Catalytic system for CO2/epoxide copolymerization
    5.
    发明授权
    Catalytic system for CO2/epoxide copolymerization 有权
    CO2 /环氧化物共聚催化体系

    公开(公告)号:US08987411B2

    公开(公告)日:2015-03-24

    申请号:US12817588

    申请日:2010-06-17

    摘要: The present invention related to a method of manufacturing a polycarbonate including the process of copolymerizing epoxide compound and CO2 using cobalt(III) or chromium(III), where the ligands contains at least 3 ammonium cations, central metal has formal −1 charge, and conjugated anions of the two cationic ammonium groups are acid-base homoconjugation, as catalyst.According to the present invention, the initial induction time can be reduced when the said polycarbonate is manufactured and it is possible to improve the activity of the catalyst and the molecular weight of the obtained polymer.

    摘要翻译: 本发明涉及一种制备聚碳酸酯的方法,包括使用钴(III)或铬(III)共聚环氧化合物和CO 2的方法,其中配体含有至少3个铵阳离子,中心金属具有正电荷-1, 两个阳离子铵基团的共轭阴离子是酸碱共结合作为催化剂。 根据本发明,当制造所述聚碳酸酯时可以减少初始诱导时间,并且可以提高催化剂的活性和所得聚合物的分子量。

    EPOXY THERMOSET COMPOSITIONS COMPRISING EXCESS EPOXY RESIN AND PROCESS FOR THE PREPARATION THEREOF
    10.
    发明申请
    EPOXY THERMOSET COMPOSITIONS COMPRISING EXCESS EPOXY RESIN AND PROCESS FOR THE PREPARATION THEREOF 审中-公开
    包含环氧树脂的环氧热固化剂组合物及其制备方法

    公开(公告)号:US20100144965A1

    公开(公告)日:2010-06-10

    申请号:US12598520

    申请日:2008-04-22

    IPC分类号: C08L63/00 C08G65/02 C08G59/68

    CPC分类号: C08G59/18

    摘要: In one aspect, embodiments disclosed herein relate to a process for curing a thermoset composition, including: reacting a curable composition comprising an epoxy resin, an epoxy-reactive compound, and a catalyst, wherein there is a stoichiometric excess of the epoxy resin; to form an intermediate product having unreacted epoxy groups and secondary hydroxyl groups; and etherifying at least a portion of the unreacted epoxy groups and the secondary hydroxyl groups, catalyzed by the catalyst, to form a thermoset composition.

    摘要翻译: 一方面,本文公开的实施方案涉及用于固化热固性组合物的方法,包括:使包含环氧树脂,环氧反应性化合物和催化剂的可固化组合物反应,其中存在化学计量过量的环氧树脂; 形成具有未反应的环氧基和仲羟基的中间产物; 以及醚化由催化剂催化的至少一部分未反应的环氧基和仲羟基以形成热固性组合物。