摘要:
The present invention provides compounds, especially polymeric compounds, a process for preparation thereof and for the use of these compounds. Intended use is in the field of electro-chemistry. Anion-conducting properties of disclosed compounds making this material suitable for the preparation of anion-conducting membranes. The object of the present invention is therefore to provide material having an ionic conductivity that is stable over long period of time. This object is solved by compounds containing at least one unit of the formula (I) wherein X being a ketone or sulfone group, wherein Z being a structure element comprising at least one tertiary carbon atom and at least one aromatic 6-ring directly bonded to one of the oxygen atoms, and wherein Y being a structure element comprising at least one nitrogen atom with a positive charge and Y being bonded to said tertiary carbon atom of Z.
摘要:
The present invention relates to an electrolyte membrane, a membrane-electrode assembly and a polymer electrolyte fuel cell. The electrolyte membrane contains a polymer (1) including a hydrophobic structural unit and a structural unit having a proton-conducting group and a polymer (2) including a hydrophobic structural unit having no sulfonic group which is different from the hydrophobic structural unit of the polymer (1).
摘要:
A soluble n-type copolymer that is useful in electronic and photonic devices. Embodiments of the invention include an n-type copolymer having a soluble n-type perylene copolymer having base formula A, where R is a backbone segment, where R1 and R2 are independently selected from the group consisting of alkyl, fluorinated alkyl, functionalized alkyl, aryl, fluorinated aryl, and functionalized aryl, and where n ranges from about 2 to 50,000.
摘要:
A method. The method includes providing Au-doped Co nanoparticles. The nanoparticles include a combination of non-ferromagnetic nanoparticles and weakly ferromagnetic nanoparticles. The nanoparticles each have an exterior surface. The surfaces of the nanoparticles are functionalized with 7-(5-uracil-ylcarbamoyl)heptanoic acid. A polymer is provided having a general formula including a uracil group. A dispersion is formed by agitating a solution of the nanoparticles. The solution is spin cast into a film. The film is heated under vacuum at a first temperature, TFM, resulting in inducing ferromagnetism in the non-ferromagnetic nanoparticles and converting the non-ferromagnetic nanoparticles to ferromagnetic nanoparticles, and resulting in enhancing ferromagnetism in the weakly ferromagnetic nanoparticles. The nanoparticles are aligned such that magnetic easy axes of the nanoparticles are oriented by applying a magnetic field to the dispersion while at a second temperature less than TFM. The axes align in a plane parallel to a plane of the film.
摘要:
This invention relates to novel benzotrifluoride aryl ether polymers useful as high performance engineering thermoplastics and as semi-permeable gas separation membranes.
摘要:
Described herein are poly(aryl ether) (“PAE”) adhesive compositions including at least one PAE chelating agent. The PAE chelating agent is a PAE polymer. In some embodiments, the PAE adhesive composition can optionally include one or more poly(aryl ether ketone) polymers distinct from the PAE chelating agent. The PAE adhesive composition can be incorporated into polymer-metal junctions to improve the strength thereof. In some such embodiments, the adhesive composition can be disposed between a portion of the plastic component and a portion of the metal component of the polymer-metal junction. In some embodiments, the PAE adhesive compositions can be used in conjunction with one or more adhesion promoters distinct from the PAE adhesive composition. In some embodiments, polymer-metal junctions including the PAE chelating agent can be desirably incorporated in mobile electronic device components.
摘要:
A composition comprises a compound comprising a partial structure represented by formula (1) and comprising an intermolecular bond-forming group; and a solvent. X1 and X2 each independently represent a substituted or unsubstituted ring structure having 4 to 10 ring atoms constituted taken together with a spiro carbon atom and carbon atoms of an aromatic ring. R1 and R2 each independently represent a halogen atom, a hydroxy group, a nitro group or a monovalent organic group. a1 and a2 are each independently an integer of 0 to 8. n1 and n2 are each independently an integer of 0 to 2; k1 and k2 are each independently an integer of 0 to 8. A sum of k1 and k2 is no less than 1, and a sum of a1 and k1. A sum of a2 and k2 are no greater than 8.
摘要:
[Object] To provide a proton exchange membrane for a fuel cell having excellent proton conductivity, lower property of swelling with hot water, and excellent durability, as well as a block copolymer forming the proton exchange membrane, and a composition, a molded product, a fuel cell proton exchange membrane electrode assembly, and a fuel cell.[Solving Means] (1) A block copolymer having a hydrophilic segment and a hydrophobic segment and having a structure expressed by Chemical Formula 1 below (where X represents H or a univalent cation, Y represents sulfonyl group or carbonyl group, each of Z and z′ independently represents any of O and S atoms, W represents one or more group selected from the group consisting of direct bond between benzenes, sulfone group and carbonyl group, each of Ar1 and Ar2 independently represents divalent aromatic group, and each of n and m independently represents an integer from 2 to 100), and a molded product, a composition, and a proton exchange membrane, as well as a fuel cell including the proton exchange membrane.
摘要:
The present invention relates to aromatic polyether resins crosslinked with amic acid or imide side chain, and more particularly, to the aromatic polyether resin crosslinked by amic acid or imide side chain, which is produced by heat curing of amic acid, wherein introduction of imide groups to the basic backbone provides excellent chemical resistance as well as heat resistance and improves surface roughness when coated as a thin film so that it can be suitable for films and flexible display plate substrate.
摘要:
The present invention relates to nonlinear optical material comprising nonlinear optical dihydroxy arylhydrazones and to nonlinear optical materials comprising compositions containing at least one divalent moiety of nonlinear optical arylhydrazones. The present invention also relates to polyesters, polyestercarbonates, polycarbonates, polyethers, and poly(hydroxy ether) polymers, incorporating the dihydroxy arylhydrazone as recurring divalent moieties in the backbone of the polymer. The polymeric compositions of the present invention have high glass transition temperatures and exhibit stable nonlinear optical activity at high temperatures over a period of time.