Manufacture of copolymers of styrene and {60 -methylstyrene
    3.
    发明授权
    Manufacture of copolymers of styrene and {60 -methylstyrene 失效
    苯乙烯和{60-甲基苯乙烯共聚物的制备

    公开(公告)号:US3725506A

    公开(公告)日:1973-04-03

    申请号:US3725506D

    申请日:1971-11-16

    Applicant: BASF AG

    CPC classification number: C08F212/08 Y10S526/922

    Abstract: Continuous process for the manufacture of copolymers of styrene and Alpha -methylstyrene having a substantially statistical distribution of the monomers by anionic polymerization at low temperatures with thorough mixing of the reactants. The process is characterized in that at least part of the heat of reaction is removed by evaporative cooling and that the monomers are fed to the polymerization zone at different points.

    Abstract translation: 用于制备苯乙烯和α-甲基苯乙烯的共聚物的连续方法,其通过阴离子聚合在低温下通过反应物的充分混合具有单体的基本统计分布。

    Process for the preparation of block polymers
    8.
    发明授权
    Process for the preparation of block polymers 失效
    制备块状聚合物的方法

    公开(公告)号:US3732335A

    公开(公告)日:1973-05-08

    申请号:US3732335D

    申请日:1971-05-26

    Applicant: SOLVAY

    CPC classification number: C08F297/08

    Abstract: POLYPROPYLENE MODIFIED BY A RANDOM COPOLYMER OF PROPYLENE AND A SECOND A-OLEFIN IS PREPARED BY A TWOSTAGE PROCESS. IN THE FIRST STAGE, PROPYLENE IS POLYMERIZEDD IN THE PRESENCE OF VIOLET TICL3 AND DIALKYLALUMINUM MONOCHLORICE UNTIL POLYPROPYLENE IN AN AMOUNT OF ABOUT 80 TO 99% BY WEIGHT OF THE TOTAL QUANTITY OF POLYMER TO BE PREPARED HAS BEEN FORMED. A SECOND A-OLEFIN AND A SECOND ACTIVATOR CONSTITUTED BY TRIALKYLALUMINUM IS THEN ADDED TO THE SYSTEM AND IN A SECOND STAGE, THE POLYMERIZATION IS CONTINUED, PROPYLENE BEING POLYMERIZED WITH THE SECOND A-OLEFIN TO FORM A RANDOM COPOLYMER IN AN AMOUNT OF 1 TO 20% BY WEIGHT OF THE TOTAL QUANTITY OF POLYMER TO BE PREPARED.

    Hydrophilic chlorosulfonated block copolymers
    10.
    发明授权
    Hydrophilic chlorosulfonated block copolymers 失效
    水解氯化嵌段共聚物

    公开(公告)号:US3607979A

    公开(公告)日:1971-09-21

    申请号:US3607979D

    申请日:1968-10-24

    Applicant: SHELL OIL CO

    Abstract: Block copolymers are provided which retain a high degree of elastomeric properties while at the same time exhibiting a large water absorption capacity are especially useful for water desalinization purposes. These block copolymers comprise chlorosulfonated derivatives of block polymers wherein the terminal polymer blocks are either polyvinyl arene blocks or polyvinyl cycloalkane blocks while the center blocks are hydrogenated conjugated diene blocks or alpha-olefin copolymer blocks of elastomeric character. The end blocks may also comprise alpha-olefin thermoplastic blocks. The chlorosulfonation is carried to an extent sufficient to impart a hydrophilic character to the polymers and is characterized by a sulfur content in the order of 1-10 percent by weight of the block copolymer.

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