公开(公告)号：US20220123124A1

公开(公告)日：2022-04-21

申请号：US17165142

申请日：2021-02-02

Applicant: Taiwan Semiconductor Manufacturing Co., Ltd.

Inventor： Shih-Hang Chiu ,  Chung-Chiang Wu ,  Jo-Chun Hung ,  Wei-Cheng Wang ,  Kuan-Ting Liu ,  Chi On Chui

IPC: H01L29/49 ,  H01L27/092 ,  H01L29/06 ,  H01L29/423 ,  H01L29/786 ,  H01L21/02 ,  H01L21/28 ,  H01L21/8238 ,  H01L29/66

Abstract: Semiconductor devices having improved gate electrode structures and methods of forming the same are disclosed. In an embodiment, a semiconductor device includes a gate structure over a semiconductor substrate, the gate structure including a high-k dielectric layer; an n-type work function layer over the high-k dielectric layer; an anti-reaction layer over the n-type work function layer, the anti-reaction layer including a dielectric material; a p-type work function layer over the anti-reaction layer, the p-type work function layer covering top surfaces of the anti-reaction layer; and a conductive cap layer over the p-type work function layer.

公开(公告)号：US20200083108A1

公开(公告)日：2020-03-12

申请号：US16686388

申请日：2019-11-18

Applicant: Taiwan Semiconductor Manufacturing Co., Ltd.

Inventor： Cheng-Yen Tsai ,  Chung-Chiang Wu ,  Tai-Wei Hwang ,  Hung-Chin Chung ,  Wei-Chin Lee ,  Da-Yuan Lee ,  Ching-Hwanq Su ,  Yin-Chuan Chuang ,  Kuan-Ting Liu

IPC: H01L21/8234 ,  H01L29/51 ,  H01L21/02 ,  H01L27/088

Abstract: Embodiments disclosed herein relate to a pre-deposition treatment of materials utilized in metal gates of different transistors on a semiconductor substrate. In an embodiment, a method includes exposing a first metal-containing layer of a first device and a second metal-containing layer of a second device to a reactant to form respective monolayers on the first and second metal-containing layers. The first and second devices are on a substrate. The first device includes a first gate structure including the first metal-containing layer. The second device includes a second gate structure including the second metal-containing layer different from the second metal-containing layer. The monolayers on the first and second metal-containing layers are exposed to an oxidant to provide a hydroxyl group (—OH) terminated surface for the monolayers. Thereafter, a third metal-containing layer is formed on the —OH terminated surfaces of the monolayers on the first and second metal-containing layers.

公开(公告)号：US11594610B2

公开(公告)日：2023-02-28

申请号：US17165142

申请日：2021-02-02

Applicant: Taiwan Semiconductor Manufacturing Co., Ltd.

Inventor： Shih-Hang Chiu ,  Chung-Chiang Wu ,  Jo-Chun Hung ,  Wei-Cheng Wang ,  Kuan-Ting Liu ,  Chi On Chui

IPC: H01L29/49 ,  H01L27/092 ,  H01L29/06 ,  H01L29/423 ,  H01L29/786 ,  H01L21/02 ,  H01L21/28 ,  H01L21/8238 ,  H01L29/66

Abstract: Semiconductor devices having improved gate electrode structures and methods of forming the same are disclosed. In an embodiment, a semiconductor device includes a gate structure over a semiconductor substrate, the gate structure including a high-k dielectric layer; an n-type work function layer over the high-k dielectric layer; an anti-reaction layer over the n-type work function layer, the anti-reaction layer including a dielectric material; a p-type work function layer over the anti-reaction layer, the p-type work function layer covering top surfaces of the anti-reaction layer; and a conductive cap layer over the p-type work function layer.

公开(公告)号：US20230140968A1

公开(公告)日：2023-05-11

申请号：US18154087

申请日：2023-01-13

Applicant: Taiwan Semiconductor Manufacturing Co., Ltd.

Inventor： Shih-Hang Chiu ,  Chung-Chiang Wu ,  Jo-Chun Hung ,  Wei-Cheng Wang ,  Kuan-Ting Liu ,  Chi On Chui

IPC: H01L29/49 ,  H01L27/092 ,  H01L29/06 ,  H01L29/423 ,  H01L29/786 ,  H01L21/02 ,  H01L29/66 ,  H01L21/8238 ,  H01L21/28

CPC classification number: H01L29/4908 ,  H01L27/092 ,  H01L29/0673 ,  H01L29/42392 ,  H01L29/78696 ,  H01L21/02603 ,  H01L29/66742 ,  H01L21/823807 ,  H01L21/823842 ,  H01L21/823864 ,  H01L29/66553 ,  H01L29/66545 ,  H01L21/28088

Abstract: Semiconductor devices having improved gate electrode structures and methods of forming the same are disclosed. In an embodiment, a semiconductor device includes a gate structure over a semiconductor substrate, the gate structure including a high-k dielectric layer; an n-type work function layer over the high-k dielectric layer; an anti-reaction layer over the n-type work function layer, the anti-reaction layer including a dielectric material; a p-type work function layer over the anti-reaction layer, the p-type work function layer covering top surfaces of the anti-reaction layer; and a conductive cap layer over the p-type work function layer.

公开(公告)号：US11302582B2

公开(公告)日：2022-04-12

申请号：US16686388

申请日：2019-11-18

Applicant: Taiwan Semiconductor Manufacturing Co., Ltd.

Inventor： Cheng-Yen Tsai ,  Chung-Chiang Wu ,  Tai-Wei Hwang ,  Hung-Chin Chung ,  Wei-Chin Lee ,  Da-Yuan Lee ,  Ching-Hwanq Su ,  Yin-Chuan Chuang ,  Kuan-Ting Liu

IPC: H01L21/8234 ,  H01L27/088 ,  H01L21/02 ,  H01L29/51

Abstract: Embodiments disclosed herein relate to a pre-deposition treatment of materials utilized in metal gates of different transistors on a semiconductor substrate. In an embodiment, a method includes exposing a first metal-containing layer of a first device and a second metal-containing layer of a second device to a reactant to form respective monolayers on the first and second metal-containing layers. The first and second devices are on a substrate. The first device includes a first gate structure including the first metal-containing layer. The second device includes a second gate structure including the second metal-containing layer different from the second metal-containing layer. The monolayers on the first and second metal-containing layers are exposed to an oxidant to provide a hydroxyl group (—OH) terminated surface for the monolayers. Thereafter, a third metal-containing layer is formed on the —OH terminated surfaces of the monolayers on the first and second metal-containing layers.

公开(公告)号：US20200091006A1

公开(公告)日：2020-03-19

申请号：US16686408

申请日：2019-11-18

Applicant: Taiwan Semiconductor Manufacturing Co., Ltd.

Inventor： Cheng-Yen Tsai ,  Chung-Chiang Wu ,  Tai-Wei Hwang ,  Hung-Chin Chung ,  Wei-Chin Lee ,  Da-Yuan Lee ,  Ching-Hwanq Su ,  Yin-Chuan Chuang ,  Kuan-Ting Liu

IPC: H01L21/8234 ,  H01L21/02 ,  H01L29/51 ,  H01L27/088

Abstract: Embodiments disclosed herein relate to a pre-deposition treatment of materials utilized in metal gates of different transistors on a semiconductor substrate. In an embodiment, a method includes exposing a first metal-containing layer of a first device and a second metal-containing layer of a second device to a reactant to form respective monolayers on the first and second metal-containing layers. The first and second devices are on a substrate. The first device includes a first gate structure including the first metal-containing layer. The second device includes a second gate structure including the second metal-containing layer different from the second metal-containing layer. The monolayers on the first and second metal-containing layers are exposed to an oxidant to provide a hydroxyl group (—OH) terminated surface for the monolayers. Thereafter, a third metal-containing layer is formed on the —OH terminated surfaces of the monolayers on the first and second metal-containing layers.

公开(公告)号：US20190326281A1

公开(公告)日：2019-10-24

申请号：US15957912

申请日：2018-04-20

Applicant: Taiwan Semiconductor Manufacturing Co., Ltd.

Inventor： Ji-Cheng Chen ,  Ching-Hwanq Su ,  Kuan-Ting Liu ,  Shih-Hang Chiu

IPC: H01L27/088 ,  H01L29/51 ,  H01L29/49 ,  H01L29/423 ,  H01L29/06 ,  H01L21/8234 ,  H01L21/762 ,  H01L29/66 ,  H01L21/28 ,  H01L21/02 ,  H01L21/285

Abstract: A gate structure includes a gate dielectric layer, a work function layer, a metal layer, and a barrier layer. The work function layer is on the gate dielectric layer. The metal layer is over the work function layer. The barrier layer is sandwiched between the metal layer and the work function layer. The barrier layer includes silicon or aluminum.

公开(公告)号：US09837507B1

公开(公告)日：2017-12-05

申请号：US15281305

申请日：2016-09-30

Applicant: TAIWAN SEMICONDUCTOR MANUFACTURING CO., LTD.

Inventor： Yu-Sheng Wang ,  Chi-Cheng Hung ,  Da-Yuan Lee ,  Hsin-Yi Lee ,  Kuan-Ting Liu

IPC: H01L29/66 ,  H01L29/49

CPC classification number: H01L29/66545 ,  H01L29/4966 ,  H01L29/66795 ,  H01L29/7848 ,  H01L29/785

Abstract: A field effect transistor includes a channel layer made of a semiconductor and a metal gate structure. The metal gate structure includes a gate dielectric layer, a barrier layer formed on the gate dielectric layer, a work function adjustment layer formed on the barrier layer and made of one of Al and TiAl, a blocking layer formed on the work function adjustment layer and made of TiN, and a body metal layer formed on the blocking layer and made of W. A gate length over the channel layer is in a range from 5 nm to 15 nm, and a thickness of the first conductive layer is in a range of 0.2 nm to 3.0 nm. A range between a largest thickness and a smallest thickness of the first conductive layer is more than 0% and less than 10% of an average thickness of the first conductive layer.

公开(公告)号：US12148810B2

公开(公告)日：2024-11-19

申请号：US18154087

申请日：2023-01-13

Applicant: Taiwan Semiconductor Manufacturing Co., Ltd.

Inventor： Shih-Hang Chiu ,  Chung-Chiang Wu ,  Jo-Chun Hung ,  Wei-Cheng Wang ,  Kuan-Ting Liu ,  Chi On Chui

IPC: H01L29/49 ,  H01L21/02 ,  H01L21/28 ,  H01L21/8238 ,  H01L27/092 ,  H01L29/06 ,  H01L29/423 ,  H01L29/66 ,  H01L29/786

Abstract: Semiconductor devices having improved gate electrode structures and methods of forming the same are disclosed. In an embodiment, a semiconductor device includes a gate structure over a semiconductor substrate, the gate structure including a high-k dielectric layer; an n-type work function layer over the high-k dielectric layer; an anti-reaction layer over the n-type work function layer, the anti-reaction layer including a dielectric material; a p-type work function layer over the anti-reaction layer, the p-type work function layer covering top surfaces of the anti-reaction layer; and a conductive cap layer over the p-type work function layer.

公开(公告)号：US12142531B2

公开(公告)日：2024-11-12

申请号：US17661576

申请日：2022-05-02

Applicant: Taiwan Semiconductor Manufacturing Co., Ltd.

Inventor： Cheng-Yen Tsai ,  Chung-Chiang Wu ,  Tai-Wei Hwang ,  Hung-Chin Chung ,  Wei-Chin Lee ,  Da-Yuan Lee ,  Ching-Hwanq Su ,  Yin-Chuan Chuang ,  Kuan-Ting Liu

IPC: H01L21/8234 ,  H01L21/02 ,  H01L27/088 ,  H01L29/51

Abstract: Embodiments disclosed herein relate to a pre-deposition treatment of materials utilized in metal gates of different transistors on a semiconductor substrate. In an embodiment, a method includes exposing a first metal-containing layer of a first device and a second metal-containing layer of a second device to a reactant to form respective monolayers on the first and second metal-containing layers. The first and second devices are on a substrate. The first device includes a first gate structure including the first metal-containing layer. The second device includes a second gate structure including the second metal-containing layer different from the second metal-containing layer. The monolayers on the first and second metal-containing layers are exposed to an oxidant to provide a hydroxyl group (—OH) terminated surface for the monolayers. Thereafter, a third metal-containing layer is formed on the —OH terminated surfaces of the monolayers on the first and second metal-containing layers.