公开(公告)号：US08987395B2

公开(公告)日：2015-03-24

申请号：US13976284

申请日：2011-12-30

申请人： Kevin M. McCauley ,  Steven Luo

发明人： Kevin M. McCauley ,  Steven Luo

IPC分类号： C08F4/70 ,  C08F4/80 ,  C08F2/02 ,  C08F36/00 ,  C08F136/06 ,  C08F36/04

CPC分类号： C08F136/06 ,  C08F36/04 ,  Y10S526/902 ,  C08F4/7098

摘要： A process for preparing a polydiene, the process comprising the step of polymerizing conjugated diene monomer with a nickel-based catalyst system, where said step of polymerizing takes place within a polymerization mixture that includes less than 20% by weight of organic solvent based on the total weight of the polymerization mixture, where the temperature of the polymerization mixture is maintained below 34° C. during said step of polymerizing, and where the conversion of the conjugated diene monomer is maintained below 30%.

摘要翻译： 一种制备聚二烯的方法，该方法包括将共轭二烯单体与镍基催化剂体系聚合的步骤，其中所述聚合步骤在聚合混合物内进行，所述聚合混合物包含基于 聚合混合物的总重量，其中聚合混合物的温度在聚合步骤期间保持在34℃以下，共轭二烯单体的转化率保持在30％以下。

公开(公告)号：US07771834B2

公开(公告)日：2010-08-10

申请号：US12236837

申请日：2008-09-24

申请人： Tomoo Sugawara

发明人： Tomoo Sugawara

IPC分类号： B32B15/08 ,  C08G61/12 ,  B32B37/00

CPC分类号： B32B27/08 ,  B32B15/08 ,  B32B27/06 ,  B32B27/18 ,  B32B2398/20 ,  B32B2457/08 ,  C08G61/08 ,  C08J5/18 ,  C08J2365/00 ,  Y10S526/902 ,  Y10T428/2915 ,  Y10T428/2971 ,  Y10T428/31678

摘要： Process for production of post-crosslinkable thermoplastic resins by bulk-polymerizing a polymerizable composition (A) comprising (I) a monomer fluid containing a cyclic olefin (α) having two or more metathetical ring-opening reaction sites in the molecule in an amount 10 wt % or above based on the total amount of the monomers or a monomer fluid containing a norbornene monomer and a crosslinking agent, (II) a metathetical polymerization catalyst, and (III) a chain transfer agent; thermoplastic resins obtained by this process. These thermoplastic resins are free from odor due to residual monomers and are excellent in storage stability. Process for producing crosslinked resins and composite materials which comprises laminating the thermoplastic resin to a substrate and then crosslinking the thermoplastic resin. These crosslinked resins and composite materials are invention are excellent in electrical insulation properties, mechanical strength, heat resistance, and dielectric characteristics, and are useful as electrical materials.

摘要翻译： 通过使聚合性组合物（A）进行本体聚合来制造后交联性热塑性树脂的方法，其包含（I）含有分子中具有两个以上元素开环反应位点的环状烯烃（α）的单体流体，其量为10 基于单体或含有降冰片烯单体和交联剂的单体流体的总量，（II）微量聚合催化剂和（III）链转移剂的总重量％以上。 通过该方法获得的热塑性树脂。 这些热塑性树脂由于残留单体而没有气味，并且储存稳定性优异。 制造交联树脂和复合材料的方法，其包括将热塑性树脂层压到基底上，然后交联热塑性树脂。 这些交联树脂和复合材料本身具有优异的电绝缘性，机械强度，耐热性和介电特性，并且可用作电气材料。

公开(公告)号：US07687589B2

公开(公告)日：2010-03-30

申请号：US11893121

申请日：2007-08-14

申请人： Timothy L. Tartamella ,  William M. Cole ,  Mark Smale

发明人： Timothy L. Tartamella ,  William M. Cole ,  Mark Smale

IPC分类号： C08F4/80 ,  C08F2/38 ,  C08F4/52 ,  C08F36/04 ,  C08F2/02

CPC分类号： C08F36/04 ,  C08F6/005 ,  Y10S526/902 ,  C08F4/545 ,  C08F2/001 ,  C08L47/00

摘要： A method for the continuous production of polydienes, the method comprising the steps of (a) charging a mixture of one or more monomer, catalyst system, and less than 50% weight percent organic solvent based on the total weight of the monomer, catalyst and solvent, into first vessel, (b) polymerizing the monomer to a conversion of up to 20% by weight of the monomer to form a mixture of reactive polymer and monomer, (c) removing the mixture of reactive polymer and monomer from the vessel, and (d) terminating the reactive polymer prior to a total monomer conversion of 25% by weight.

摘要翻译： 一种连续生产聚二烯的方法，所述方法包括以下步骤：（a）将单体，催化剂体系和小于50％重量百分比的有机溶剂的混合物以单体，催化剂和 溶剂进入第一容器，（b）将单体聚合至高达单体重量的20％的转化率以形成反应性聚合物和单体的混合物，（c）从容器中除去反应性聚合物和单体的混合物， 和（d）在总单体转化率为25重量％之前终止反应性聚合物。

公开(公告)号：US20090281257A1

公开(公告)日：2009-11-12

申请号：US12296797

申请日：2007-04-02

申请人： Baochen Huang ,  Zhichao Zhao ,  Wei Yao ,  Aihua Du ,  Yongxian Zhao

发明人： Baochen Huang ,  Zhichao Zhao ,  Wei Yao ,  Aihua Du ,  Yongxian Zhao

IPC分类号： C08F2/01

CPC分类号： C08F136/08 ,  Y10S526/902 ,  Y10S526/904 ,  Y10S526/905 ,  C08F2/01 ,  C08F2/02

摘要： A synthesis process of trans-1,4-polyisoprene, using bulk precipitation polymerization of isoprene catalyzed by supported titanium catalyst TiCl4/MgCl2. The process includes prepolymerizing carried out in a prepolymerization reactor with an anchor agitator; polymerizing carried out in a polymerization reactor with a helical ribbon agitator; and devolatilizing and drying carried out in a vacuum rake dryer. Not only does the process require lower energy consumption and thus a lower production cost, but it also eliminates the emission of three wastes.

摘要翻译： 由负载钛催化剂TiCl4 / MgCl2催化的异戊二烯的体积沉淀聚合反式-1,4-聚异戊二烯的合成方法。 该方法包括在预聚合反应器中用锚式搅拌器进行预聚合; 在具有螺旋状带状搅拌器的聚合反应器中进行聚合; 并在真空耙式干燥器中进行脱挥发和干燥。 该方法不仅需要较低的能源消耗，而且降低了生产成本，同时也消除了三种废物的排放。

公开(公告)号：US20090163678A1

公开(公告)日：2009-06-25

申请号：US12291898

申请日：2008-11-14

申请人： Gabor Kiss ,  Robert Patrick Reynolds, JR. ,  John W. Chu ,  Steven P. Rucker ,  James Richardson Lattner

发明人： Gabor Kiss ,  Robert Patrick Reynolds, JR. ,  John W. Chu ,  Steven P. Rucker ,  James Richardson Lattner

IPC分类号： C08F2/01 ,  C08F4/06 ,  C08F210/02

CPC分类号： C08F210/16 ,  C08F4/65908 ,  C08F4/65927 ,  C08F210/06 ,  Y10S526/902 ,  C08F2/02 ,  C08F2/14 ,  C08F2500/03 ,  C08F2500/12

摘要： Provided are bulk homogeneous polymerization processes for producing ethylene propylene random copolymers. The process includes contacting in a reactor or in a series of reactors propylene monomer, ethylene comonomer with one or more catalyst systems and optional solvent (present at less than 40 wt %), wherein the reactor train is at a temperature of between 65° C. and 180° C. and at a pressure no lower than 10 MPa below the cloud point pressure of the polymerization system and less than 1500 MPa, and wherein the polymerization system for the reactor train is in its dense fluid state to form a polymer reactor effluent including a homogeneous fluid phase polymer-monomer mixture in the reactor train; and wherein the resultant copolymer product comprises between 10 wt % and 20 wt % randomly distributed ethylene and the concentration of total region defects in the continuous propylene segments of the random EP copolymer is between 40 and 150% greater than in a copolymer of equivalent melt flow rate and wt % ethylene polymerized by a solution polymerization process.

摘要翻译： 提供用于生产乙烯丙烯无规共聚物的本体均相聚合方法。 该方法包括使反应器或一系列反应器中的丙烯单体，乙烯共聚单体与一种或多种催化剂体系和任选的溶剂（以小于40wt％存在）接触，其中反应器系在65℃ 并且在低于聚合体系的浊点压力不低于10MPa的压力下低于1500MPa，并且其中反应器系列的聚合系统处于其致密的流体状态以形成聚合物反应器 流出物包括在反应器系列中的均相流体相聚合物 - 单体混合物; 并且其中所得共聚物产物包含10重量％至20重量％的随机分布的乙烯，并且随机EP共聚物的连续丙烯链段中总区域缺陷的浓度比当量熔体流动的共聚物中的区域间缺陷的浓度高40至150％ 速率和wt％乙烯通过溶液聚合方法聚合。

公开(公告)号：US20090042720A1

公开(公告)日：2009-02-12

申请号：US10587058

申请日：2006-07-21

申请人： Floran Prades ,  Christophe Boisson ,  Roger Spitz ,  Abbas Razavi

发明人： Floran Prades ,  Christophe Boisson ,  Roger Spitz ,  Abbas Razavi

IPC分类号： B01J31/12 ,  C01B7/19 ,  C01B33/10 ,  B32B5/16

CPC分类号： C08F10/00 ,  C08F4/65912 ,  C08F4/65927 ,  C08F110/02 ,  C08F110/06 ,  C08F210/16 ,  Y10S526/902 ,  Y10S526/907 ,  Y10S526/943 ,  Y10T428/2982 ,  C08F4/65916 ,  C08F4/025 ,  C08F2500/15 ,  C08F2500/12 ,  C08F2500/18 ,  C08F210/14

摘要： The present invention relates to a process for preparing an activating support for metallocene complexes in the polymerisation of olefins comprising the steps of: I) providing a support prepared consisting in particles formed from at least one porous mineral oxide; II) optionally fixing the rate of silanols on the surface of the support; III) functionalising the support with a solution containing a fluorinated functionalising agent; IV) heating the functionalised and fluorinated support of step c) under an inert gas and then under oxygen; V) retrieving an active fluorinated support. That activating support is used to activate a metallocene catalyst component for the polymerisation of olefins.

摘要翻译： 本发明涉及一种在烯烃聚合中制备茂金属络合物的活化载体的方法，包括以下步骤：I）提供由至少一种多孔矿物氧化物形成的颗粒制备的载体; II）任选地将硅烷醇的速率固定在载体的表面上; III）使用含氟官能化剂的溶液功能化载体; IV）在惰性气体下，然后在氧气下加热步骤c）的官能化和氟化载体; V）检索活性氟化支持物。 该活化载体用于活化用于烯烃聚合的茂金属催化剂组分。

公开(公告)号：US20070191563A1

公开(公告)日：2007-08-16

申请号：US11783705

申请日：2007-04-11

申请人： Tomoo Sugawara

发明人： Tomoo Sugawara

IPC分类号： C08F136/00

CPC分类号： B32B27/08 ,  B32B15/08 ,  B32B27/06 ,  B32B27/18 ,  B32B2398/20 ,  B32B2457/08 ,  C08G61/08 ,  C08J5/18 ,  C08J2365/00 ,  Y10S526/902 ,  Y10T428/2915 ,  Y10T428/2971 ,  Y10T428/31678

摘要： The invention relates to a process for the production of post-crosslinkable thermoplastic resins by bulk-polymerizing a polymerizable composition (A) comprising (I) a monomer fluid containing a cyclic olefin (α) having two or more metathetical ring-opening reaction sites in the molecule in an amount 10 wt % or above based on the total amount of the monomers or a monomer fluid containing a norbornene monomer and a crosslinking agent, (II) a metathetical polymerization catalyst, and (III) a chain transfer agent; thermoplastic resins obtained by this process; and a process for producing crosslinked resins or crosslinked resin composite materials which comprises laminating such a thermoplastic resin with a substrate at need and then crosslinking the thermoplastic resin. According to the invention, thermoplastic resins which are free from odor due to residual monomers and excellent in storage stability can be efficiently obtained by a simple process of bulk-polymerizing the composition (A). The process is not only easy and simple but also applicable to continuous production, thus being industrially advantageous. The crosslinked resins and crosslinked resin composite materials obtained according to the invention are excellent in electrical insulation properties, mechanical strengths, heat resistance, dielectric characteristics and so on, thus being useful as electrical materials or the like.

摘要翻译： 本发明涉及一种通过使聚合性组合物（A）进行本体聚合来制备后交联性热塑性树脂的方法，所述聚合性组合物（A）包含（I）含有具有两个以上元素开环反应位点的环状烯烃（α）的单体流体， 基于单体或含有降冰片烯单体和交联剂的单体流体的总量，（II）微分聚合催化剂和（III）链转移剂的量的10重量％以上的分子; 通过该方法获得的热塑性树脂; 以及用于生产交联树脂或交联树脂复合材料的方法，其包括在需要时将这种热塑性树脂与基底层压，然后交联热塑性树脂。 根据本发明，通过本体聚合组合物（A）的简单方法可以有效地获得由于残留单体而没有气味并且储存稳定性优异的热塑性树脂。 该方法不仅容易和简单，而且适用于连续生产，在工业上具有优势。 根据本发明获得的交联树脂和交联树脂复合材料具有优异的电绝缘性能，机械强度，耐热性，介电特性等，因此可用作电气材料等。

公开(公告)号：US07220804B1

公开(公告)日：2007-05-22

申请号：US09687734

申请日：2000-10-13

申请人： Sun-Chueh Kao

发明人： Sun-Chueh Kao

IPC分类号： C08F4/44

CPC分类号： C08F10/00 ,  C08F4/65904 ,  C08F4/65912 ,  C08F110/02 ,  Y10S526/902 ,  Y10S526/943 ,  C08F4/65916 ,  C08F2500/12

摘要： The present invention relates to a supported catalyst composition and a method for making the supported catalyst composition and its use in a process for polymerizing olefin(s). In particular, the invention is directed to a method for making a supported catalyst composition by contacting a supported activator with a bulky ligand and a metal compound.

摘要翻译： 负载型催化剂组合物及其制备方法技术领域本发明涉及负载型催化剂组合物及其制造方法及其在烯烃聚合方法中的应用。 特别地，本发明涉及通过使负载的活化剂与大体积配体和金属化合物接触来制备负载型催化剂组合物的方法。

公开(公告)号：US20050090619A1

公开(公告)日：2005-04-28

申请号：US10500422

申请日：2002-12-27

申请人： Nobuyoshi Yoshimura ,  Yuji Moriya

发明人： Nobuyoshi Yoshimura ,  Yuji Moriya

IPC分类号： C09J7/02 ,  C08F2/22 ,  C08F2/30 ,  C08F2/44 ,  C08F265/00 ,  C08F265/02 ,  C08F265/04 ,  C08F265/06 ,  C08F291/00 ,  C08L51/00 ,  C09J133/04 ,  C09J133/06 ,  C09J151/00 ,  C09J151/06 ,  C08F2/00

CPC分类号： C08F265/06 ,  C08F2/22 ,  C08F265/02 ,  C08F265/04 ,  C08F291/00 ,  C08L51/003 ,  C08L2666/02 ,  C09J151/003 ,  C09J2201/606 ,  Y10S526/902

摘要： There is provided a synthetic resin emulsion comprising polymer particles having a core/shell structure, wherein the shell comprises a copolymer of an unsaturated carboxylic acid and a hydrophilic comonomer, the core comprises a copolymer of a monomer mixture comprising a radically polymerizable main monomer and a radically polymerizable functional monomer, and the monomers constituting the monomer mixture are selected so that the glass transition point (Tg) of the copolymer produced by polymerization is −20° C. or below, and the synthetic resin emulsion has been produced by adding the monomer mixture for core formation and a pH adjustor to an aqueous copolymer solution, which has not been neutralized, produced by polymerizing the unsaturated carboxylic acid and the hydrophilic comonomer in an aqueous medium, and allowing a polymerization reaction to proceed. The use of the synthetic resin emulsion can provide a pressure-sensitive adhesive which has excellent adhesive properties such as adhesive strength, cohesive force and tackiness and can be easily swollen with water without any treatment with an alkali.

摘要翻译： 提供了包含具有核/壳结构的聚合物颗粒的合成树脂乳液，其中所述壳包含不饱和羧酸和亲水共聚单体的共聚物，所述核包含单体混合物的共聚物，所述单体混合物包含可自由基聚合的主单体和 可自由基聚合的官能单体和构成单体混合物的单体的选择，使得通过聚合制备的共聚物的玻璃化转变点（Tg）为-20℃以下，合成树脂乳液通过添加单体 用于芯形成的混合物和通过在水性介质中聚合不饱和羧酸和亲水性共聚单体并使聚合反应进行而产生的尚未中和的水性共聚物溶液的pH调节剂。 使用合成树脂乳液可以提供粘合强度，内聚力和粘合性优异的粘合性的粘合剂，并且可以在不用碱处理的情况下容易地用水溶胀。

公开(公告)号：US06586094B1

公开(公告)日：2003-07-01

申请号：US09443695

申请日：1999-11-19

申请人： Serge Rebouillat ,  Friedrich V. Pfister

发明人： Serge Rebouillat ,  Friedrich V. Pfister

IPC分类号： D02G300

CPC分类号： D06M15/285 ,  C03C25/26 ,  D06M13/507 ,  D06M13/513 ,  D06M15/263 ,  D06M15/643 ,  D06M15/647 ,  D06M23/08 ,  D06M23/10 ,  G02B6/4494 ,  H01B7/288 ,  Y10S526/902 ,  Y10S526/922 ,  Y10T428/2913 ,  Y10T428/2927 ,  Y10T428/2929 ,  Y10T428/2933 ,  Y10T428/2969

摘要： The present invention relates to a fiber coated with a water blocking material that includes an essentially water free dispersion comprising a superabsorbent polymer and a dispersing medium. The fibers made according to this invention may be used, for example, as fiber reinforcing material used in the manufacture of cables, and in particular in yarns for fiber optical cables that use optical light wave guides for optical communication transmissions.