公开(公告)号：US07732124B2

公开(公告)日：2010-06-08

申请号：US12292528

申请日：2008-11-20

Applicant: Yasuaki Deguchi ,  Shin Soejima ,  Naoto Ohshima ,  Tatsuya Ishizaka ,  Katsuyuki Takada ,  Futoshi Yoshida ,  Atsushi Maruhashi ,  Yoshinori Morimoto ,  Takehisa Ohno

Inventor： Yasuaki Deguchi ,  Shin Soejima ,  Naoto Ohshima ,  Tatsuya Ishizaka ,  Katsuyuki Takada ,  Futoshi Yoshida ,  Atsushi Maruhashi ,  Yoshinori Morimoto ,  Takehisa Ohno

IPC: G03C7/26 ,  G03C7/36 ,  G03C7/42 ,  G03C1/08 ,  G03C1/06

CPC classification number: G03C5/04 ,  G03C1/09 ,  G03C1/16 ,  G03C1/30 ,  G03C7/3022 ,  G03C7/3225 ,  G03C7/346 ,  G03C7/3825 ,  G03C7/3926 ,  G03C7/407 ,  G03C2001/03517 ,  G03C2001/03535 ,  G03C2001/093 ,  G03C2001/096 ,  G03C2007/3025 ,  G03C2200/52 ,  G03C2200/60

Abstract: A color-image forming method in a silver halide color photographic light-sensitive material, having the steps of: performing exposure of the light-sensitive material cut into sheets; and subjecting the exposed light-sensitive material sheets to photographic processing, while conveying them with conveying rollers, with the sheet conveying speed being 40.0 to 100 mm/sec; wherein the light-sensitive material to be exposed contains any of: 1) a dye-forming coupler of formula (IA), 2) a compound of formula (I), and 3) 1.4 mg/m2 or more of a compound of formula (II); wherein R′ and R″ are a substituent; Z is a hydrogen atom, or a coupling split-off group; A is an alkyl group, M is a cation, and R is an atom or group having 100 or lower total molecular weight.

Abstract translation: 一种卤化银彩色摄影感光材料中的彩色图像形成方法，具有以下步骤：对切割成片材的感光材料进行曝光; 并在曝光的感光材料片材进行照相处理，同时用输送辊输送它们，片材输送速度为40.0至100mm /秒; 其中要曝光的感光材料包含以下任何一种：1）式（IA）的染料形成成色剂，2）式（I）化合物和3）1.4mg / m 2或更多的式 （二）; 其中R'和R“是取代基; Z是氢原子或偶联分离基; A是烷基，M是阳离子，R是具有100个或更低总分子量的原子或基团。

公开(公告)号：US20090130613A1

公开(公告)日：2009-05-21

申请号：US12292528

申请日：2008-11-20

Applicant: Yasuaki Deguchi ,  Shin Soejima ,  Naoto Ohshima ,  Tatsuya Ishizaka ,  Katsuyuki Takada ,  Futoshi Yoshida ,  Atsushi Maruhashi ,  Yoshinori Morimoto ,  Takehisa Ohno

Inventor： Yasuaki Deguchi ,  Shin Soejima ,  Naoto Ohshima ,  Tatsuya Ishizaka ,  Katsuyuki Takada ,  Futoshi Yoshida ,  Atsushi Maruhashi ,  Yoshinori Morimoto ,  Takehisa Ohno

IPC: G03C7/26 ,  G03C1/46

CPC classification number: G03C5/04 ,  G03C1/09 ,  G03C1/16 ,  G03C1/30 ,  G03C7/3022 ,  G03C7/3225 ,  G03C7/346 ,  G03C7/3825 ,  G03C7/3926 ,  G03C7/407 ,  G03C2001/03517 ,  G03C2001/03535 ,  G03C2001/093 ,  G03C2001/096 ,  G03C2007/3025 ,  G03C2200/52 ,  G03C2200/60

Abstract: A color-image forming method in a silver halide color photographic light-sensitive material, having the steps of: performing exposure of the light-sensitive material cut into sheets; and subjecting the exposed light-sensitive material sheets to photographic processing, while conveying them with conveying rollers, with the sheet conveying speed being 40.0 to 100 mm/sec; wherein the light-sensitive material to be exposed contains any of: 1) a dye-forming coupler of formula (IA), 2) a compound of formula (I), and 3) 1.4 mg/m2 or more of a compound of formula (II); wherein R′ and R″ are a substituent; Z is a hydrogen atom, or a coupling split-off group; A is an alkyl group, M is a cation, and R is an atom or group having 100 or lower total molecular weight.

Abstract translation: 一种卤化银彩色摄影感光材料中的彩色图像形成方法，具有以下步骤：对切割成片材的感光材料进行曝光; 并在曝光的感光材料片材进行照相处理，同时用输送辊输送它们，片材输送速度为40.0至100mm /秒; 其中要曝光的感光材料包含以下任何一种：1）式（IA）的染料形成成色剂，2）式（I）化合物和3）1.4mg / m 2或更多的式 （二）; 其中R'和R“是取代基; Z是氢原子或偶联分离基; A是烷基，M是阳离子，R是具有100个或更低总分子量的原子或基团。

公开(公告)号：US06949332B2

公开(公告)日：2005-09-27

申请号：US10796163

申请日：2004-03-10

Applicant: Hiroshi Kawakami ,  Mikio Ihama ,  Takeshi Suzumoto

Inventor： Hiroshi Kawakami ,  Mikio Ihama ,  Takeshi Suzumoto

IPC: G03C1/29 ,  A61K31/44 ,  G03C1/005 ,  G03C1/035 ,  G03C1/047 ,  G03C1/10 ,  G03C1/12 ,  G03C1/16 ,  G03C1/18 ,  G03C7/38 ,  G03C5/18 ,  G03C5/26 ,  G03C1/494

CPC classification number: A61K31/44 ,  G03C1/005 ,  G03C1/035 ,  G03C1/047 ,  G03C1/10 ,  G03C1/12 ,  G03C7/3825 ,  G03C2001/0357 ,  G03C2001/0854 ,  G03C2200/24

Abstract: A silver halide emulsion containing water, dispersion medium comprising modified gelatin whose amino group is chemically modified, and silver halide grains comprising spectrally sensitized silver halide grains each having a multilayer adsorption of dye chromophores on the surface thereof. A method of preparing the silver halide emulsion. A silver halide photosensitive material contains the silver halide emulsion in a light-sensitive silver halide emulsion layer thereof.

Abstract translation: 含有水的卤化银乳剂，其包含氨基被化学改性的改性明胶的分散介质和包含光谱增感的卤化银颗粒的卤化银颗粒，每个卤化银颗粒在其表面上具有多层吸附染料发色团。 制备卤化银乳剂的方法。 卤化银感光材料在其感光卤化银乳剂层中含有卤化银乳剂。

公开(公告)号：US20050123868A1

公开(公告)日：2005-06-09

申请号：US10969031

申请日：2004-10-21

Applicant: Hiroyuki Yoneyama ,  Yasuaki Deguchi ,  Naoto Ohshima ,  Kiyoshi Takeuchi ,  Akira Ikeda ,  Naoto Matsuda

Inventor： Hiroyuki Yoneyama ,  Yasuaki Deguchi ,  Naoto Ohshima ,  Kiyoshi Takeuchi ,  Akira Ikeda ,  Naoto Matsuda

IPC: G03C1/09 ,  G03C7/30 ,  G03C7/32 ,  G03C7/34 ,  G03C7/36 ,  G03C7/38 ,  G03C7/388 ,  G03C7/392 ,  G03C1/46

CPC classification number: G03C7/3013 ,  G03C1/0051 ,  G03C1/09 ,  G03C5/50 ,  G03C7/3022 ,  G03C7/3041 ,  G03C7/3225 ,  G03C7/34 ,  G03C7/346 ,  G03C7/36 ,  G03C7/3825 ,  G03C7/3885 ,  G03C7/39208 ,  G03C2001/03517 ,  G03C2001/03535 ,  G03C2001/03541 ,  G03C2001/093 ,  G03C2007/3025 ,  G03C2007/3043 ,  G03C2200/07 ,  G03C2200/33

Abstract: A silver halide color photographic light-sensitive material comprising at least one yellow color developable light-sensitive silver halide emulsion layer, at least one magenta color developable light-sensitive silver halide emulsion layer, and at least one cyan color developable light-sensitive silver halide emulsion layer, each of which is provided on a support: which comprises at least one yellow coupler of formula (I) and at least one cyan coupler of formula (A); wherein Q represents a group of non-metal atoms that form a 5- to 7-membered ring in combination with —N═C—N(R1)-, each of R1 and R2 represents a substituent, m represents an integer of 0 to 5, and X represents a hydrogen atom or a group capable of being split-off upon a coupling reaction; wherein R11 and R12 each represent an alkyl group or an aryl group, J represents an alkylene group, and X represents a hydrogen atom or a group that can split off upon a coupling reaction.

Abstract translation: 一种卤化银彩色照相感光材料，其包含至少一种黄色可显影感光卤化银乳剂层，至少一种品红色可显影感光卤化银乳剂层和至少一种青色显影性感光卤化银 乳剂层，其各自设置在载体上：其包含至少一种式（I）的黄色偶联剂和至少一种式（A）的青色成色剂; 其中Q表示与-NCN（R1） - 组合形成5-至7-元环的一组非金属原子，R 1和R 2各自表示取代基，m表示0至5的整数，X表示 表示氢原子或能够在偶联反应时分裂的基团; 其中R 11和R 12各自表示烷基或芳基，J表示亚烷基，X表示氢原子或可以分解的基团 偶联反应。

公开(公告)号：US20040058282A1

公开(公告)日：2004-03-25

申请号：US10658607

申请日：2003-09-10

Applicant: FUJI PHOTO FILM CO., LTD.

Inventor： Kimiyasu Mor imura ,  Kohzaburoh Yamada

IPC: G03C005/29 ,  G03C005/50 ,  G03C007/407 ,  G03C001/08 ,  G03C001/10 ,  G03C001/28 ,  G03C001/34

CPC classification number: G03C1/10 ,  G03C5/50 ,  G03C7/30 ,  G03C7/3022 ,  G03C7/3825 ,  G03C2001/03535

Abstract: A method of processing, with a developer in which a solution physical development arises, a silver halide photosensitive material containing a compound capable of undergoing a one-electron oxidation to thereby form a one-electron oxidation product thereof which belongs to the following types 1 to 4: Type 1: the one-electron oxidation product being capable of releasing further two or more electrons accompanying a subsequent bond cleavage reaction; Type 2: the one-electron oxidation product being capable of releasing further one electron accompanying a subsequent bond cleavage reaction, and the compound having, in its molecule, two or more groups adsorptive to silver halide; Type 3: the one-electron oxidation product being capable of releasing further one or more electrons after going through a subsequent bond forming reaction; and Type 4: the one-electron oxidation product being capable of releasing further one or more electrons after going through a subsequent intramolecular ring cleavage reaction.

Abstract translation: 一种处理溶液物理发展的显影剂的方法，其包含能够进行单电子氧化的化合物的卤化银感光材料，从而形成其以下的1〜 4：类型1：单电子氧化产物能够释放伴随随后的键断裂反应的两个或多个电子; 类型2：单电子氧化产物能够进一步释放伴随随后的键断裂反应的一个电子，并且在其分子中具有吸附卤化银的两个或更多个基团的化合物; 类型3：单电子氧化产物在经过随后的结合形成反应后能够进一步释放一个或多个电子; 和4型：单电子氧化产物能够在经过随后的分子内环裂解反应后进一步释放一个或多个电子。

公开(公告)号：US20020076661A1

公开(公告)日：2002-06-20

申请号：US09956974

申请日：2001-09-20

Applicant: KONICA CORPORATION

Inventor： Tomonori Kawamura ,  Shigeo Tanaka ,  Satoshi Nishino ,  Hirohide Ito ,  Naohito Naraoka ,  Naoyo Suzuki ,  Shinya Watanabe ,  Masataka Takimoto ,  Hideaki Sakata ,  Junichi Tanabe ,  Tetsuya Taniguchi ,  Naoki Nozaki ,  Yasushi Okubo ,  Koji Daifuku ,  Katsuji Kondo ,  Toshitsugu Suzuki

IPC: G03C001/09 ,  G03C001/14 ,  G03C001/29 ,  G03C001/38 ,  G03C001/46 ,  G03C003/00 ,  G03C007/32 ,  G03C007/26 ,  G03C005/31 ,  G03C005/30

CPC classification number: G03C3/00 ,  G03C1/09 ,  G03C1/16 ,  G03C1/18 ,  G03C1/29 ,  G03C1/385 ,  G03C1/49881 ,  G03C5/04 ,  G03C7/3022 ,  G03C7/3041 ,  G03C7/36 ,  G03C7/3825 ,  G03C7/407 ,  G03C7/4136 ,  G03C2001/03517 ,  G03C2001/03535 ,  G03C2001/091 ,  G03C2001/096

Abstract: The present invention provides a system of a digital color proof in which consistent images are obtained while minimizing density variation in spite of various variations of conditions due to the use of a silver halide light-sensitive color material, specifically, the present invention provides a method for forming proof images similar to printed images in terms of various characteristics such as the paper quality of silver halide light-sensitive materials, the dot gain, and the density.

Abstract translation: 本发明提供了一种数字彩色证明的系统，其中尽管由于使用卤化银感光色材料而导致各种各样的变化，尽可能减少密度变化而获得一致的图像，具体地说，本发明提供一种方法 用于根据诸如卤化银感光材料的纸张质量，点增益和密度的各种特性形成类似于印刷图像的证明图像。

公开(公告)号：US20020025497A1

公开(公告)日：2002-02-28

申请号：US09899100

申请日：2001-07-06

Inventor： Naoto Matsuda ,  Hisashi Mikoshiba

IPC: G03C001/46 ,  G03C007/34 ,  G03C005/50

CPC classification number: G03C7/3225 ,  G03C5/50 ,  G03C7/30 ,  G03C7/3029 ,  G03C7/346 ,  G03C7/3825 ,  G03C7/3885 ,  G03C2007/3034

Abstract: A silver halide color photographic light-sensitive material has a red-, green-, and blue-sensitive emulsion layer in this order from the side closest to a support. The green-sensitive layer contains a coupler represented by formula (MC-I), and the red-sensitive emulsion layer contains a coupler represented by formula (CC-I): 1 wherein R1 represents a hydrogen atom or substituent; one of G1 and G2 represents C, the other represents N; and R2 represents a substituent which substitutes one of G1 and G2 which is C; X represents a hydrogen atom or a splitting off group; 2 wherein Rc1 represents a hydrogen atom or alkyl group, Rc2 represents an alkyl or aryl group, n is 1, 2, or 3, and Y is positioned in the meta and/or para position of the phenyl group with respect to the sulfonyl group, and represents alkyl, alkenyl, alkoxy, aryloxy, acyloxy, acylamino, sulfonyloxy, sulfamoylamino, sulfonamide, ureido, oxycarbonyl, oxycarbonylamino, or carbamoyl group.

Abstract translation: 卤化银彩色照相感光材料从最靠近载体的一侧依次具有红，绿和蓝敏感乳剂层。 感光层包含由式（MC-1）表示的成色剂，并且感红乳剂层含有由式（CC-I）表示的成色剂：其中R1表示氢原子或取代基; G1和G2之一表示C，另一个表示N; 并且R 2表示取代基为G的G 1和G 2之一的取代基; X表示氢原子或分解基团; 其中Rc1表示氢原子或烷基，Rc2表示烷基或芳基，n为1,2或3，并且Y位于苯基相对于磺酰基的间位和/或对位， 并表示烷基，烯基，烷氧基，芳氧基，酰氧基，酰氨基，磺酰氧基，氨磺酰氨基，磺酰胺，脲基，氧羰基，氧羰基氨基或氨基甲酰基。

公开(公告)号：US5851741A

公开(公告)日：1998-12-22

申请号：US300849

申请日：1994-09-06

Applicant: Osamu Takahashi ,  Hideaki Naruse ,  Nobuo Sakai

Inventor： Osamu Takahashi ,  Hideaki Naruse ,  Nobuo Sakai

IPC: G03C7/38 ,  G03C7/388 ,  G03C7/392 ,  G03C7/413 ,  G03C7/384

CPC classification number: G03C7/3885 ,  G03C7/413 ,  G03C2001/03541 ,  G03C2001/0357 ,  G03C2200/20 ,  G03C7/3825 ,  G03C7/39288

Abstract: The present invention provides a method for forming color images by processing in a short period of time color photographic materials containing at least one oil-soluble coupler with a color developer which does not substantially contain benzyl alcohol, wherein a silver halide color photographic material having at least one silver halide emulsion layer on a reflective support, the emulsion layer containing a dispersion of oleophilic fine grains having a mean grain size of 0.25 .mu.m or less, which contain a coupler capable of forming a dye after having been coupled with an oxidation product of an aromatic primary amine developing agent, and at least one high boiling organic solvent having a dielectric constant of 4.00 or more (25.degree. C., 10 KHz). The photographic material is imagewise exposed and then subjected to development with a color developer which contains an aromatic primary amine developing agent but does not substantially contain benzyl alcohol for 2 minutes and 30 seconds or less.

Abstract translation: 本发明提供一种通过在短时间内处理包含至少一种油溶性成色剂的彩色照相材料来形成彩色图像的方法，所述成色剂具有基本上不含苄醇的显色剂，其中卤化银彩色照相材料具有 在反射性载体上的至少一个卤化银乳剂层，该乳剂层含有平均粒度为0.25μm以下的亲油性细粒分散体，其含有能够与氧化产物偶联后形成染料的成色剂 的芳族伯胺显影剂和至少一种介电常数为4.00以上（25℃，10KHz）的高沸点有机溶剂。 照相材料成像曝光，然后用含有芳族伯胺显影剂但基本上不含苄醇的彩色显影剂显影2分30秒或更短。

公开(公告)号：US5609996A

公开(公告)日：1997-03-11

申请号：US608916

申请日：1996-02-29

Applicant: Ping W. Tang ,  Stanley W. Cowan ,  David J. Decker ,  Terrence C. Mungal

Inventor： Ping W. Tang ,  Stanley W. Cowan ,  David J. Decker ,  Terrence C. Mungal

IPC: C07D487/04 ,  G03C7/38

CPC classification number: C07D487/04 ,  G03C7/3825

Abstract: A photographic light sensitive silver halide emulsion layer has associated therewith a pyrazoloazole dye-forming coupler having the formula: ##STR1## wherein: R.sup.1 is a substituent bonded to the pyrazolotriazole nucleus by a fully substituted carbon atom;X is hydrogen or a coupling-off group;L is a divalent linking group;R.sup.2, R.sup.3, and R.sup.4 are independently hydrogen or substituent groups; andZ.sub.a, Z.sub.b, and Z.sub.c are independently --C(R')(R")--, .dbd.N--, .dbd.C(R')--, or --NH--, wherein R', and R" are independently H or a substituent, provided that one of either the Z.sub.a --Z.sub.b or the Z.sub.b --Z.sub.c bond is a double bond and the other is a single bond, and provided that when the Z.sub.b --Z.sub.c bond is a double bond, it may form part of a fused ring.

Abstract translation: 照相感光卤化银乳剂层与其具有通过完全取代的碳原子的具有下式的吡唑并苯染料形成成色剂： X是氢或偶合离去基团; L是二价连接基团; R2，R3和R4独立地是氢或取代基; 并且Za，Zb和Zc独立地为-C（R'）（R“） - ，= N - ，= C（R'） - 或-NH-，其中R'和R”独立地为H 或Za-Zb​​或Zb-Zc键​​中的任一个为双键且另一个为单键，并且条件是当Zb-Zc键​​为双键时，其可以形成为 稠环。

公开(公告)号：US5573898A

公开(公告)日：1996-11-12

申请号：US313587

申请日：1994-09-29

Applicant: Hidekazu Sakai

Inventor： Hidekazu Sakai

IPC: G03C5/08 ,  G03C1/79 ,  G03C1/91 ,  G03C7/00 ,  G03C7/30 ,  G03C7/38 ,  G03C7/392 ,  G03C7/407 ,  G03C1/46

CPC classification number: G03C7/3825 ,  G03C1/79 ,  G03C7/39208 ,  G03C7/3008 ,  G03C7/3022

Abstract: Disclosed is a silver halide color photographic material having plural light-sensitive layers on a reflective support, in which the reflective support is composed of a base and two or more waterproof resin coat layers each having a different white pigment content in such a way that the resin coat layers are sandwiched between the base and the light-sensitive layers, the cyan coupler-containing silver halide emulsion layer contains a particular pyrroloazole cyan dye-forming coupler, and the pH of the coated film of the material is from 4.0 to 6.5. The material is low-priced and has a good coloring property, excellent color reproducibility and high sharpness. As the material has sufficient pressure resistance, it has few stress marks even after stored. Also disclosed is a method for forming a color image, using the photographic material.

Abstract translation: 公开了一种在反射支撑体上具有多个感光层的卤化银彩色照相材料，其中反射支撑体由基底和两层或多层防水树脂涂层组成，每层具有不同的白色颜料含量， 树脂涂层夹在基底和感光层之间，含青色成色剂的卤化银乳剂层含有特定的吡咯并苯并氮青色染料成色剂，该材料的涂膜的pH为4.0至6.5。 该材料价格低廉，着色性能好，色彩再现性好，清晰度高。 由于该材料具有足够的耐压性，所以即使在储存之后它也几乎没有应力痕迹。 还公开了使用照相材料形成彩色图像的方法。