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    Colour photographic silver halide material
    4.
    发明授权
    Colour photographic silver halide material 失效
    彩色照相卤化银材料

    公开(公告)号：US06783924B2

    公开(公告)日：2004-08-31

    申请号：US10612560

    申请日：2003-07-02

    Applicant: Ralf Weimann ,  Markus Geiger ,  Cuong Ly ,  Klaus Sinzger ,  Beate Weber ,  Heinz Wiesen

    Inventor： Ralf Weimann ,  Markus Geiger ,  Cuong Ly ,  Klaus Sinzger ,  Beate Weber ,  Heinz Wiesen

    IPC: G03C108

    CPC classification number: G03C1/18 ,  G03C1/127 ,  G03C5/04 ,  G03C7/30 ,  G03C7/3006 ,  G03C7/346 ,  G03C7/3926 ,  G03C7/39276 ,  G03C2200/19

    Abstract: A color photographic silver halide material comprising a substrate, at least one red-sensitive silver halide emulsion layer containing at least one cyan coupler, at least one green-sensitive silver halide emulsion layer containing at least one magenta coupler and at least one blue-sensitive silver halide emulsion layer containing at least one yellow coupler, characterised in that the silver halide crystals of the red-sensitive layer have a chloride content of at least 95 mol %, the cyan coupler corresponding to formula wherein R1 represents a hydrogen atom or an alkyl group, R2 represents an alkyl, aryl or hetaryl group R3 represents an alkyl or aryl group, R4 represents an alkyl, alkenyl, alkoxy, aryloxy, acyloxy, acylamino, sulphonyloxy, sulphamoylamino, sulphonamido, ureido, hydroxycarbonyl, hydroxycarbonylamino, carbamoyl, alkylthio, arylthio, alkylamino or arylamino group or a hydrogen atom and Z represents a hydrogen atom or a group which may be split off under the conditions of chromogenic development and the red-sensitive layer contains at least one compound of formula wherein R5 represents H, CH3 or OCH3, R6 represents H, OH, CH3, OCH3, NHCO—R7, COOR7, SO2NH2, NHCONH2 or NHCONH—CH3 and R7 represents C1 to C4 alkyl, is distinguished by very good stability in storage simultaneously with very good latent image stability.

    Abstract translation: 一种彩色照相卤化银材料，其包含基材，至少一种含有至少一种青色成色剂的感红卤化银乳剂层，至少一种包含至少一种品红色成色剂的至少一种感绿卤化银乳剂层和至少一种蓝色敏感性 含有至少一种黄色成色剂的卤化银乳剂层，其特征在于，所述红色感光层的卤化银晶体的氯化物含量为至少95摩尔％，对应于其中的青色成色剂R 1表示氢原子或 烷基，R 2表示烷基，芳基或杂芳基R 3表示烷基或芳基，R 4表示烷基，烯基，烷氧基，芳氧基，酰氧基，酰氨基，磺酰氧基，氨磺酰氨基，磺酰氨基，脲基 ，羟基羰基，羟基羰基氨基，氨基甲酰基，烷硫基，芳硫基，烷基氨基或芳基氨基或氢原子，Z表示氢原子或可以在条件o f显色发育和红敏层含有至少一种糠醛的化合物，R 5表示H，CH 3或OCH 3，R 6表示H，OH，CH 3，OCH 3，NHCO-R 7，COOR 7， SO 2 NH 2，NHCONH 2或NHCONH-CH 3和R 7表示C 1至C 4烷基，其特征在于非常好的保存稳定性，同时具有非常好的潜像稳定性。

    Photographic element containing ballasted tetrazole derivative and inhibitor releasing coupler
    5.
    发明授权
    Photographic element containing ballasted tetrazole derivative and inhibitor releasing coupler 有权
    含有镇流四唑衍生物和抑制剂释放成色剂的照相元件

    公开(公告)号：US06190849B1

    公开(公告)日：2001-02-20

    申请号：US09358500

    申请日：1999-07-21

    Applicant: Paul A. Burns ,  Louis E. Friedrich ,  Stephen P. Singer

    Inventor： Paul A. Burns ,  Louis E. Friedrich ,  Stephen P. Singer

    IPC: G03C108

    CPC classification number: G03C7/3926 ,  G03C1/346 ,  G03C7/3005 ,  G03C7/30541 ,  G03C7/30552 ,  G03C7/30558 ,  Y10S430/156 ,  Y10S430/158

    Abstract: The invention provides a color photographic element comprising: a) a first light sensitive silver halide emulsion layer containing a tetrazole compound of Formula I:  wherein when R1 is hydrogen, then R2 is an alkyl, aryl, alkoxy , aryloxy, alkylthio or arylthio, sulfoxyl, sulfonyl, sulfamoyl, —O—CO—, —O—SO2—, a heterocyclic group, a carbonyl group or an amino group or when R2 is a thiol (—SH) group, then R1 is an alkyl, aryl or heterocyclic group provided further that the ClogP for the compound of Formula I is at least 2.0 and less than 7.8; and b) a second light sensitive silver halide emulsion layer, having a spectral sensitivity different from that of the first light sensitive silver halide emulsion layer, containing a compound of Formula II: COUP—(TIME)j—INH  II wherein: 1) COUP is a coupler parent group capable of forming a dye upon reaction with an oxidized developer; 2) TIME is a timing group bonded to the coupling position of COUP and j is 0 or 1; and 3) INH is a mild silver development inhibitor fragment. The invention provides improved color reproduction.

    Abstract translation: 本发明提供了一种彩色照相元件，其包括：a）含有式I的四唑化合物的第一感光卤化银乳剂层：其中当R 1为氢时，R 2为烷基，芳基，烷氧基，芳氧基，烷硫基或芳硫基， ，磺酰基，氨磺酰基，-O-CO-，-O-SO 2 - ，杂环基，羰基或氨基，或者当R 2为硫醇（-SH））时，R 1为烷基，芳基或杂环基 进一步提供式I化合物的ClogP为至少2.0且小于7.8; 和b）具有不同于第一感光卤化银乳剂层的光谱灵敏度的第二感光卤化银乳剂层，其含有式II化合物：其中：1）COUP是能够形成染料的成色剂母体基团 与氧化的显影剂反应; 2）TIME是键合到COUP的偶联位置的定时基团，j是0或1; 和3）INH是温和的银开发抑制剂片段。本发明提供了改进的色彩再现。

    Photographic element with new singlet oxygen quenchers
    6.
    发明授权
    Photographic element with new singlet oxygen quenchers 失效
    摄影元素与新的单线态氧猝灭剂

    公开(公告)号：US6013429A

    公开(公告)日：2000-01-11

    申请号：US32555

    申请日：1998-02-27

    Applicant: Catherine A. Franke ,  Albert J. Mura, Jr. ,  Shari L. Eiff

    Inventor： Catherine A. Franke ,  Albert J. Mura, Jr. ,  Shari L. Eiff

    IPC: C07C311/32 ,  G03C7/30 ,  G03C7/392 ,  G03C7/333

    CPC classification number: C07C311/32 ,  G03C7/3008 ,  G03C7/39236 ,  G03C7/38 ,  G03C7/384 ,  G03C7/39248 ,  G03C7/3926 ,  G03C7/39268 ,  G03C7/39272 ,  G03C7/39288

    Abstract: Photographic elements are disclosed comprising a silver halide emulsion layer having associated therewith a magenta coupler and a magenta dye stabilizer compound of the formula S-I: ##STR1## wherein R.sup.0 represents an aryl group or a heterocyclic group; L.sub.1 and L.sub.2 are independently linear alkylene or cycloalkylene linking groups; and R.sup.a and R.sup.b are independently selected substituent groups at least one of which has a .sigma.* value of at least 1.8. Compounds in accordance with formula S-I act as singlet oxygen quenchers and are effective stabilizers for magenta dye images. Photographic elements of the present invention upon exposure and photographic processing yield magenta dye images that have low fading when exposed to light.

    Abstract translation: 公开了包含卤化银乳剂层的照相元件，所述卤化银乳剂层具有品红成色剂和式S-1的品红染料稳定剂化合物：其中R 0表示芳基或杂环基; L1和L2独立地是直链亚烷基或亚环烷基连接基团; 并且R a和R b独立地选自至少一个具有至少1.8的σ*值的取代基。 根据式S-1的化合物作为单线态氧猝灭剂，并且是品红色染料图像的有效稳定剂。 本发明的照相元件在曝光和照相处理时产生当暴露于光时具有低褪色的品红色染料图像。

    Process for the development of color photographic light-sensitive material
    7.
    发明授权
    Process for the development of color photographic light-sensitive material 失效
    彩色摄影感光材料的开发工艺

    公开(公告)号：US4418140A

    公开(公告)日：1983-11-29

    申请号：US366515

    申请日：1982-04-08

    Applicant: Hiroyuki Mifune ,  Shoji Ishiguro ,  Tadao Shishido ,  Tatsuo Nishimura

    Inventor： Hiroyuki Mifune ,  Shoji Ishiguro ,  Tadao Shishido ,  Tatsuo Nishimura

    IPC: G03C7/26 ,  C07D257/04 ,  G03C7/30 ,  G03C7/392 ,  G03C7/00

    CPC classification number: C07D257/04 ,  G03C7/3926 ,  Y02P20/55

    Abstract: A process for the development of color photographic light-sensitive material is described. The process comprises color developing an exposed light-sensitive material in the presence of a compound of the general formula: ##STR1## wherein M is a hydrogen atom, an alkali metal atom, NH.sub.4 or a protective group for the mercapto group which undergoes cleavage by the action of an alkali; R is a hydrogen atom or an alkyl group containing 1 to 3 carbon atoms; and R' is a hydrogen atom or an alkyl group containing 1 to 3 carbon atoms. This process prevents the formation of color development fog without seriously reducing sensitivity.

    Abstract translation: 描述了彩色照相感光材料的开发方法。 该方法包括在下列通式的化合物存在下显色曝光的感光材料：其中M是氢原子，碱金属原子，NH 4或巯基的保护基，其通过 碱的作用; R是氢原子或含有1至3个碳原子的烷基; 并且R'是氢原子或含有1至3个碳原子的烷基。 该过程防止形成颜色发展，而不会严重降低灵敏度。

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