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    Method for desulphurising acid gases using catalysts are insensitive to oxidation and contain aminocarboxylate
    1.
    发明申请
    Method for desulphurising acid gases using catalysts are insensitive to oxidation and contain aminocarboxylate 失效
    使用催化剂对酸性气体脱硫的方法对氧化不敏感并含有氨基羧酸盐

    公开(公告)号：US20040241068A1

    公开(公告)日：2004-12-02

    申请号：US10488921

    申请日：2004-03-12

    Inventor： Werner Hesse ,  Hans-Ulrich Jager

    IPC: C07F015/02

    CPC classification number: B01D53/1493 ,  B01D53/1468

    Abstract: A process is described for the catalytic removal of H2S gas from a sour gas stream in the presence of a chelate ligand of the formula (I) 1 where: X is hydrogen, an alkali metal or NH4null, n is 1, 2 or 3, and at least one of the radicals R1 to R6 is alkyl, aryl, alkyloxy, aryloxy, carboxyl or hydroxyl, the remaining radicals being hydrogen, and the metal in the metal chelate complex is a polyvalent metal, which can occur in more than one oxidation state. A mixture is also described for removing H2S gas from a sour gas stream, the mixture comprising an aminocarboxylate-containing metal chelate complex, and the use is also described of an aminocarboxylate-containing metal chelate complex for removing H2S gas from a sour gas stream.

    Abstract translation: 描述了在存在式（I）的螯合配体的情况下从酸性气流催化除去H 2 S气体的方法，其中：X是氢，碱金属或NH 4 +，n是1,2或 3，并且R 1至R 6中的至少一个基团是烷基，芳基，烷氧基，芳氧基，羧基或羟基，剩余的基团是氢，并且金属螯合络合物中的金属是多价金属， 其可以发生在多于一个氧化态。 还描述了用于从酸性气流中除去H 2 S气体的混合物，该混合物包含含氨基羧酸盐的金属螯合物络合物，并且还描述了用于从酸性气流中除去H 2 S气体的含氨基羧酸盐的金属螯合物络合物。

    Ferrocenyl diphosphines and their use
    3.
    发明申请
    Ferrocenyl diphosphines and their use 有权
    二茂铁二膦及其用途

    公开(公告)号：US20030212284A1

    公开(公告)日：2003-11-13

    申请号：US10312816

    申请日：2002-12-31

    Inventor： Walter Weissensteiner ,  Thomas Sturm ,  Felix Spindler

    IPC: C07F015/02 ,  C07C29/60 ,  C07C029/04 ,  C07C041/06

    CPC classification number: B01J31/2409 ,  B01J31/2295 ,  B01J31/24 ,  B01J2231/643 ,  B01J2231/645 ,  B01J2531/16 ,  B01J2531/17 ,  B01J2531/18 ,  B01J2531/31 ,  B01J2531/822 ,  B01J2531/824 ,  B01J2531/827 ,  B01J2531/828 ,  B01J2531/84 ,  C07B53/00 ,  C07C67/31 ,  C07C231/18 ,  C07F17/02 ,  C07C69/68

    Abstract: Compounds of the formula (I) and (Ia) in the form of racemates, mixtures of diastereomers or in essentially enantiomerically pure form, (I), (Ia), where R is hydrogen, C1-C8alkyl, C5-C12cycloakyl, phenyl or phenyl substituted by from 1 to 3 C1-C4alky or C1-C4alkoxy groups; n is 0 or an integer from 1 to 4 and R1 are identical or different subtitutuents selected from the group consisting of C1-C4alkyl, C1-C4fluoroalkyl and C1-C4alkoxy; X1 and X2 are each, indenpendently of one another, secondary phosphino; T is C6-C20arylene or C3-C16heteroarylene; and X2 is bound in the ortho position relative to the T-cyclopenitadienyl bond. The compounds are ligands for complexes of metal selected from transition groups (I) and (VIII) of the Periodic Table of the Elements, and these metal complexes are valuable catalysts for the asymmetric addition of hydrogen, boron hydrides or silanes onto carbon-carbon or carbon-heteroatom multiple bonds in prochiral organic compounds or the asymmetric addition of carbon nucleophiles or amines onto allyl compounds. 1

    Abstract translation: 式（I）和（Ia）化合物为外消旋体形式，非对映异构体混合物或基本上为对映体纯形式的（I），（Ia），其中R为氢，C 1 -C 8烷基，C 5 -C 12环烷基，苯基或 被1至3个C 1 -C 4烷基或C 1 -C 4烷氧基取代的苯基; n为0或1至4的整数，R 1为选自C 1 -C 4烷基，C 1 -C 4氟烷基和C 1 -C 4烷氧基的相同或不同的选择基团; X1和X2各自独立地为二次膦基; T是C 6 -C 20亚芳基或C 3 -C 16亚芳基; 并且X2相对于T-环戊二烯基键在邻位上结合。 这些化合物是选自元素周期表的转变基团（I）和（VIII）的金属络合物的配体，这些金属络合物是用于将氢，硼氢化物或硅烷不对称加成到碳 - 碳上的有价值的催化剂 前手性有机化合物中的碳 - 杂原子多重键或碳亲核试剂或胺不对称加成到烯丙基化合物上。

    Catalyst based on cobalt and/or rhodium employed in a two-phase medium
    4.
    发明申请
    Catalyst based on cobalt and/or rhodium employed in a two-phase medium 有权
    基于在两相介质中使用的钴和/或铑的催化剂

    公开(公告)号：US20030055299A1

    公开(公告)日：2003-03-20

    申请号：US10193705

    申请日：2002-07-12

    Applicant: Institut Francais du Petrole

    Inventor： Gerhard Hillebrand ,  Andre Hirschauer ,  Dominique Commereuc ,  Helene Olivier-Bourbigou ,  Lucien Saussine

    IPC: C07F015/02 ,  C07F015/06 ,  C07C027/12

    CPC classification number: C07C45/50 ,  C07C47/02

    Abstract: An improved catalyst based on cobalt and/or rhodium dissolved in a non-aqueous ionic solvent which is liquid at a temperature of less than 90null C. More particularly, the catalyst comprises at least one complex of cobalt and/or rhodium coordinated with at least one nitrogen-containing ligand and the non-aqueous ionic solvent comprises at least one quaternary ammonium and/or phosphonium cation and at least one inorganic anion.

    Abstract translation: 一种基于溶解在低于90℃温度下为液体的非水离子溶剂中的钴和/或铑的改进的催化剂。更具体地说，催化剂包括至少一种与ium配位的钴和/或铑络合物 至少一种含氮配体和非水离子溶剂包含至少一种季铵和/或鏻阳离子和至少一种无机阴离子。

    S, S-ethylenediamine-N, N'-disuccinic acid iron alkali salt and a process for production thereof
    5.
    发明申请
    S, S-ethylenediamine-N, N'-disuccinic acid iron alkali salt and a process for production thereof 有权
    S，S-乙二胺-N，N'-二琥珀酸铁碱金属盐及其制备方法

    公开(公告)号：US20020040156A1

    公开(公告)日：2002-04-04

    申请号：US09931245

    申请日：2001-08-17

    Applicant: Mitsubishi Rayon Co., Ltd.

    Inventor： Toshitake Yamakawa ,  Haruo Sakai

    IPC: C07F015/02

    CPC classification number: C07D241/06 ,  C07C227/18 ,  C07C227/40 ,  C07C229/24 ,  C07D241/08

    Abstract: An S,S-ethylenediamine-N,Nnull-disuccinic acid iron alkali salt which contains a lactam compound represented by the following general formula (1): 1 wherein M is an ammonium ion or an alkali metal ion, and an ethylenediaminemonosuccinic acid represented by the following general formula (2): 2 wherein M is an ammonium ion or an alkali metal ion, in an amount of 7 wt % or less, respectively.

    Abstract translation: 一种含有由以下通式（1）表示的内酰胺化合物的S，S-乙二胺-N，N'-二琥珀酸铁碱金属盐：其中M是铵离子或碱金属离子，和由以下化学式表示的乙二胺一琥珀酸： 以下通式（2）：其中M为铵离子或碱金属离子，分别为7重量％以下。

    Process for producing ferrous picrate and a fuel additive containing ferrous picrate from wire
    8.
    发明申请
    Process for producing ferrous picrate and a fuel additive containing ferrous picrate from wire 有权

    公开(公告)号：US20030213167A1

    公开(公告)日：2003-11-20

    申请号：US10150224

    申请日：2002-05-16

    Inventor： David M. Stewart

    IPC: C07F015/02 ,  C10L001/22

    CPC classification number: C10L1/231 ,  C07C205/24

    Abstract: A process for producing ferrous picrate and a fuel additive containing ferrous picrate involving placing wire composed of an alloy of iron in any solution of picric acid in a solvent that is known in the art for reacting with iron to produce ferrous picrate. The wire can be suspended in the solution or placed upon the bottom of a reaction vessel that holds the solution. Preferably the wire is loosely coiled, at least when placed upon the bottom of a reaction vessel. Also preferably, after a concentrated fuel additive has been prepared, to the concentrate is added so much of a pre-mix solution produced by the steps of (a) dissolving picric acid in the same kind of solvent that was utilized to produce the solution into which the steel wool was placed and (b) removing water from the precursor to the pre-mix solution thus produced and so much of the same kind of alcohol that was utilized to produce the solution into which the steel wool was placed that the final product produced thereby contains approximately 1.9 percent free picric acid and 15 to 16 percent of the alcohol.

    Ligands and catalyst systems thereof for ethylene oligomerisation to linear alpha olefins
    9.
    发明申请
    Ligands and catalyst systems thereof for ethylene oligomerisation to linear alpha olefins 失效
    用于乙烯低聚至直链α-烯烃的配体及其催化剂体系

    公开(公告)号：US20030119921A1

    公开(公告)日：2003-06-26

    申请号：US10208535

    申请日：2002-07-30

    Inventor： Eric Johannes Maria De Boer ,  Harry Van Der Heijden ,  Wilhelmina Cornelia Verhoef-Van Wijk ,  Arie Van Zon

    IPC: C07F015/02 ,  C07C027/06 ,  C07C002/02

    CPC classification number: C08F10/00 ,  C07F15/025 ,  C07F15/065 ,  C07F17/00 ,  Y02P20/582 ,  C08F4/7042

    Abstract: Mixed bis-imine pyridine ligands of formula (I), wherein Z1, which is different from Z2, is an optionally substituted aryl group; and Z2 comprises an optionally substituted heterohydrocarbyl moiety, or an optionally substituted aryl group in combination with a metal, said optionally substituted aryl group being null-co-ordinated to the metal; 1 mixed bis-imine pyridine complexes comprising a ligand of formula (I); mixed ionic bis-imine pyridine complexes comprising a ligand of formula (I); and processes for the production of alpha olefins from ethylene, using said complexes.

    Abstract translation: 式（I）的混合双亚胺吡啶配体，其中不同于Z 2的Z 1是任选取代的芳基; 和Z2包含任选取代的杂烃基部分，或与金属组合的任选取代的芳基，所述任选取代的芳基与金属配位; 包含式（I）的配体的混合的双亚胺吡啶络合物; 包含式（I）的配体的混合离子双亚胺吡啶络合物; 以及使用所述复合物从乙烯生产α-烯烃的方法。

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