Bis(ethylenedithio)tetrathiafulvalene.cyanometalate complex
    4.
    发明授权
    Bis(ethylenedithio)tetrathiafulvalene.cyanometalate complex 失效
    双(亚乙基二硫)四硫富瓦烯氰化金属络合物

    公开(公告)号:US5534638A

    公开(公告)日:1996-07-09

    申请号:US429009

    申请日:1995-04-26

    Abstract: This describes the following five novel organic substances: Bis (ethylenedithio) tetrathiafulvalene (henceforth to be called BEDT-TTF) compounded with cyanometalate anions in what is called Tetracyano Nickel acid Bis (Ethylenedithio) Tetrathiafulvalene salt.hydrate expressed by (BEDT-TTF).sub.4 [Ni(CN).sub.4 ].H.sub.2 O, Tetracyano Platinum acid Bis (Ethylenedithio) Tetrathiafulvalene salt.hydrate that is expressed by (BEDT-TTF).sub.4 [Pt(CN).sub.4 ].H.sub.2 O, Cyanide Palladium Bis (Ethylenedithio) Tetrathiafulvalene salt that is expressed by (BEDT-TTF)-[Pd(CN).sub.2 ], Tetracyano Palladium acid Bis (Ethylenedithio) Tetrathiafulvalene salt.hydrate that is expressed by (BEDT-TFF).sub.4 [Pd(CN).sub.4 ].H.sub.2 O and Tetracyano Palladium acid Bis (Ethylenedithio) Tetrathiafulvalene salt that is represented by (BEDT-TTF).sub.4 [Pd(CN).sub.4 ]. BEDT-TTF, acting as a common constituent in the crystals of all of the above substances, provides the properties of an insulator, a metal or a superconductor. Anions that construct the framework of BEDT-TTF determine the arrangement of BEDT-TTF and thus the electronic state of the compound. It can be predicted that superconducting phenomena could be discovered in compounds of BEDT-TTF type in which there are compounded cyanometalate anions that have the tendency to form large frameworks so that the effective volume is large as in the case of the novel substances of the present invention.

    Abstract translation: 这描述了以下五种新型有机物质:由(BEDT-TTF)4表示的所谓的四氰基镍酸双(乙二硫)四硫富瓦烯盐水合物与氰化金属阴离子复合的双(亚乙基二硫)四硫富瓦烯(以下称为BEDT-TTF) 由[BEDT-TTF] 4 [Pt(CN)4]·H 2 O,氰化物钯双(亚乙基二硫)四硫富瓦烯盐表示的四硫代双(亚乙基二硫)四硫富瓦烯盐水合物,[Ni(CN)4]·H 2 O, 由(BEDT-TFF)4 [Pd(CN)4]·H 2 O和四氰基钯表示的(BEDT-TTF) - [Pd(CN)2],四氰基钯酸双(亚乙基二硫)四硫富瓦烯盐水合物 由(BEDT-TTF)4 [Pd(CN)4]表示的酸性双(亚乙基二硫)四硫富瓦烯盐。 作为所有上述物质的晶体中的共同成分的BEDT-TTF提供绝缘体,金属或超导体的性质。 构建BEDT-TTF框架的阴离子决定了BEDT-TTF的排列以及化合物的电子状态。 可以预测,在具有复合的氰化金属阴离子的BEDT-TTF型化合物中可以发现超导现象,其具有形成大框架的趋势,使得有效体积大,如在本发明的新物质的情况下 发明。

    Soluble copper amino alkoxides
    6.
    发明授权
    Soluble copper amino alkoxides 失效
    可溶性铜氨基醇盐

    公开(公告)号:US5084201A

    公开(公告)日:1992-01-28

    申请号:US480705

    申请日:1990-02-15

    Applicant: Carl C. Greco

    Inventor: Carl C. Greco

    CPC classification number: C07C215/10 Y10S505/734 Y10S505/802 Y10S505/811

    Abstract: More storage stable solutions comprising an organic solvent containing a soluble copper amino alkoxide are disclosed. The compound is of the formula ##STR1## where and R is lower alkyl such as methyl or ethyl.

    Abstract translation: 公开了包含含有可溶性铜氨基醇盐的有机溶剂的更多储存稳定溶液。 该化合物具有式“IMAGE”,其中R是低级烷基如甲基或乙基。

    Method of making a superconducting fullerene composition by reacting a
fullerene with an alloy containing alkali metal
    9.
    发明授权
    Method of making a superconducting fullerene composition by reacting a fullerene with an alloy containing alkali metal 失效
    通过使富勒烯与含有碱金属的合金反应来制造超导富勒烯组合物的方法

    公开(公告)号:US5196396A

    公开(公告)日:1993-03-23

    申请号:US730737

    申请日:1991-07-16

    Abstract: A method for making a superconducting fullerine composition, includes reacting a fullerine with an alloy, and particularly reacting C.sub.60 with a binary alloy including an alkali metal or a tertiary alloy including two alkali metals in the vapor phase. Also, a Cesium-doped fullerine high T.sub.c superconducting composition has the formula Cs.sub.x C.sub.60, and particularly Cs.sub.3 C.sub.60. Also, a homogeneous bulk single phase high T.sub.c superconducting composition has the formula (Rb.sub.x K.sub.1-x).sub.3 C.sub.60.

    Abstract translation: 一种制造超导富勒林组合物的方法,包括使富勒林与合金反应,特别是使C60与包含在气相中包含两种碱金属的碱金属或三元合金的二元合金反应。 此外,铯掺杂的富勒氏高Tc超导组合物具有式CsxC60,特别是Cs 3 C 60。 此外,均质的单相高Tc超导组合物具有式(RbxK1-x)3C60。

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