Abstract:
The invention relates to a method for producing a high temperature superconductor (HTSC) from a strip including an upper side precursor layer and which, for continuous sintering of the precursor layer within a furnace in the presence of a fed-in reaction gas, is drawn across a support. A furnace for performing the method is also described.
Abstract:
The invention relates to a method for producing a high temperature superconductor (HTSC) from a strip including an upper side precursor layer and which, for continuous sintering of the precursor layer within a furnace in the presence of a fed-in reaction gas, is drawn across a support. A furnace for performing the method is also described.
Abstract:
A superconducting device operable at temperatures in excess of 30° K. and a method for making the device are described. A representative device is an essentially coplanar SQUID device formed in a single layer of high Tc superconducting material, the SQUID device being operable at temperatures in excess of 60° K. High energy beams, for example ion beams, are used to convert selected portions of the high Tc superconductor to nonsuperconductive properties so that the material now has both superconductive regions and nonsuperconductive regions. In this manner a superconducting loop having superconducting weak links can be formed to comprise the SQUID device.
Abstract:
A high Tc superconducting ceramic material is produced by a method in which a mixture of chemicals in suitable amounts is compacted into a desired form. The compacted mixture is then fired and, at the same time, an electric current is caused to pass through the compacted mixture in a predetermined direction. By virtue of the passage of the current through the material during firing, the orderliness of the molecular arrangement is enhanced and an elevated transition temperature Tc is obtained.
Abstract:
A superconductive fullerene and a process for making such superconductive fullerene are provided. The process involves contacting a quantity of fullerene with the vapor of an interhalogen compound such as ICl. The halogen doped fullerenes exhibited a transition temperature above 60 K.
Abstract:
Provided is an Hg-Ba-Ca-Cu-O oxide superconductor having a high superconductivity transition temperature Tc and a method which can prepare the same in excellent reproducibility. This oxide superconductor consists essentially of Hg, Ba, Ca, Cu and O, and is expressed in a chemical formula (Hg.sub.1-X Cu.sub.X)Ba.sub.2 Ca.sub.2 Cu.sub.3 O.sub.Y, wherein X=0.05 to 0.7 and Y=8 to 8.75. A method of preparing the oxide superconductor comprises a step of mixing raw materials of Hg, Ba, Ca and Cu with each other so that (Hg+Ba):Ca:Cu=b:1:C and Hg:Ba=(1-a):a, wherein 0.625.ltoreq.a.ltoreq.0.714, 1.ltoreq.b.ltoreq.3 and 1.667.ltoreq.c.ltoreq.3.444, in mole ratio, and compression-molding the mixture, and a step of heat treating a compact obtained by the compression molding. This oxide superconductor has a superconductivity transition temperature Tc of 134 K., which is the highest at present.
Abstract translation:提供具有高超导转变温度Tc的Hg-Ba-Ca-Cu-O氧化物超导体和可以以优异的再现性制备它的方法。 该氧化物超导体主要由Hg,Ba,Ca,Cu和O组成,并以化学式(Hg1-XCuX)Ba2Ca2Cu3OY表示,其中X = 0.05〜0.7,Y = 8〜8.75。 制备氧化物超导体的方法包括将Hg,Ba,Ca和Cu的原料彼此混合以使(Hg + Ba):Ca:Cu = b:1:C和Hg:Ba =(1- a):a,其中以摩尔比0.625 i = 0.714,1 / b = 3和1.667 = c = 3.444,并将混合物压缩成型,并且步骤 对通过压缩成型获得的压块进行热处理。 该氧化物超导体的超导转变温度Tc为134K,目前为最高。
Abstract:
Polycrystalline high-T.sub.c superconductors of the formula M.sub.m E.sub.e RO.sub.x, which contain grains which are crystallographically aligned to the greatest possible extent, where M is at least one trivalent element such as a lanthanide element, E is at least one divalent element such as an alkaline earth element and R is at least one transition metal such as Cu, and x denotes the proportion of oxygen, are obtained by substituting a part of the alkaline earth element by a foreign element, preferably an alkali-metal element, which is no longer present in the product after the reaction sintering and sintering except for contents in the ppm to parts per thousand range and brings about the orientation effect. This produces a material which contains a slight deficit of E and optionally M, has an unaltered critical temperature and is substantially more resistant to external agents than equivalent known materials. A post-treatment in a stream of air or oxygen is unnecessary. Single crystals having relatively large dimensions can also be produced in a corresponding manner.
Abstract:
A melting-and-solidification manufacturing method for manufacturing an ingot of a high critical temperature superconductive oxide belonging, in particular, to the YBaCuO, BiSrCaCuO, or TlBaCaCuO families, wherein:an ingot of oxide having the appropriate stoichiometery is used;the ingot is held horizontally by levitation on a film of gas inside a furnace;the ingot is melted;a vertical thermal gradient is established inside said furnace such that nucleation starts at the bottom portion of said ingot;while maintaining said thermal gradient, the overall temperature of the furnace is lowered at a rate of not more than 0.1.degree. C./hour down to the temperature which corresponds to complete ingot solidification; andfinally, conventional oxygenation treatment is applied to said ingot.
Abstract:
A method is provided for preparing a precursor of a superconductor containing atoms of oxygen, atoms of copper and atoms of at least two other metals and sufficient atoms of oxygen so that up to, but no more than, one atom of copper is in the trivalent state, in which method there are blended together, in finely divided particulate state, components containing atoms of the metals in the desired proportion with at least one of the components containing oxygen in an amount above that which would put more than one atom of copper into the trivalent state and thereafter milling the components together in a high energy system to a maximum particle size of about 5 microns for at least 99 weight percent of the blend.
Abstract:
A ceramic oxide superconductive composite material comprising a ceramic oxide superconductor and a non-superconductive material comprising at least one element which does not react with any of the elements of the ceramic oxide superconductor has improved superconductive properties such as a higher critical temperature and a larger critical current density.