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    Hydroformylation of olefins
    1.
    发明授权
    Hydroformylation of olefins 失效
    烯烃的加氢甲酰化

    公开(公告)号：US4159999A

    公开(公告)日：1979-07-03

    申请号：US526298

    申请日：1974-11-22

    申请人： Adin L. Stautzenberger ,  James L. Paul ,  Jerry D. Unruh

    发明人： Adin L. Stautzenberger ,  James L. Paul ,  Jerry D. Unruh

    IPC分类号： C07C27/20 ,  B01J31/22 ,  C07C27/00 ,  C07C45/50 ,  C07C67/00 ,  C07C45/08

    CPC分类号： B01J31/185 ,  B01J31/20 ,  B01J31/2404 ,  C07C45/50 ,  B01J2231/321 ,  B01J2531/80 ,  B01J2531/822 ,  B01J2531/90 ,  B01J31/28

    摘要： Olefins are converted to aldehydes and/or alcohols having one more carbon atom than the olefin by reacting the olefin with carbon monoxide and hydrogen in the presence of an in situ formed catalytic complex of a Group VIII metal, carbon monoxide and a trivalent ligand, the metal being introduced into the reaction zone in the form of a solution of a water-soluble inorganic salt dissolved in a solvent comprised of at least 40% by volume of a polyalkylene glycol, the polyalkylene glycol acting as a coupling agent preventing precipitation of the metal prior to formation of the catalyst complex.

    摘要翻译： 在原位形成的第Ⅷ族金属，一氧化碳和三价配体的催化络合物的存在下，烯烃通过使烯烃与一氧化碳和氢气反应而转化为具有比烯烃多一个碳原子的醛和/或醇， 金属以溶解在由至少40体积％的聚亚烷基二醇组成的溶剂中的水溶性无机盐的溶液的形式引入反应区域中，聚亚烷基二醇作为防止金属沉淀的偶联剂 在形成催化剂络合物之前。

    Hydroformylation process
    2.
    发明授权
    Hydroformylation process 失效
    加氢甲酰化过程

    公开(公告)号：US4155939A

    公开(公告)日：1979-05-22

    申请号：US853426

    申请日：1977-11-21

    申请人： John E. Poist

    发明人： John E. Poist

    IPC分类号： C07C45/50 ,  C07F9/02 ,  C07F15/00 ,  C07C45/08

    CPC分类号： C07F9/02 ,  C07C45/50 ,  C07F15/0093

    摘要： This invention provides a novel hydroformylation catalyst which is a ligand stabilized complex of platinum dihalide dimer and stannous halide.A preferred species of the invention hydroformylation catalyst can be represented by a formula corresponding to the chemical structure: ##STR1## wherein R is an organic radical such as alkyl or aryl, and X is a halogen radical.

    摘要翻译： 本发明提供了一种新的加氢甲酰化催化剂，其是二卤化二脒和卤化亚锡的配体稳定的络合物。

    Hydrocarbonylation
    4.
    发明授权
    Hydrocarbonylation 失效
    氢化羰基化

    公开(公告)号：US4110404A

    公开(公告)日：1978-08-29

    申请号：US840815

    申请日：1969-07-10

    申请人： William D. Schaeffer ,  Frank B. Booth

    发明人： William D. Schaeffer ,  Frank B. Booth

    IPC分类号： C07C45/50 ,  C07C45/08

    CPC分类号： C07C45/50

    摘要： An ethylenically unsaturated hydrocarbon is hydroformylated to an aldehyde having one more carbon than the unsaturated hydrocarbon by contacting the unsaturated hydrocarbon, carbon monoxide and hydrogen in the presence of a reaction medium comprising a Group VIII noble metal and a bicyclo or tricyclo(heterocyclo) saturated amine having 2 to 10 carbons, 1 to 4 nitrogens and at least one nitrogen in a bridgehead position. Liquid phase contacting is employed with the catalyst dispersed in a liquid phase at temperatures from 50.degree. to about 200.degree. C. and pressures from 1 to 300 atmospheres. A typical reaction comprises contacting ethylene, carbon monoxide and hydrogen at a temperature of about 88.degree. C. and a pressure of 50 atmospheres with an inert liquid reaction medium containing rhodium chloride and triethylenediamine. Preferably the reaction medium also contains a biphyllic ligand which is a trivalent phosphorus, antimony or arsenic organic compound. The presence of the heterocyclo saturated amine has been found to increase the yield of the aldehyde without increasing the yield of alcohol and/or dimerized products.

    摘要翻译： 在包含VIII族贵金属和二环或三环（杂环）饱和胺的反应介质的存在下，通过使不饱和烃，一氧化碳和氢气接触，将烯键式不饱和烃加氢甲酰化成具有比不饱和烃多一碳的醛 在桥头位置具有2至10个碳，1至4个氮和至少一个氮。 使用液相接触，催化剂在50至200℃的温度和1至300个大气压的压力下分散在液相中。 典型的反应包括在约88℃的温度和50大气压的压力下，与含氯化铑和三亚乙基二胺的惰性液体反应介质接触乙烯，一氧化碳和氢气。 优选地，反应介质还含有三价磷，锑或砷有机化合物的二元配体。 发现杂环饱和胺的存在可增加醛的产率，而不增加醇和/或二聚产物的产率。