshiko Endoh ,  Hidehiko Kudoh ,  Shunji Higashi

IPC分类号： B01J23/40 ,  B01J27/22 ,  B01J27/24 ,  C01B9/00 ,  C01B33/107 ,  C01G31/04 ,  C01G33/00

CPC分类号： C01G31/04 ,  B01J23/40 ,  B01J27/22 ,  B01J27/24 ,  C01B33/1071 ,  C01B9/00 ,  C01G33/00 ,  C01P2004/32 ,  C01P2006/10 ,  C01P2006/11 ,  C01P2006/12 ,  C01P2006/14 ,  C01P2006/16 ,  C01P2006/17 ,  C01P2006/19 ,  C01P2006/80

摘要： A catalyst for dehalogenation of a halide comprising a corrosion-resistant ceramic or graphite having a surface area of 5.0 m.sup.2 /g or less and, supported thereon, at least one of a platinum group metal and a silicide thereof, and a method of dehalogenation of a halide using this catalyst.

摘要翻译： 一种卤化物的脱卤催化剂，其包含表面积为5.0m 2 / g以下的耐腐蚀陶瓷或石墨，并且在其上负载有铂族金属及其硅化物中的至少一种，以及脱卤的方法 使用该催化剂的卤化物。

公开(公告)号：US4440631A

公开(公告)日：1984-04-03

申请号：US504439

申请日：1983-06-15

申请人： Osamu Togari ,  Masatoshi Matsuda ,  Kenji Shimokawa ,  Toshiji Makabe

发明人： Osamu Togari ,  Masatoshi Matsuda ,  Kenji Shimokawa ,  Toshiji Makabe

IPC分类号： C10G47/10 ,  B01J23/00 ,  B01J23/22 ,  B01J23/28 ,  B01J23/68 ,  B01J23/847 ,  B01J23/88 ,  B01J23/885 ,  B01J27/00 ,  B01J27/04 ,  B01J27/051 ,  B01J35/10 ,  C10G47/12

CPC分类号： B01J35/10 ,  B01J23/22 ,  B01J23/28 ,  B01J23/68 ,  B01J23/8472 ,  B01J23/885 ,  C10G47/12 ,  B01J35/1014 ,  B01J35/1038 ,  B01J35/1061

摘要： A catalyst for hydrocracking heavy hydrocarbon oils includes a porous inorganic carrier composed mainly of alumina or titania, and two or more catalytic metal components composited with the carrier. The metals of the catalytic metal components are either (a) V and at least one element selected from Zn, Fe, Co, Ni, Cu, Ag, Sn and Pb or (b) Mo and at least one element selected from Zn, Cu, Ag, Sn, Pb and the lanthanum-series elements. The catalyst has at least 60% of its total pore volume in pores with a diameter of 200 .ANG. or more, at least 40% of its totalpore volume in pores with a diameter of 300 .ANG. or more and not more than 20% of its total pore volume in pores with a diameter of at least 1000 .ANG.. Disclosed also is a process for hydrocracking a heavy hydrocarbon oil in the presence of the above catalyst.

摘要翻译： 用于加氢裂化重质烃油的催化剂包括主要由氧化铝或二氧化钛组成的多孔无机载体和与载体合成的两种或更多种催化金属组分。 催化金属组分的金属为（a）V和选自Zn，Fe，Co，Ni，Cu，Ag，Sn和Pb中的至少一种元素或（b）Mo和选自Zn，Cu中的至少一种元素 ，Ag，Sn，Pb和镧系元素。 催化剂具有直径为200安培或以上的孔中其总孔体积的至少60％，孔中总孔体积的至少40％，直径为300安培或以上且不超过其总数的20％ 直径至少为1000安的孔中的孔体积。 还公开了在上述催化剂存在下加氢裂化重质烃油的方法。

公开(公告)号：US20090105511A1

公开(公告)日：2009-04-23

申请号：US11922462

申请日：2006-06-19

申请人： Yoshimi Okada ,  Toshiji Makabe ,  Masashi Saito ,  Takako Nishijima

发明人： Yoshimi Okada ,  Toshiji Makabe ,  Masashi Saito ,  Takako Nishijima

IPC分类号： B01J27/02 ,  B01J27/053 ,  B01J31/02 ,  C07C5/367

CPC分类号： B01J27/053 ,  B01J21/04 ,  B01J23/42 ,  B01J23/464 ,  B01J27/045 ,  B01J35/008 ,  B01J35/0093 ,  B01J35/1019 ,  B01J35/1038 ,  B01J35/1061 ,  B01J37/0201 ,  B01J37/18 ,  B01J37/20 ,  C07C5/367 ,  Y02P20/52 ,  C07C15/06 ,  C07C15/24 ,  C07C15/02 ,  C07C15/27

摘要： Provided are: a uniformly, highly dispersed metal catalyst including a catalyst carrier and a catalyst metal being loaded thereon dispersed throughout the carrier, the uniformly, highly dispersed metal catalyst having excellent performances with respect to catalytic activity, selectivity, life, etc.; and a method of producing the same. The uniformly, highly dispersed metal catalyst includes a catalyst carrier made of a metal oxide and a catalyst metal having catalytic activity, the catalyst metal being loaded on the catalyst carrier, in which the catalyst carrier is a sulfur-containing catalyst carrier having sulfur or a sulfur compound almost evenly distributed throughout the carrier and the catalyst metal is loaded on the sulfur-containing catalyst carrier in a substantially evenly dispersed manner over the entire carrier substantially according to the distribution of the sulfur or the sulfur compound.

摘要翻译： 提供：均匀高度分散的金属催化剂，其包含分散在整个载体上的催化剂载体和催化剂金属，均匀高度分散的金属催化剂在催化活性，选择性，寿命等方面具有优异的性能; 及其制造方法。 均匀，高度分散的金属催化剂包括由金属氧化物制成的催化剂载体和具有催化活性的催化剂金属，催化剂金属负载在催化剂载体上，其中催化剂载体是具有硫或硫的催化剂载体 硫化合物几乎均匀分布在整个载体上，催化剂金属基本上按照硫或硫化合物的分布，以基本上均匀分散的方式载于整个载体上。

公开(公告)号：US5276232A

公开(公告)日：1994-01-04

申请号：US39179

申请日：1993-04-16

申请人： Shinichi Inoue ,  Toshiji Makabe ,  Tatsuo Morimoto ,  Kazutomo Shimizu

发明人： Shinichi Inoue ,  Toshiji Makabe ,  Tatsuo Morimoto ,  Kazutomo Shimizu

IPC分类号： B01J29/87 ,  C10G35/06 ,  C10G35/095 ,  C10G50/00 ,  C07C2/00

CPC分类号： C10G35/095 ,  B01J29/87 ,  C10G35/065 ,  C10G50/00

摘要： The process of this invention produces high-octane gasoline blending stock advantageously by treating light hydrocarbons mainly comprising of paraffins and/or olefins having 2 to 7 carbon atoms at a hydrogen partial pressure of 5 kg/cm.sup.2 or less and at a temperature of 350.degree. to 650.degree. C. in the presence of a catalyst composition containing ammonia-modified crystalline aluminogallosilicates of high initial activity and long life obtained by contacting hydrogen type aluminogallosilicates with ammonia under a dry condition as catalyst component.

摘要翻译： PCT No.PCT / JP92 / 01047 Sec。 371日期：1993年04月16日 102（e）日期1993年4月16日PCT提交1992年8月19日PCT公布。 出版物WO93 / 04145 日本1994年4月3日。本发明的方法有利地通过在5kg / cm 2或更低的氢分压下处理主要包含具有2至7个碳原子的链烷烃和/或烯烃的轻烃来生产高辛烷值汽油调配料 在350℃至650℃的温度下，在催化剂组合物存在下，该催化剂组合物含有氨基改性的结晶铝铝酸硅酸盐，其具有高的初始活性和长的使用寿命，其通过在干燥条件下使氢型铝焦铝酸盐与氨接触而作为催化剂组分。

公开(公告)号：US07943115B2

公开(公告)日：2011-05-17

申请号：US10484846

申请日：2002-01-15

申请人： Shinichi Inoue ,  Hidehiko Kudou ,  Akihiro Mutou ,  Tateo Ono ,  Toshiji Makabe ,  Toru Takatsuka ,  Hisashi Nomura

发明人： Shinichi Inoue ,  Hidehiko Kudou ,  Akihiro Mutou ,  Tateo Ono ,  Toshiji Makabe ,  Toru Takatsuka ,  Hisashi Nomura

IPC分类号： C01G23/047

CPC分类号： B01J21/063 ,  B01J21/06 ,  B01J21/066 ,  B01J23/28 ,  B01J23/85 ,  B01J23/88 ,  B01J23/882 ,  B01J23/883 ,  B01J23/888 ,  B01J27/188 ,  B01J35/10 ,  B01J35/1014 ,  B01J35/1019 ,  B01J35/1038 ,  B01J35/1042 ,  B01J35/1085 ,  B01J37/0009 ,  B01J37/036 ,  C01G23/04 ,  C01G23/0536 ,  C01G25/02 ,  C01P2002/72 ,  C01P2006/12 ,  C01P2006/14 ,  C01P2006/17 ,  C01P2006/21 ,  C01P2006/82 ,  C10G45/08

摘要： This invention relates to a 4 group metal oxide and to a method for preparation thereof and the 4 group metal oxide prepared by adding a particle growth inhibiter to a hydrosol a hydrogel or a dried product of a hydrous 4 group metal oxide represented by MO(2-x)(OH)2x (wherein M denotes a 4 group metal and x is a number greater than 0.1 or x>0.1) followed by drying and calcining has a specific surface area of 80 m2/g or more, a pore volume of 0.2 ml/g or more and a pore sharpness degree of 50% or more and excellent heat stability and is useful for a catalyst or a catalyst carrier in which a catalyst metal is dispersed to a high degree. This invention further relates to a porous 4 group metal oxide and to a method for preparation thereof and the 4 group metal oxide prepared by application of a pH swing operation is characterized by a large specific surface area, excellent heat stability, high dispersion of a catalyst metal and a controlled and sharp pore distribution and is useful for a catalyst or a catalyst carrier of excellent reaction selectivity.

摘要翻译： 本发明涉及一种4组金属氧化物及其制备方法以及通过向水溶胶中添加颗粒生长抑制剂而制备的4组金属氧化物，所述水凝胶或由MO（2）表示的含水4族金属氧化物的干燥产物 -x）（OH）2x（其中M表示4组金属，x是大于0.1或x> 0.1的数），随后干燥和煅烧的比表面积为80m 2 / g以上，孔体积 0.2ml / g以上，孔锐度为50％以上，热稳定性优异，可用于高催化剂金属分散的催化剂或催化剂载体。 本发明还涉及一种多孔4族金属氧化物及其制备方法，通过应用pH挥发操作制备的4组金属氧化物的特征在于具有大比表面积，优异的热稳定性，催化剂的高分散性 金属和可控且尖锐的孔分布，并且可用于具有优异反应选择性的催化剂或催化剂载体。

公开(公告)号：US5464593A

公开(公告)日：1995-11-07

申请号：US273874

申请日：1994-07-12

申请人： Kazuo Takahashi ,  Fumio Kumata ,  Hitoshi Nozaki ,  Shinichi Inoue ,  Toshiji Makabe

发明人： Kazuo Takahashi ,  Fumio Kumata ,  Hitoshi Nozaki ,  Shinichi Inoue ,  Toshiji Makabe

IPC分类号： B01J29/06 ,  B01J29/40 ,  B01J35/08 ,  B01J20/18

CPC分类号： B01J29/06 ,  B01J29/40 ,  B01J35/08 ,  B01J2229/42

摘要： A process for producing a spherical zeolite catalyst is disclosed, which comprises dropping a zeolite-containing alumina sol into a surfactant-containing oil phase from a dropping opening directly or through air to thereby form spherical droplets of the sol, and then allowing the droplets to gel in an aqueous alkaline solution phase underlying the oil phase and withdrawing the thus gelled droplets, said dropping of the sol being conducted while the dropping opening is being impulsed to thereby impart a spherical and uniform shape to the resulting zeolite particles containing alumina as a binder, and a novel apparatus therefor.

摘要翻译： 公开了一种制备球形沸石催化剂的方法，其包括将含沸石的氧化铝溶胶直接或通过空气从滴入口滴入含表面活性剂的油相中，从而形成溶胶的球形液滴，然后使液滴 凝胶在水相下面的碱性溶液相中并且抽出如此凝胶化的液滴，当滴下的开口被冲击时，所述溶胶的滴下被引导，从而赋予所得到的含有氧化铝作为粘合剂的沸石颗粒的球形和均匀形状 ，及其新颖的装置。