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    Oligomerization process
    1.
    发明申请
    Oligomerization process 失效
    低聚过程

    公开(公告)号：US20040220440A1

    公开(公告)日：2004-11-04

    申请号：US10425430

    申请日：2003-04-29

    发明人： Jihad Mohammed Dakka ,  Hans K.T. Goris ,  Georges M.K. Mathys ,  Stephen Harold Brown ,  Bruce R. Cook

    IPC分类号： C07C002/02

    CPC分类号： C07C2/12 ,  C07C11/02 ,  C07C2529/85

    摘要： In a process for oligomerizing an olefinic hydrocarbon feedstock comprising sulfur-containing molecules, the feedstock is contacted in the absence of hydrogen with a first metal oxide catalyst at a temperature in excess of 150null C. and then is contacted under olefin oligomerization conditions with a second catalyst comprising a crystalline molecular sieve, such as ZSM-22 or ZSM-57.

    摘要翻译： 在包含含硫分子的烯属烃原料低聚的方法中，原料在不存在氢气的情况下与第一金属氧化物催化剂在超过150℃的温度下接触，然后在烯烃低聚条件下与 第二催化剂包含结晶分子筛，例如ZSM-22或ZSM-57。

    Process for producing low polymer of alpha-olefin
    2.
    发明申请
    Process for producing low polymer of alpha-olefin 有权
    生产α-烯烃低聚物的方法

    公开(公告)号：US20040199037A1

    公开(公告)日：2004-10-07

    申请号：US10487728

    申请日：2004-02-25

    发明人： Ryoichi Kobayashi ,  Shigeki Kura

    IPC分类号： C07C002/02

    CPC分类号： C08F2/00 ,  C08F10/00 ,  C08F10/02 ,  C08F110/02 ,  Y10S585/901 ,  C08F2/06 ,  C08F2500/02

    摘要： A process for producing an null-olefin oligomer by oligomerization of an null-olefin in a presence of a Ziegler-based catalyst, the process comprising introducing at least a portion of a reaction product which is taken out of a reactor and has a temperature of 115null C. or higher into an external heat exchanger, cooling the introduced reaction product, maintaining an oligomerization solution taken out of the external heat exchanger at a temperature of 110null C. or higher and returning at least a portion of the oligomerization solution to the reactor. In the production of an null-olefin oligomer, precipitation and adhesion of polymers at the inside of manufacturing apparatuses such as the external heat exchanger and troubles caused thereby can be prevented and a stable continuous operation can be continued for a long time.

    摘要翻译： 一种在齐格勒基催化剂存在下通过α-烯烃低聚生产α-烯烃低聚物的方法，该方法包括将至少一部分从反应器中取出的反应产物引入并具有 115℃以上进入外部热交换器，冷却引入的反应产物，将从外部热交换器取出的低聚溶液在110℃以上的温度下保持，并将至少一部分低聚溶液返回到 反应堆。 在α-烯烃低聚物的制备中，可以防止诸如外部热交换器的制造装置内部的聚合物的沉淀和粘附以及由此引起的故障，并且可以长时间持续稳定的连续操作。

    Dimerization of olefins
    5.
    发明申请
    Dimerization of olefins 有权
    烯烃二聚

    公开(公告)号：US20040030212A1

    公开(公告)日：2004-02-12

    申请号：US10312704

    申请日：2003-06-30

    发明人： Farouk Al-Soufi ,  Sami A.I. Barri ,  Yajnavalkya Subrai Bhat ,  Altaf Husain

    IPC分类号： C07C002/02 ,  C07C002/04

    CPC分类号： C07C2/12 ,  C07C2529/70 ,  C07C2529/85

    摘要： A process for the dimerization of at least one olefin with a carbon number between 2 and 10 by contacting the feed with a catalyst system comprising at least: (a) tectometallosilicate zeolite with having TON-type structure, (b) tectometalloslicate zeolite with having MTT-type structure, (c) tectometallosilicate zeolite with the same structure as that of the ZSM-48 zeolite, or (d) silicoaluminophosphate (SAPO) zeo-type with AEL-type structure; under dimerization condition to produce highly branched olefins.

    摘要翻译： 通过使进料与至少包含以下的催化剂体系（a）具有TON型结构的组成层硅酸盐沸石，（b）具有MTT的组织筛选沸石的沸石接触，使碳原子数为2至10的至少一种烯烃二聚化的方法 （c）具有与ZSM-48沸石相同结构的结构硅酸盐硅酸盐沸石，或（d）具有AEL型结构的硅铝磷酸盐（SAPO）zeo型; 在二聚条件下产生高度支化的烯烃。

    Olefin oligomerization
    6.
    发明申请
    Olefin oligomerization 有权
    烯烃低聚

    公开(公告)号：US20040015028A1

    公开(公告)日：2004-01-22

    申请号：US10201203

    申请日：2002-07-22

    发明人： Stephen Harold Brown ,  Georges M.K. Mathys

    IPC分类号： C07C002/02

    CPC分类号： C07C2/12 ,  C07C2527/173 ,  C07C2529/08 ,  C07C2529/18 ,  C07C2529/40 ,  C07C2529/50

    摘要： This invention is to a method of oligomerizing an olefin feed stream. The olefin feed stream contains at least one C2 to C12 olefin to obtain an olefin feed stream and has from about 1,000 ppm to about 10 percent by weight oxygenated hydrocarbon. The olefin is oligomerized by contacting with an acid based oligomerization catalyst.

    摘要翻译： 本发明是一种使烯烃进料流低聚的方法。 烯烃进料流含有至少一种C 2至C 12烯烃以获得烯烃进料流并具有约1,000ppm至约10重量％的氧化烃。 通过与酸基低聚催化剂接触来使烯烃低聚。

    Novel transition metal complexes and their use in transition metal-catalysed reactions
    7.
    发明申请
    Novel transition metal complexes and their use in transition metal-catalysed reactions 审中-公开
    新型过渡金属络合物及其在过渡金属催化反应中的应用

    公开(公告)号：US20030220512A1

    公开(公告)日：2003-11-27

    申请号：US10439159

    申请日：2003-05-16

    发明人： Siegfried Blechert

    IPC分类号： C07F015/00 ,  C07C002/02

    CPC分类号： C07F15/0046

    摘要： The invention relates to novel transition metal complexes of the formula (I) 1 to processes for preparing these transition metal complexes, to intermediates for preparing them, and also to the use of the transition metal complexes as catalysts in organic reactions, particularly in metathesis reactions.

    摘要翻译： 本发明涉及式（I）的新型过渡金属络合物与制备这些过渡金属配合物的方法，制备它们的中间体，以及过渡金属配合物在有机反应中的用途，特别是在复分解反应中。

    REACTIVE DISTILLATION PROCESS FOR THE ALKYLATION OF AROMATIC HYDROCARBONS
    8.
    发明申请
    REACTIVE DISTILLATION PROCESS FOR THE ALKYLATION OF AROMATIC HYDROCARBONS 失效
    芳香烃的烷基化反应蒸馏法

    公开(公告)号：US20030171630A1

    公开(公告)日：2003-09-11

    申请号：US10091199

    申请日：2002-03-05

    发明人： J. Barry Winder ,  Donald L. Wharry ,  John R. Schell ,  Mary J. Brown ,  Joy L. Murray ,  Richard C. Howe ,  Wayne L. Sorensen ,  Daniel P. Szura

    IPC分类号： C07C002/02 ,  C07C015/00

    CPC分类号： C07C2/66 ,  Y02P20/127

    摘要： A unified process for reactive distillation under pressure for the alkylation of light aromatic hydrocarbons such as benzene and cumene with straight chain C6-C18 olefins using a solid acid alkylation catalyst supported in the reflux zone of the distillation column. The process is continuous, using a reactive distillation configuration such that at least a portion of the olefin is injected below the benzene rectification zone at the top of the column. The aromatic hydrocarbon is injected continuously at a low rate above the rectification zone at the base of the column and above the reboiler. The alkylation reaction takes place primarily in the liquid phase on the solid acid catalyst and is characterized in that the molar ratio of aromatic hydrocarbon to olefin in the liquid phase may be adjusted. The molar ratio is adjustable up to about 100/1, through adjustment of the internal column operating pressure, the benzene reflux rate, the amount of benzene removed from the reflux condenser to storage or from the reboiler with the distillation column operated at or near total aromatic hydrocarbon reflux. The unexpectedly high liquid phase aromatic hydrocarbon to olefin molar ratios achieved in the reactive distillation column increases the selectivity to mono-alkylated aromatics and helps stabilize catalyst lifetime.

    摘要翻译： 在压力下进行反应蒸馏的统一方法是使用负载在蒸馏塔的回流区中的固体烷基化催化剂烷基化轻质芳烃如苯和枯烯与直链C 6 -C 18烯烃。 该方法是连续的，使用反应蒸馏构型使得至少一部分烯烃被注入塔顶部的苯精馏区下方。 芳族烃在柱的底部和再沸器上方的精馏区上方的低速率连续注入。 烷基化反应主要发生在固相酸催化剂上的液相中，其特征在于可调节芳族烃与烯烃在液相中的摩尔比。 通过调整内部柱的工作压力，苯回流速率，从回流冷凝器到储存器或从蒸馏塔中回收的蒸馏塔中除去的苯的量可调整到约100/1的摩尔比可以达到约100/1 芳烃回流。 在反应蒸馏塔中实现的意想不到的高液相芳烃与烯烃的摩尔比提高了对单烷基化芳族化合物的选择性，有助于稳定催化剂的使用寿命。

    Synthesis of functionalized and unfunctionalized olefins via cross and ring-closing Metathesis
    10.
    发明申请
    Synthesis of functionalized and unfunctionalized olefins via cross and ring-closing Metathesis 有权
    通过交叉和闭环合成官能化和非官能化烯烃复分解

    公开(公告)号：US20020137978A1

    公开(公告)日：2002-09-26

    申请号：US09891144

    申请日：2001-06-25

    发明人： Robert H. Grubbs ,  Arnab K. Chatterjee ,  John P. Morgan ,  Matthias Scholl ,  Tae-Lim Choi

    IPC分类号： C07C002/02

    CPC分类号： C07D303/22 ,  C07B37/00 ,  C07C45/673 ,  C07C45/69 ,  C07C45/72 ,  C07C67/293 ,  C07C67/343 ,  C07C201/12 ,  C07C231/12 ,  C07C259/06 ,  C07C315/04 ,  C07D263/22 ,  C07D263/24 ,  C07D309/12 ,  C07D309/30 ,  C07D315/00 ,  C07D317/12 ,  C07D319/12 ,  C07D319/14 ,  C07D321/08 ,  C07D413/12 ,  C07C49/597 ,  C07C317/14 ,  C07C233/09 ,  C07C233/11 ,  C07C205/06 ,  C07C205/56

    摘要： The invention is directed to the cross-metathesis and ring-closing metathesis reactions between geminal disubstituted olefins and terminal olefins, wherein the reaction employs a Ruthenium or Osmium metal carbene complex. Specifically, the invention relates to the synthesis of null-functionalized or unfunctionalized olefins via intermolecular cross-metathesis and intramolecular ring-closing metathesis using a ruthenium alkylidene complex. The catalysts preferably used in the invention are of the general formula 1 wherein: M is ruthenium or osmium; X and X1 are each independently an anionic ligand; L is a neutral electron donor ligand; and, R, R1R6, R7, R8, and R9 are each independently hydrogen or a substituent selected from the group consisting of C1-C20 alkyl, C2-C20 alkenyl, C2-C20 alkynyl, aryl, C1-C20 carboxylate, C1-C20 alkoxy, C2-C20 alkenyloxy, C2-C20 alkynyloxy, aryloxy, C2-C20 alkoxycarbonyl, C1-C20 alkylthio, C1-C20 alkylsulfonyl and C1-C20 alkylsulfinyl.

    摘要翻译： 本发明涉及孪生二取代的烯烃和末端烯烃之间的交叉复分解和闭环复分解反应，其中该反应采用钌或锇金属卡宾络合物。 具体地，本发明涉及通过分子间交叉复分解和使用亚烷基钌络合物的分子内闭合复分解来合成α-官能化或未官能化的烯烃。 优选用于本发明的催化剂具有以下通式：其中：M是钌或锇; X和X1各自独立地为阴离子配体; L是中性电子给体配体; 且R 1，R 2，R 6，R 7，R 8和R 9各自独立地为氢或选自C 1 -C 20烷基，C 2 -C 20烯基，C 2 -C 20炔基，芳基，C 1 -C 20羧酸酯，C 1 -C 20 烷氧基，C 2 -C 20链烯氧基，C 2 -C 20炔氧基，芳氧基，C 2 -C 20烷氧基羰基，C 1 -C 20烷硫基，C 1 -C 20烷基磺酰基和C 1 -C 20烷基亚磺酰基。