公开(公告)号：US11901331B2

公开(公告)日：2024-02-13

申请号：US17647275

申请日：2022-01-06

Applicant: IMMUNOLIGHT, LLC

Inventor： Zakaryae Fathi ,  James Clayton ,  Harold Walder ,  Frederic A. Bourke, Jr.

IPC: C08K3/00 ,  H01L23/00 ,  B41J2/175 ,  C09J4/00 ,  A61B17/00 ,  A61L24/06 ,  B32B37/12 ,  B32B37/18 ,  B32B38/00 ,  C09J133/08 ,  C09K11/02 ,  C09K11/77 ,  H01L25/065 ,  H01L25/00 ,  B32B3/26 ,  B32B7/14 ,  B32B9/04 ,  C09J9/02 ,  C09J11/04 ,  C09J11/06 ,  H01L23/522

CPC classification number: H01L24/83 ,  A61B17/0057 ,  A61L24/06 ,  B32B3/266 ,  B32B7/14 ,  B32B9/04 ,  B32B37/1284 ,  B32B37/18 ,  B32B38/0008 ,  B41J2/17559 ,  C08K3/00 ,  C09J4/00 ,  C09J9/02 ,  C09J11/04 ,  C09J11/06 ,  C09J133/08 ,  C09K11/02 ,  C09K11/777 ,  C09K11/7769 ,  H01L23/5226 ,  H01L24/32 ,  H01L25/0657 ,  H01L25/50 ,  B32B2037/1253 ,  B32B2457/00 ,  B32B2457/08 ,  B32B2457/14 ,  H01L2224/16225 ,  H01L2224/32225 ,  H01L2224/48091 ,  H01L2224/48227 ,  H01L2224/73204 ,  H01L2224/73253 ,  H01L2224/73265 ,  H01L2224/83192 ,  H01L2224/83855 ,  H01L2224/92125 ,  H01L2225/06524 ,  H01L2225/06589 ,  H01L2924/07811 ,  H01L2924/1461 ,  H01L2924/15311 ,  Y10T428/2852 ,  H01L2224/48091 ,  H01L2924/00014 ,  H01L2224/73265 ,  H01L2224/32225 ,  H01L2224/48227 ,  H01L2924/00 ,  H01L2924/15311 ,  H01L2224/73265 ,  H01L2224/32225 ,  H01L2224/48227 ,  H01L2924/00 ,  H01L2924/15311 ,  H01L2224/73204 ,  H01L2224/16225 ,  H01L2224/32225 ,  H01L2924/00 ,  H01L2224/83192 ,  H01L2224/32225 ,  H01L2924/00 ,  H01L2924/07811 ,  H01L2924/00 ,  H01L2924/1461 ,  H01L2924/00 ,  H01L2224/92125 ,  H01L2224/73204 ,  H01L2224/16225 ,  H01L2224/32225 ,  H01L2924/00 ,  H01L2224/83192 ,  H01L2224/73204 ,  H01L2224/16225 ,  H01L2224/32225 ,  H01L2924/00

Abstract: A polymerizable composition includes at least one monomer, a photoinitiator capable of initiating polymerization of the monomer when exposed to light, and a phosphor capable of producing light when exposed to radiation (typically X-rays). The material is particularly suitable for bonding components at ambient temperature in situations where the bond joint is not accessible to an external light source. An associated method includes: placing a polymerizable adhesive composition, including a photoinitiator and energy converting material, such as a down-converting phosphor, in contact with at least two components to be bonded to form an assembly; and, irradiating the assembly with radiation at a first wavelength, capable of conversion (down-conversion by the phosphor) to a second wavelength capable of activating the photoinitiator, to prepare items such as inkjet cartridges, wafer-to-wafer assemblies, semiconductors, integrated circuits, and the like.

公开(公告)号：US09649832B2

公开(公告)日：2017-05-16

申请号：US14593049

申请日：2015-01-09

Applicant: Immunolight, LLC ,  Duke University

Inventor： Zakaryae Fathi ,  James Clayton ,  Harold Walder ,  Frederic A. Bourke, Jr. ,  Ian Stanton ,  Jennifer Ayres ,  Joshua T. Stecher ,  Michael Therien ,  Eric Toone ,  Dave Gooden ,  Mark Dewhirst ,  Joseph A. Herbert ,  Diane Fels ,  Katherine S. Hansen

IPC: B32B38/00 ,  C09J4/00 ,  C09J133/08 ,  B41J2/175 ,  C08K3/00 ,  A61B17/00 ,  A61L24/06 ,  B32B37/12 ,  B32B37/18

CPC classification number: H01L24/83 ,  A61B17/0057 ,  A61L24/06 ,  B32B3/266 ,  B32B7/14 ,  B32B9/04 ,  B32B37/1284 ,  B32B37/18 ,  B32B38/0008 ,  B32B2037/1253 ,  B32B2457/00 ,  B32B2457/08 ,  B32B2457/14 ,  B41J2/17559 ,  C08K3/00 ,  C09J4/00 ,  C09J9/02 ,  C09J11/04 ,  C09J11/06 ,  C09J133/08 ,  C09K11/02 ,  C09K11/7769 ,  C09K11/777 ,  H01L23/5226 ,  H01L24/32 ,  H01L25/0657 ,  H01L25/50 ,  H01L2224/16225 ,  H01L2224/32225 ,  H01L2224/48091 ,  H01L2224/48227 ,  H01L2224/73204 ,  H01L2224/73253 ,  H01L2224/73265 ,  H01L2224/83192 ,  H01L2224/83855 ,  H01L2224/92125 ,  H01L2225/06524 ,  H01L2225/06589 ,  H01L2924/07811 ,  H01L2924/1461 ,  H01L2924/15311 ,  Y10T428/2852 ,  H01L2924/00014 ,  H01L2924/00

Abstract: A polymerizable composition includes at least one monomer, a photoinitiator capable of initiating polymerization of the monomer when exposed to light, and a phosphor capable of producing light when exposed to radiation (typically X-rays). The material is particularly suitable for bonding components at ambient temperature in situations where the bond joint is not accessible to an external light source. An associated method includes: placing a polymerizable adhesive composition, including a photoinitiator and energy converting material, such as a down-converting phosphor, in contact with at least two components to be bonded to form an assembly; and, irradiating the assembly with radiation at a first wavelength, capable of conversion (down-conversion by the phosphor) to a second wavelength capable of activating the photoinitiator, to prepare items such as inkjet cartridges, wafer-to-wafer assemblies, semiconductors, integrated circuits, and the like.

公开(公告)号：US20050073239A1

公开(公告)日：2005-04-07

申请号：US10674376

申请日：2003-10-01

Applicant: Alok Mani Srivastava ,  Anant Setlur ,  Sergio Loureiro ,  Darryl Williams ,  Mohan Manoharan

Inventor： Alok Mani Srivastava ,  Anant Setlur ,  Sergio Loureiro ,  Darryl Williams ,  Mohan Manoharan

IPC: C09K11/08 ,  C09K11/02 ,  C09K11/66 ,  C09K11/67 ,  C09K11/70 ,  C09K11/74 ,  C09K11/77 ,  H01J1/62 ,  H01J9/22 ,  H01J61/44

CPC classification number: H01J61/44 ,  C09K11/02 ,  C09K11/08 ,  C09K11/666 ,  C09K11/668 ,  C09K11/673 ,  C09K11/701 ,  C09K11/7478 ,  C09K11/7704 ,  C09K11/7706 ,  C09K11/7709 ,  C09K11/7712 ,  C09K11/7734 ,  C09K11/7739 ,  C09K11/774 ,  C09K11/7769 ,  C09K11/777 ,  C09K11/7774 ,  C09K11/7777 ,  C09K11/778 ,  C09K11/7787 ,  C09K11/7792 ,  C09K11/7793 ,  C09K11/7797 ,  Y10S977/95 ,  Y10T428/2991 ,  Y10T428/2993

Abstract: A light source comprises: (a) a source of plasma discharge that emits electromagnetic radiation, a portion of which has wavelengths shorter than about 200 nm; and (b) a phosphor composition that comprises particles, each of the particles comprising at least a first phosphor and at least a second phosphor, the phosphor composition is disposed such that the first phosphor absorbs substantially the portion of EM radiation having wavelengths shorter than about 200 nm, and the first phosphor emits EM radiation having wavelengths longer than about 200 nm.

Abstract translation: 光源包括：（a）发射电磁辐射的等离子体放电源，其一部分波长短于约200nm; 和（b）包含颗粒的荧光体组合物，每个颗粒至少包括第一荧光体和至少第二荧光体，磷光体组合物设置成使得第一荧光体基本上吸收波长短于约 200nm，并且第一荧光体发射具有大于约200nm的波长的EM辐射。

公开(公告)号：US06699406B2

公开(公告)日：2004-03-02

申请号：US09272912

申请日：1999-03-19

Applicant: Richard E. Riman ,  John Ballato

Inventor： Richard E. Riman ,  John Ballato

IPC: C09K1102

CPC classification number: C09K11/777 ,  C09K11/7701 ,  C09K11/7704 ,  C09K11/7705 ,  C09K11/7767 ,  C09K11/7773

Abstract: A rare earth element doped composition having a dopant concentration of up to about 60 mole percent of one or more rare earth elements selected from Tb, Dy, Ho, Er, Tm, Yb and Lu, wherein the composition is optically transparent to wavelengths at which excitation, fluorescence or luminescence of the rare earth elements occur. Method for making the compositions, composite materials having dispersed therein the compositions and luminescent devices containing optical or acoustical elements formed from the composite materials are also disclosed.

Abstract translation: 掺杂剂浓度高达约60摩尔％的稀土元素掺杂组合物，其选自Tb，Dy，Ho，Er，Tm，Yb和Lu中的一种或多种稀土元素，其中该组合物对于波长为 发生稀土元素的激发，荧光或发光。 还公开了制备组合物的方法，其中分散有组合物的复合材料和包含由复合材料形成的光学或声学元件的发光装置。

公开(公告)号：US20030232005A1

公开(公告)日：2003-12-18

申请号：US10460809

申请日：2003-06-11

Inventor： Hisatake Okada ,  Satoshi Ito ,  Takayuki Suzuki ,  Hideki Hoshino ,  Naoko Furusawa

IPC: C01G057/00

CPC classification number: B82Y30/00 ,  C01G1/02 ,  C01G99/006 ,  C01P2004/62 ,  C01P2004/64 ,  C01P2006/40 ,  C09K11/584 ,  C09K11/595 ,  C09K11/628 ,  C09K11/662 ,  C09K11/665 ,  C09K11/673 ,  C09K11/77 ,  C09K11/7718 ,  C09K11/7731 ,  C09K11/7734 ,  C09K11/7739 ,  C09K11/774 ,  C09K11/7752 ,  C09K11/7764 ,  C09K11/7767 ,  C09K11/7768 ,  C09K11/777 ,  C09K11/7771 ,  C09K11/7774 ,  C09K11/778 ,  C09K11/7784 ,  C09K11/7789 ,  C09K11/7792 ,  C09K11/7794 ,  C09K11/7797

Abstract: A method for manufacturing a phosphor precursor by using a mixing device comprising: (a) at least one first inlet flow passage; (b) at least one second inlet flow passage, the first and the second inlet flow passages connect together so as to form a collision section; and (c) an outlet flow passage which is connected with the collision section, the method comprising the steps of: (i) supplying continuously a first and a second raw phosphor materials into the inlet flow passages; (ii) introducing the first and the second raw phosphor material solutions into the collision section so as to form a phosphor precursor; and (iii) releasing continuously the phosphor precursor from an exit of the outlet flow passage with controlling a Reynolds number of the phosphor precursor to be not less than 3000 while retaining the phosphor precursor in the outlet flow passage for not less than 0.001 seconds.

Abstract translation: 一种通过使用混合装置制造荧光体前体的方法，包括：（a）至少一个第一入口流动通道; （b）至少一个第二入口流动通道，第一和第二入口流动通道连接在一起以形成碰撞部分; 和（c）与所述碰撞部分连接的出口流动通道，所述方法包括以下步骤：（i）将第一和第二原料荧光体材料连续供应到所述入口流动通道中; （ii）将第一和第二原料荧光体材料溶液引入到碰撞部分中以形成荧光体前体; 并且（iii）通过将荧光体前体的雷诺数控制在3000以上，同时将荧光体前体保持在出口流路中不少于0.001秒，从出口流动通道的出口连续释放荧光体前体。

公开(公告)号：US5051589A

公开(公告)日：1991-09-24

申请号：US510914

申请日：1990-04-18

Applicant: Satoshi Arakawa

Inventor： Satoshi Arakawa

IPC: A61B6/00 ,  C09K11/77 ,  G06T1/00 ,  G21K4/00 ,  H01J37/22

CPC classification number: H01J37/224 ,  C09K11/7733 ,  C09K11/777 ,  G21K4/00 ,  G21K2004/06 ,  H01J2237/2443

Abstract: Stimulable phosphor sheet comprises a plurality of stimulable phosphors which are mixed together or which take on the form of layers. The stimulable phosphors have different response speeds, with which light emission from the stimulable phosphors responds to stimulating rays which cause them to emit light in proportion to the amounts of radiation stored thereon during their exposure to radiation, and different radiation absorption characteristics which represent absorptivity with respect to energy levels of the radiation. Radiation images of an object are stored on the stimulable phosphor sheet. The stimulable phosphor sheet is then exposed to pulsed stimulating rays. Light emitted by the stimulable phosphor sheet is detected with different timings corresponding to the response speeds of the stimulable phosphors, and a plurality of image signals representing the radiation images are thereby obtained. Thereafter, subtraction processing for the radiation images is carried out on the plurality of the image signals.

Abstract translation: 可刺激的荧光粉片包括多个可激发的荧光体，它们混合在一起或以层的形式。 可刺激的荧光体具有不同的响应速度，来自可刺激磷光体的光发射响应于刺激光线，其使得它们在其暴露于辐射期间与其上存储的辐射量成比例地发光，以及不同的辐射吸收特性，其表示吸收 尊重辐射能级。 物体的辐射图像存储在可刺激的荧光体片材上。 然后将可刺激的荧光粉片暴露于脉冲刺激的射线。 用与可激发荧光体的响应速度相对应的不同定时检测由可刺激荧光粉片发射的光，从而获得表示辐射图像的多个图像信号。 此后，对多个图像信号进行放射线图像的减法处理。

公开(公告)号：US4604550A

公开(公告)日：1986-08-05

申请号：US667043

申请日：1984-11-01

Applicant: Jan L. van Koesveld ,  Roelof E. Schuil

Inventor： Jan L. van Koesveld ,  Roelof E. Schuil

IPC: C09K11/08 ,  C09K11/77 ,  H01J29/18 ,  H01J29/20 ,  H01J29/28 ,  H01J31/00 ,  H01J29/10

CPC classification number: C09K11/7771 ,  C09K11/777 ,  H01J29/185 ,  H01J29/28

Abstract: A display tube comprising in an evacuated envelope means to generate at least one electron beam which is focused on a display screen and describes a field thereon, which display screen comprises a terbium-activated blue-luminescing phosphor on a carrier, and in which the light emitted by the phosphor falls through a filter. If the energy of the emissions of the phosphor which find their origin in the .sup.5 D.sub.3 -level of terbium is at least 40% of the energy of the emissions of all terbium levels and the filter has a transmission of more than 75% at those wavelengths where the .sup.5 D.sub.3 .fwdarw..sup.7 F.sub.5 and the .sup.5 D.sub.3 .fwdarw..sup.7 F.sub.4 emissions of terbium are located and the filter has a transmission of less than 10% at those wavelengths where the .sup.5 D.sub.4 .fwdarw..sup.7 F.sub.5 and the .sup.5 D.sub.4 .fwdarw..sup.7 F.sub.4 and the .sup.5 D.sub.4 .fwdarw..sup.7 F.sub.3 emissions of terbium are located so that the color point of the filtered light is located in the range x.ltoreq. 0.200 and y.ltoreq.0.100 in the CIE color triangle, a well saturated blue picture is displayed having a satisfactorily high energy efficiency.

Abstract translation: 一种显示管，包括在真空包络中的装置，以产生聚焦在显示屏幕上的至少一个电子束，并描述其上的场，该显示屏幕包括在载体上的铽激活的蓝色发光荧光体，其中光 由荧光体发射的光通过滤光器落下。 如果发现其起源于铽的5D3级的荧光体的发射能量是所有铽水平的发射能量的至少40％，并且在那些波长处的滤波器的透射率大于75％ 在5D4-> 7F5和5D4-> 7F4和5D4-> 7F3发射的波长处，铽的5D3-> 7F5和5D3-> 7F4发射位于滤波器的透射率小于10％ 铽的位置使得滤色光的色点位于CIE彩色三角形的x <0.2和y <0.100范围内，显示出良好饱和的蓝色图像，具有令人满意的高能量效率。

公开(公告)号：US4603259A

公开(公告)日：1986-07-29

申请号：US735305

申请日：1985-05-17

Applicant: Jacob G. Rabatin

Inventor： Jacob G. Rabatin

IPC: C09K11/77 ,  G21K4/00 ,  G01J1/58

CPC classification number: C09K11/777 ,  G21K4/00

Abstract: X-ray image converters using rare earth oxyhalide phosphors activated with terbium and/or thulium ion are described exhibiting improved brightness. Novel reflector means are provided in said x-ray image converter devices which reflect UV radiation incident thereupon back through the phosphor layer to associated readout or recording means sensitive to this wavelength radiation. A multi layer x-ray screen construction utilizing said improved reflector means is also described providing improved image sharpness while further reducing the crossover problem because more reflected UV radiation is being transmitted to an associated photographic film.

Abstract translation: 描述了使用用铽和/或ium离子激活的稀土卤氧化物荧光体的X射线图像转换器显示出改进的亮度。 在所述X射线图像转换器装置中设置有新的反射器装置，其反射通过荧光体层反射的UV辐射到对该波长辐射敏感的相关读出或记录装置。 还描述了利用所述改进的反射器装置的多层x射线屏幕结构，其提供改善的图像清晰度，同时进一步减少交叉问题，因为更多的反射的UV辐射被传输到相关的摄影胶片。

公开(公告)号：US4539138A

公开(公告)日：1985-09-03

申请号：US591224

申请日：1984-03-12

Applicant: Junji Miyahara ,  Takashi Nakamura ,  Kenji Takahashi

Inventor： Junji Miyahara ,  Takashi Nakamura ,  Kenji Takahashi

IPC: G03B42/02 ,  C09K11/08 ,  C09K11/64 ,  C09K11/67 ,  C09K11/77 ,  G03C1/815 ,  G21K4/00 ,  C09K11/46 ,  C09K11/465

CPC classification number: C09K11/7788 ,  C09K11/7701 ,  C09K11/7705 ,  C09K11/777

Abstract: A rare earth element activated divalent metal represented by the formulaM.sup.II FX.xSiO.sub.2 :yLnwherein M.sup.II is at least one divalent metal selected from the group consisting of Ba, Ca, Sr, Mg, Zn and Cd; Ln is at least one rare earth element selected from the group consisting of Eu, Tb, Ce, Tm, Dy, Pr, Ho, Nd, Yb, Er, Sm and Gd; X is at least one halogen selected from the group consisting of Cl, Br and I; x and y are numbers satisfying the condition 5.times.10.sup.-5 .ltoreq.x.ltoreq.0.5 and of 0

Abstract translation: 由式MIIFX.xSiO 2：yLn表示的稀土元素活化二价金属，其中MII是选自Ba，Ca，Sr，Mg，Zn和Cd中的至少一种二价金属; Ln是选自Eu，Tb，Ce，Tm，Dy，Pr，Ho，Nd，Yb，Er，Sm和Gd中的至少一种稀土元素; X是选自Cl，Br和I中的至少一种卤素; x和y分别是满足条件5×10-5≤x≤0.5且0≤y≤0.2的数字。 该荧光体具有发光亮度高，粉末流动性高，余辉性好等特点。

公开(公告)号：US4311487A

公开(公告)日：1982-01-19

申请号：US158192

申请日：1980-06-11

Applicant: George W. Luckey ,  Christine M. Towers

Inventor： George W. Luckey ,  Christine M. Towers

IPC: C09K11/77 ,  C09K11/86 ,  G21K4/00 ,  C09K11/46

CPC classification number: G21K4/00 ,  C09K11/7701 ,  C09K11/777

Abstract: A method for the recrystallization of activated rare-earth oxyhalide phosphors is disclosed. The method comprises recrystallizing the phosphor by firing a phosphor-flux mixture in an inert atmosphere. The phosphor-flux is substantially homogeneous and the flux contains substantially dehydrated magnesium halide. One particularly preferred phosphor made by the method is a lanthanum oxychloride phosphor coactivated with bismuth and ytterbium. This phosphor made by the present method has high speed and low afterglow.

Abstract translation: 公开了一种活化的稀土氧卤化物荧光体的再结晶方法。 该方法包括在惰性气氛中烧制磷光体 - 助熔剂混合物，使磷光体重结晶。 磷光体通量基本上是均匀的，并且焊剂含有基本脱水的卤化镁。 通过该方法制造的一种特别优选的荧光体是与铋和镱共激活的氯氧化镧荧光体。 通过本方法制造的该荧光体具有高速度和低余辉。