Chemical derivatization of silica coated fullerenes and use of derivatized silica coated fullerenes
    1.
    发明授权
    Chemical derivatization of silica coated fullerenes and use of derivatized silica coated fullerenes 有权
    二氧化硅涂覆的富勒烯的化学衍生化和使用衍生的二氧化硅涂覆的富勒烯

    公开(公告)号:US07491376B2

    公开(公告)日:2009-02-17

    申请号:US11451110

    申请日:2006-06-12

    IPC分类号: C01B31/00

    摘要: This invention is directed to a new composition of matter in the form of chemically derivatized silica coated fullerenes, including silica coated C60 molecules and silica coated carbon nanotubes, processes for making the same and to uses for the derivatized silica coated fullerenes. Included among many uses in chemical, physical or biological fields of use, but not limited thereto, are high speed, low loss electrical interconnects for nanoscale electronic devices, components and circuits. In one embodiment, this invention also provides a method for preparing silica coated fullerenes having substituents attached to the surface of silica coated fullerenes by reacting silica coated fullerenes with a wide range of organic or inorganic chemical species in a gaseous or liquid state. Preferred substituents include but are not limited to organic groups and organic groups containing heteroatoms such as oxygen, nitrogen, sulfur, and halogens. The identity of the surface functional group is chosen to provide desirable properties to the silica coated fullerenes including but not limited to solubility, miscibility, stickiness, and melting point. The present invention also describes the application of surface functionalized silica coated fullerenes as components of polymer blends and composites.

    摘要翻译: 本发明涉及以化学衍生的二氧化硅涂覆的富勒烯形式的物质的新组合物,包括二氧化硅涂覆的C60分子和二氧化硅涂覆的碳纳米管,其制备方法和用于衍生的二氧化硅涂覆的富勒烯的用途。 在化学,物理或生物领域的许多用途中包括用于纳米级电子器件,部件和电路的高速度,低损耗电互连,但不限于此。 在一个实施方案中,本发明还提供了一种制备二氧化硅涂覆的富勒烯的方法,其具有通过使二氧化硅涂覆的富勒烯与宽范围的气态或液态的有机或无机化学物质反应而附着到二氧化硅涂覆的富勒烯的表面上的取代基。 优选的取代基包括但不限于有机基团和含有杂原子如氧,氮,硫和卤素的有机基团。 选择表面官能团的身份来为二氧化硅涂覆的富勒烯提供所需的性质,包括但不限于溶解度,混溶性,粘性和熔点。 本发明还描述了表面官能化二氧化硅涂覆的富勒烯作为聚合物共混物和复合材料的组分的应用。

    Method for preparing nano-size particulate graphite
    3.
    发明授权
    Method for preparing nano-size particulate graphite 失效
    制备纳米尺寸颗粒状石墨的方法

    公开(公告)号:US06692718B1

    公开(公告)日:2004-02-17

    申请号:US09926626

    申请日:2002-02-26

    申请人: Eiji Osawa

    发明人: Eiji Osawa

    IPC分类号: C01B3104

    摘要: A multi-layer fullerene, particularly a carbon nano-onion which is nano-size particulate can be produced efficiently and in high purity by irradiating soot-like carbon such as carbon black obtained by incomplete combustion or thermal cracking of carbon-containing compound such as hydrocarbon, aromatic oil and so on with high energy such as electron rays, gamma rays, X-rays, beam from an ion source and so on, and heat-treated.

    摘要翻译: 多层富勒烯,特别是纳米尺寸颗粒的碳纳米洋葱,可以通过照射碳黑等有机碳,例如通过不完全燃烧得到的炭黑或含碳化合物的热裂解,例如 碳氢化合物,芳香油等具有高能量,例如电子射线,γ射线,X射线,来自离子源的束等,并进行热处理。

    Method for producing a palladium-containing hydrogenation catalyst
    6.
    发明申请
    Method for producing a palladium-containing hydrogenation catalyst 失效
    含钯氢化催化剂的制造方法

    公开(公告)号:US20060205589A1

    公开(公告)日:2006-09-14

    申请号:US10564019

    申请日:2004-07-06

    IPC分类号: B01J21/18

    摘要: The invention relates to physical chemistry and can be used for adjusting the rate of autocatalytic hydrogenation reactions. The method for producing a palladium-containing hydrogenation catalyst consists in reducing divalent palladium from the initial compound thereof and precipitating the thus reduced palladium on a carbon material, wherein, according to said invention, the initial compound is embodied in the form of tetra aqua-palladium (II) perchlorate. The reduced palladium is precipitated on a nano-carbon material which can be embodied in the form of fullerene C60, carbon nanotubes, cathodic deposit and the mixture of C60 and C70 fullerenes at the following ratio thereof: 60-80 mass % fullerene C60 and 20-40 mass % fluorine C70. The invention makes it possible to develop the method for producing a palladium-containing hydrogenation catalyst which exhibits a higher catalytic activity and operates in softer conditions (at a room temperature and a normal (atmospheric) pressure).

    摘要翻译: 本发明涉及物理化学,可用于调节自催化氢化反应的速率。 含钯氢化催化剂的制备方法在于从其初始化合物中还原二价钯,并将如此还原的钯沉淀在碳材料上,其中根据本发明,初始化合物以四水合物形式体现, 高氯酸钯(II)。 还原的钯在纳米碳材料上沉淀,纳米碳材料可以以富勒烯C 60,碳纳米管,阴极沉积物和C 60 C和C的混合物的形式体现 70%富勒烯按以下比例:60-80质量%富勒烯C 60和20-40质量%氟C 70 70。 本发明使得可以开发出具有较高催化活性并在较软条件(室温和正常(大气压))下操作的含钯氢化催化剂的方法。

    Ultrafine particle enclosing fullerene and production method thereof
    7.
    发明授权
    Ultrafine particle enclosing fullerene and production method thereof 有权
    包围富勒烯的超细颗粒及其制造方法

    公开(公告)号:US5951832A

    公开(公告)日:1999-09-14

    申请号:US166799

    申请日:1998-10-06

    摘要: After an ultrafine particle is disposed on a giant fullerene by driving the ultrafine particle using an electron beam, the ultrafine particle is enclosed in a core hollow portion of the giant fullerene, by contracting the giant fullerene with the electron beam irradiation. Or a metal ultrafine particle composed of an active metal is enclosed in the core hollow portion of the giant fullerene, by irradiating a high energy beam such as the electron beam to an amorphous carbon including the active metal to form the giant fullerene in an irradiated portion, and by contracting the giant fullerene with the irradiation of the high energy beam.

    摘要翻译: 在通过使用电子束驱动超细颗粒将超细颗粒设置在巨型富勒烯上之后,通过用电子束照射收缩巨型富勒烯,将超细颗粒封闭在巨富勒烯的芯空心部分中。 或者由活性金属构成的金属超微粒子通过将诸如电子束的高能束照射到包含活性金属的无定形碳上而被包围在巨型富勒烯的芯空心部分中,以在照射部分中形成巨富勒烯 ,并通过高能束照射来承担巨型富勒烯。

    Method for coating fullerene materials for tribology
    9.
    发明授权
    Method for coating fullerene materials for tribology 失效
    用于摩擦磨损的富勒烯材料的涂覆方法

    公开(公告)号:US5558903A

    公开(公告)日:1996-09-24

    申请号:US326345

    申请日:1994-10-20

    IPC分类号: C23C14/06 C01B31/02

    摘要: The invention relates to an improved synthesis of fullerene (C.sub.60) films, whereby improved purity and adhesion to a substrate are achieved. The invention is not limited to C.sub.60 molecules and other fullerenes and fullerene based materials, including for example, metallofullerenes, fluorinated fullerenes, and codeposition of fullerene and other solid lubricants. The invention also relates to the use of these fullerene materials in oils, greases, polymers and other materials, both organic and inorganic, for improving lubrication and wear life. The invention further relates to a process for the ion bombardment of fullerene materials, including but not limited to, C.sub.60 fullerene materials to improve their tribological properties.

    摘要翻译: 本发明涉及富勒烯(C60)膜的改进合成,从而实现了提高的纯度和对基材的粘合性。 本发明不限于C60分子和其它富勒烯和富勒烯基材料,包括例如金属富勒烯,氟化富勒烯,以及富勒烯和其它固体润滑剂的共沉积。 本发明还涉及这些富勒烯材料在油,油脂,聚合物和其它有机和无机材料中的用途,以改善润滑和磨损寿命。 本发明还涉及用于离子轰击富勒烯材料的方法,包括但不限于C60富勒烯材料以改善其摩擦学性能。

    Carbon nanotubule enclosing a foreign material
    10.
    发明授权
    Carbon nanotubule enclosing a foreign material 失效
    碳纳米管封闭外来物质

    公开(公告)号:US5457343A

    公开(公告)日:1995-10-10

    申请号:US170806

    申请日:1993-12-21

    摘要: The invention provides a nanometer sized carbon tubule enclosing a foreign material except for carbon. The carbon tubule comprises a plurality of tubular graphite monoatomic sheets coaxially arranged. The foreign material is introduced through a top portion of the carbon tubule. The introduction of the foreign material is accomplished after forming an opening at the top portion of the carbon tubule either by contacting the foreign material with the top portion of the carbon tubule together with a heat treatment or by an evaporation of the foreign material on the top portion of the carbon tubule together with the heat treatment. The foreign material is introduced only in a center hollow space defined by an internal surface of the most inner tubular graphite monoatomic sheet.

    摘要翻译: 本发明提供一种纳米尺寸的碳素管,其中包含除碳以外的异物。 碳素管包括同轴布置的多个管状石墨单原子片。 异物通过碳素管的顶部引入。 外部材料的引入是通过在碳素管的顶部形成开口之后,通过将异物与碳素管的顶部接触,以及热处理或外部材料在顶部的蒸发 碳管的一部分与热处理一起。 异物仅被引入由最内管状石墨单原子片的内表面限定的中心空间。