公开(公告)号：US4152357A

公开(公告)日：1979-05-01

申请号：US853834

申请日：1977-11-22

申请人： John E. Poist

发明人： John E. Poist

IPC分类号： B01J31/24 ,  C07C45/50 ,  C07C45/08

CPC分类号： B01J31/0239 ,  B01J31/1845 ,  B01J31/24 ,  B01J31/2404 ,  B01J31/26 ,  C07C45/50 ,  B01J2231/321 ,  B01J2531/828

摘要： This invention provides a novel hydroformylation catalyst which is an ionic combination of a quaternary ammonium component and a ligand stabilized complex of platinum dihalide and stannous halide.A preferred species of the invention hydroformylation catalyst can be represented empirically by the chemical structure: ##STR1## wherein R and R' are organic radicals such as alkyl and aryl, and X is a halogen radical.The present invention stabilized platinum-tin complex hydroformylation catalyst provides a faster reaction rate at lower pressures and a superior combination of a high level of olefin conversion and efficiency to aldehyde products than prior art hydroformylation catalysts.

公开(公告)号：US4155939A

公开(公告)日：1979-05-22

申请号：US853426

申请日：1977-11-21

申请人： John E. Poist

发明人： John E. Poist

IPC分类号： C07C45/50 ,  C07F9/02 ,  C07F15/00 ,  C07C45/08

CPC分类号： C07F9/02 ,  C07C45/50 ,  C07F15/0093

摘要： This invention provides a novel hydroformylation catalyst which is a ligand stabilized complex of platinum dihalide dimer and stannous halide.A preferred species of the invention hydroformylation catalyst can be represented by a formula corresponding to the chemical structure: ##STR1## wherein R is an organic radical such as alkyl or aryl, and X is a halogen radical.

摘要翻译： 本发明提供了一种新的加氢甲酰化催化剂，其是二卤化二脒和卤化亚锡的配体稳定的络合物。

公开(公告)号：UST968001I4

公开(公告)日：1978-03-07

申请号：US764325

申请日：1977-01-31

申请人： John E. Poist

发明人： John E. Poist

IPC分类号： C09D151/08

CPC分类号： C09D151/08

摘要： a coating coagulation bath is disclosed containing an emulsified graft copolymer of an epoxy ester and an alpha beta ethyleneically unsaturated monomer. The bath itself is self-coagulatable in that a metal panel dipped into the bath will exhibit a coating on its surface immediately after removal.

公开(公告)号：US4101565A

公开(公告)日：1978-07-18

申请号：US794780

申请日：1977-05-09

申请人： John E. Poist

发明人： John E. Poist

IPC分类号： C07C45/50 ,  C07F9/02 ,  C07F15/00 ,  C07F7/22 ,  B01J31/18 ,  B01J31/24 ,  C07C45/08

CPC分类号： C07F9/02 ,  C07C45/50 ,  C07F15/0093

摘要： This invention provides a novel hydroformylation catalyst which is a ligand stabilized complex of platinum dihalide dimer and stannous halide.A preferred species of the invention hydroformylation catalyst can be represented by a formula corresponding to the chemical structure: ##STR1## wherein R is an organic radical such as alkyl or aryl, and X is a halogen radical.

摘要翻译： 本发明提供了一种新的加氢甲酰化催化剂，其是二卤化二甲基锡和卤化亚锡的配体稳定的络合物。

公开(公告)号：US4101564A

公开(公告)日：1978-07-18

申请号：US794781

申请日：1977-05-09

申请人： John E. Poist

发明人： John E. Poist

IPC分类号： B01J31/24 ,  C07C45/50 ,  B01J31/18 ,  C07C45/08

CPC分类号： B01J31/0239 ,  B01J31/1845 ,  B01J31/24 ,  B01J31/2404 ,  B01J31/26 ,  C07C45/50 ,  B01J2231/321 ,  B01J2531/828

摘要： This invention provides a novel hydroformylation catalyst which is an ionic combination of a quaternary ammonium component and a ligand stabilized complex of platinum dihalide and stannous halide.A preferred species of the invention hydroformylation catalyst can be represented empirically by the chemical structure: ##STR1## wherein R and R' are organic radicals such as alkyl and aryl, and X is a halogen radical.The present invention stabilized platinum-tin complex hydroformylation catalyst provides a faster reaction rate at lower pressures and a superior combination of a high level of olefin conversion and efficiency to aldehyde products than prior art hydroformylation catalysts.

摘要翻译： 本发明提供了一种新型加氢甲酰化催化剂，其是季铵组分和铂二卤化物和卤化亚锡的配体稳定化络合物的离子组合。