Abstract:
According to the invention, a metal salt and an oxygen source are applied to penetrate or impregnate a suitable substrate sequentially in effective amounts so as to react in contact with the substrate and produce a mineral compound fixed within the surface of the substrate. The inventive combination of a mutually compatible metal salt, oxygen source, and substrate brings about an in situ reaction, and modifies the substrate to bring about a lasting desired effect. The mineral compound that is produced according to the invention is linked to the substrate, is stable and long-lasting or permanent, and is immobilized or insolubilized in the substrate. The mineral compound is bound or contained within and on the surface of the substrate, so it may be said to be ingrained in the fibers or matrix of the substrate, or embedded within the substrate. The desired effect is preferably a color. A wide variety of metal salts may be used depending on the desired effect. The oxygen source is preferably a peroxide, and the substrate is preferably a cellulose product such as wood, cotton, or paper; leather; or masonry. The invention contemplates methods of treating substrates, treatment kits, and treated products. With wood products, the invention provides a water-based stain of low toxicity useful for soft woods.
Abstract:
The combination of ingredients, especially for use in the formulation of a one or two-pack retroreflective ink, comprising retroreflective elements, microbeads additional to said retroreflective elements and/or constituting said retroreflective elements at least in part, binder chemicals for attaching the retroreflective elements and microbeads to a substrate to which the ink is to be applied, and a coupling agent for coupling the microbeads and cross-linking the binder chemicals, the coupling agent being unreactive until the printing process is carried out.
Abstract:
Methods and devices for producing images on coated articles are provided. The methods generally comprise applying a layer of magnetizable pigment coating in liquid form on a substrate, with the magnetizable pigment coating containing a plurality of magnetic non-spherical particles or flakes. A magnetic field is then applied to selected regions of the pigment coating while the coating is in liquid form, with the magnetic field altering the orientation of selected magnetic particles or flakes. Finally, the pigment coating is solidified, affixing the reoriented particles or flakes in a non-parallel position to the surface of the pigment coating to produce an image such as a three dimensional-like image on the surface of the coating. The pigment coating can contain various interference or non-interference magnetic particles or flakes, such as magnetic color shifting pigments.
Abstract:
A vapor process for mineral dyeing cotton textiles is disclosed. Cellulosic fabric is impregnated with a chromium solution, exposed to sulfur dioxide vapors, dried, cured, and washed. The result is a superior process to "pearl gray" mineral dye fabric. Chromium containing salts used in the pad bath are selected from the group consisting of (NH.sub.4).sub.2 Cr.sub.2 O.sub.7 ; K.sub.2 CrO.sub.4 ; (NH.sub.4).sub.2 CrO.sub.4, Na.sub.2 CrO.sub.4 ; Na.sub.2 Cr.sub.2 O.sub.7 ; and K.sub.2 Cr.sub.2 O.sub.7. The pad baths contain from about 3.5% to 5.0% chromium consisting of 40 to 50 parts of a 20 to 28% sodium dichromate dihydrate solution made alkaline with 25 to 50 parts of 10 to 20% sodium hydroxide solution to attain a pH of about 9.6 to 13.0 with about 0.5 parts of wetting agent and 0-30 parts of water. A pad bath comprising about 3 parts of ammonium dichromate, 7.5 parts ammonium carbonate, 0.6 parts zirconyl ammonium carbonate and 0.5 parts wetting agent in about 90 parts water, reacted with about 40 parts concentrated ammonium hydroxide to result in a final pH of about 11, can also be used.
Abstract:
A method is provided for color marking wherein a color marking composition is ejected through a hollow needle into each of piled fabric pieces, said composition containing a water dispersion of an acid- and/or base-soluble inorganic pigment, a penetrant, a volatization retardant and an anti-settling agent. The mark obtained by this process is erasable with an appropriate acid or base.
Abstract:
The present unique process is based on an acid complex of chromium hydroxydiacetate and zirconyl acetate and a dodecylbenzylfurfuryldimethyl ammonium chloride quaternary, with or without an aliphatic polyether wetting agent. The clear blackish-green bath is stable for days, and decomposes on cellulosics, with heat, to produce a chrome gray-green mineral dyeing along with a quaternary-zirconium fungicide. The process makes it possible to produce a chrome fungicidal mineral dyeing from a single bath zirconyl acetate system, where no alkali is required, and only one bath is required to deposit both dye and fungicide.