公开(公告)号：US11879108B2

公开(公告)日：2024-01-23

申请号：US17600797

申请日：2020-03-23

申请人： BASF SE

发明人： Ivette Garcia Castro ,  Wolfgang Grabarse ,  Jan Strittmatter ,  Rene Koschabek ,  Robert Rupaner

IPC分类号： C10M107/28 ,  C08F220/18 ,  C08F210/02 ,  C10M145/14

CPC分类号： C10M107/28 ,  C08F210/02 ,  C08F220/1808 ,  C10M145/14 ,  C08F2800/20 ,  C10M2205/022 ,  C10M2209/0845 ,  C08F210/02 ,  C08F220/1804 ,  C08F220/1808 ,  C08F210/02 ,  C08F220/1812 ,  C08F210/02 ,  C08F220/1804 ,  C08F210/02 ,  C08F220/1808 ,  C08F220/1808 ,  C08F210/02 ,  C08F220/1804 ,  C08F210/02 ,  C08F220/1804 ,  C08F220/1812 ,  C08F220/1808 ,  C08F210/02 ,  C10M2205/022 ,  C10M2209/084 ,  C08F210/02 ,  C08F220/18 ,  C08F2500/02 ,  C08F2500/06 ,  C08F2500/17

摘要： The present invention relates to a middle-pressure polymerization process for the preparation of a liquid ethylene copolymer which comprises in polymerized form 20 to 60 wt % of ethylene; and at least 20 wt % of an acrylate, which is selected from C1-C22 alkyl (meth)acrylate, where a monomer mix comprising the ethylene and the acrylate is polymerized at a pressure of 50 to 400 bar and in the presence of at least 2 wt % of a chain transfer agent. The invention further relates to a liquid ethylene copolymer obtainable by the polymerization process; and to a lubricant comprising the liquid ethylene copolymer obtainable by the polymerization process; and to a method for reducing friction between moving surfaces comprising the step of contacting the surfaces with the lubricant or with the ethylene copolymer.

公开(公告)号：US11773197B2

公开(公告)日：2023-10-03

申请号：US16866730

申请日：2020-05-05

申请人： NOVA Chemicals (International) S.A.

发明人： Niousha Kazemi ,  Monika Kleczek ,  Vinod Konaganti ,  Bronwyn Gillon ,  Shivendra Goyal ,  Fazle Sibtain ,  Sepideh Kasiri ,  Stephen Salomons ,  Kenneth Taylor ,  Mehdi Keshtkar

IPC分类号： C08F2/01 ,  C08F4/6592 ,  C08F210/16 ,  C08L23/08 ,  C08J5/18 ,  B32B27/08 ,  B32B27/32 ,  C08F4/659

CPC分类号： C08F210/16 ,  C08J5/18 ,  B32B27/08 ,  B32B27/32 ,  C08F4/65908 ,  C08F4/65912 ,  C08J2323/06 ,  C08J2323/08 ,  C08L23/0815 ,  C08F210/16 ,  C08F2/001 ,  C08F210/16 ,  C08F2/06 ,  C08F210/16 ,  C08F4/65927 ,  C08F210/16 ,  C08F210/14 ,  C08F2500/04 ,  C08F2500/05 ,  C08F2500/06 ,  C08F2500/10 ,  C08F2500/11 ,  C08F2500/12 ,  C08F2500/26 ,  C08F210/16 ,  C08F210/14 ,  C08F2500/02 ,  C08F2500/03 ,  C08F2500/08 ,  C08F2500/09 ,  C08F2500/10 ,  C08F2500/11 ,  C08F2500/12 ,  C08F2500/17 ,  C08F2500/26 ,  C08F210/16 ,  C08F210/14 ,  C08F2500/02 ,  C08F2500/03 ,  C08F2500/05 ,  C08F2500/08 ,  C08F2500/09 ,  C08F2500/10 ,  C08F2500/11 ,  C08F2500/12 ,  C08F2500/17 ,  C08F2500/26

摘要： This disclosure relates to an improved continuous solution polymerization process wherein production rate is increased. Process solvent, ethylene, optional comonomers, optional hydrogen and a bridged metallocene catalyst formulation are injected into a first reactor to form a first ethylene interpolymer. Optionally, process solvent, ethylene, optional comonomers, optional hydrogen and a bridged metallocene catalyst formulation are injected into a second reactor forming a second ethylene interpolymer. The first and second reactors may be configured in series or parallel modes of operation. Optionally, a third ethylene interpolymer is formed in a third reactor, wherein a homogeneous catalyst formulation or a heterogeneous catalyst formulation is employed. In solution, the first, optional second and optional third ethylene interpolymers are combined, the catalyst is deactivated, the solution is optionally passivated and following a phase separation process an ethylene interpolymer product is recovered.

公开(公告)号：US20180201705A1

公开(公告)日：2018-07-19

申请号：US15742552

申请日：2016-07-07

申请人： INEOS EUROPE AG

发明人： Serge DESPORTES ,  Imen GHOUILA ,  Claudine LALANNE-MAGNE ,  Eric OSMONT

IPC分类号： C08F210/16 ,  C08J5/18

CPC分类号： C08F210/16 ,  C08F4/65908 ,  C08F4/65912 ,  C08F4/65916 ,  C08F2410/01 ,  C08F2420/02 ,  C08J5/18 ,  C08J2323/08 ,  C08F4/6592 ,  C08F2/34 ,  C08F210/14 ,  C08F2500/06 ,  C08F2500/12 ,  C08F2500/08

摘要： Novel copolymers having a density (D) in the range 0.895-0.910 g/cm3, a melt index MI2 (2.16 kg, 190° C.) in the range of 0.01-6 g/10 min, a Compositional Distribution Branch Index (CDBI) in the range 55-85%, and a sealing initiation temperature (SIT) and density (D) satisfying the relationship SIT≤(A×D)−B wherein A is 800° C.×cm3/g and B is 650° C., wherein the SIT (° C.) is determined on a 70 μm film at 0.5N/15 mm and D Is in units of g/cm3 are disclosed. The copolymers may be suitably prepared by use of metallocene catalyst systems and may be used in film applications, in particular as sealing layers for packaging applications.

公开(公告)号：US20170226244A1

公开(公告)日：2017-08-10

申请号：US15501881

申请日：2015-08-06

申请人： NOVA Chemicals (International) S.A.

发明人： Shivendra Kumar Goyal ,  Bronwyn Hilary Gillon ,  Christopher John Brooke Dobbin ,  Stephen Salomons

IPC分类号： C08F210/16 ,  C08L23/08 ,  B32B7/02 ,  B32B27/08 ,  B32B27/32 ,  C08J5/18 ,  C08L23/06

CPC分类号： C08F210/16 ,  B32B7/02 ,  B32B27/08 ,  B32B27/327 ,  B32B2307/72 ,  B32B2553/00 ,  C08F4/65908 ,  C08F4/65912 ,  C08F210/00 ,  C08F2420/04 ,  C08F2500/08 ,  C08F2500/26 ,  C08J5/18 ,  C08J2323/08 ,  C08L23/06 ,  C08L23/0815 ,  C08L2203/16 ,  C08L2205/02 ,  Y02P20/52 ,  C08F4/6592 ,  C08F2/001 ,  C08F2/04 ,  C08F2500/06 ,  C08F2500/12

摘要： Provided herein are VLDPE polymer compositions suitable for use in the manufacture of flexible films or sheets. In one embodiment, the copolymer comprises a polyethylene VLDPE resin with Mz/Mw of greater than 2, CDBI50 of greater than 55 and a single melting peak in DSC measurement. The polymer compositions disclosed herein may be suitable for use in the manufacture of films with improved balance of film toughness, processability and sealability in monolayer and multi-layer film structures.

公开(公告)号：US20160347891A1

公开(公告)日：2016-12-01

申请号：US15163266

申请日：2016-05-24

申请人： NOVA Chemicals (International) S.A.

发明人： Patrick Lam ,  Victoria Ker ,  Robert Quaiattini

IPC分类号： C08F210/16 ,  C08J5/18

CPC分类号： C08F210/16 ,  B32B27/32 ,  C08F4/65912 ,  C08F4/65916 ,  C08F4/6592 ,  C08F210/08 ,  C08F2410/02 ,  C08F2420/04 ,  C08F2500/26 ,  C08J5/18 ,  C08J2323/08 ,  C08F2500/11 ,  C08F2500/12 ,  C08F2500/06 ,  C08F2500/10 ,  C08F2500/19

摘要： Ethylene/1-butene copolymers made with a single site catalyst system have high melt strength and good processability.

摘要翻译： 用单中心催化剂体系制备的乙烯/ 1-丁烯共聚物具有高熔体强度和良好的加工性能。

公开(公告)号：US20160326282A1

公开(公告)日：2016-11-10

申请号：US15137241

申请日：2016-04-25

申请人： NOVA Chemicals (International) S.A.

发明人： Qinyan Wang ,  Savini Udara Suduweli Kondage ,  Mark Kelly ,  Amy Marie Baltimore ,  Jessamyn Ross Logan ,  Tyler Craig

IPC分类号： C08F210/16

CPC分类号： C08F210/16 ,  C08F2410/02 ,  C08F4/6555 ,  C08F4/6546 ,  C08F4/022 ,  C08F4/6492 ,  C08F210/14 ,  C08F2500/12 ,  C08F2500/10 ,  C08F2500/06 ,  C08F2500/24 ,  C08F2500/18

摘要： Some embodiments herein disclose a process for producing an ethylene polymer or copolymer which contains less than 5 ppm titanium and has a bulk density, in granular form, of at least 22.5 lbs/ft3, using a spheroidal Ziegler-Natta type olefin polymerization catalyst having a particle size distribution characterized by a Dm*/Dn of less than 3.0 and comprising a titanium compound, an aluminum compound, and a spheroidal magnesium chloride support.

摘要翻译： 本文的一些实施方案公开了使用球形齐格勒 - 纳塔型烯烃聚合催化剂制备乙烯聚合物或共聚物的方法，该方法包含小于5ppm的钛并且具有至少22.5lbs / ft 3的颗粒形式的堆积密度，所述催化剂具有 粒径分布的特征在于Dm * / Dn小于3.0，并包含钛化合物，铝化合物和球形氯化镁载体。

公开(公告)号：US09296842B2

公开(公告)日：2016-03-29

申请号：US13967961

申请日：2013-08-15

申请人： MITSUBISHI RAYON CO., LTD.

发明人： Atsushi Yasuda ,  Tomoya Oshikiri ,  Daisuke Matsumoto ,  Keisuke Katou ,  Shinichi Maeda

IPC分类号： C08F24/00 ,  C08F297/02 ,  C08F2/00 ,  G03F7/039 ,  G03F7/004 ,  G03F7/085

CPC分类号： C08F24/00 ,  C08F2/00 ,  C08F297/026 ,  C08F2500/06 ,  G03F7/0045 ,  G03F7/0046 ,  G03F7/039 ,  G03F7/0397 ,  G03F7/085

摘要： A copolymer obtained by polymerizing two or more types of monomers, wherein among fractions obtained by dividing an eluate showing peaks relative to the copolymer, in an elution curve obtained by gel permeation chromatography (GPC), into eight fractions in order of fractionation, such that each fraction has the same volume, a difference between a monomer composition ratio of a copolymer contained in a first eluted fraction and a monomer composition ratio of all copolymers is −3 mol % to +3 mol % in any of the constitutional units derived from the respective monomers.

摘要翻译： 通过聚合两种或更多种类型的单体获得的共聚物，其中在通过将通过凝胶渗透色谱法（GPC）获得的洗脱曲线中除以相对于共聚物的峰的洗脱液分离得到的分数，按分级顺序分成8个馏分，使得 每个级分具有相同的体积，所有共聚物中包含的共聚物的单体组成比与所有共聚物的单体组成比之间的差异在任何衍生自所述共聚物的任何结构单元中为-3摩尔％至+3摩尔％ 各自的单体。

公开(公告)号：US20130144019A1

公开(公告)日：2013-06-06

申请号：US13816665

申请日：2010-09-29

申请人： Mehmet Demirors ,  Lawrence J. Effler ,  Lonnie G. Hazlitt ,  Teresa P. Karjala ,  Cristina Serrat

发明人： Mehmet Demirors ,  Lawrence J. Effler ,  Lonnie G. Hazlitt ,  Teresa P. Karjala ,  Cristina Serrat

IPC分类号： C08F4/42

CPC分类号： C08F4/42 ,  C08F10/00 ,  C08F210/16 ,  C08J5/18 ,  C08J2323/08 ,  C08F210/14 ,  C08F2500/12 ,  C08F2500/06 ,  C08F2500/03 ,  C08F2500/26 ,  C08F4/6546

摘要： The instant invention provides an ethylene/alpha-olefin interpolymer suitable for use in shrinkage film applications, and articles made therefrom. The ethylene/alpha-olefin interpolymer according to the present invention has a CDBI of less than 60%, and comprises at least two fractions in crossfractionation of the ethylene/alpha-olefin interpolymer, eluting from 85° C. to 90° C. and from 90° C. to 95° C., comprising a weight fraction ratio of >0.68 and a molecular weight homogeneity index of greater than 0.65; wherein the weight fraction ratio is the ratio of the weight of polymer in each fraction divided by the weight of polymer eluting between 95° C. and 100° C. and the molecular weight homogeneity index is the ratio of the weight average molecular weight of the polymer in the fraction divided by the weight average molecular weight of the polymer eluting between 95° C. and 100° C., and wherein the ethylene/alpha-olefin interpolymer has a density in the range of 0.920 to 0.940 g/cm3.

摘要翻译： 本发明提供了适用于收缩膜应用的乙烯/α-烯烃互聚物和由其制成的制品。 根据本发明的乙烯/α-烯烃互聚物的CDBI小于60％，并且在85℃至90℃下从乙烯/α-烯烃互聚物的交叉分级中至少包含两个馏分， 包括重量分数比> 0.68且分子量均匀度指数大于0.65的90℃至95℃; 其中重量分数比是每个级分中聚合物的重量比除以95℃和100℃之间洗脱的聚合物的重量的比例，分子量均匀度指数是重均分子量 该分数中的聚合物除以在95℃和100℃之间洗脱的聚合物的重均分子量，其中乙烯/α-烯烃互聚物的密度在0.920至0.940g / cm3的范围内。

公开(公告)号：US20100184929A1

公开(公告)日：2010-07-22

申请号：US12663110

申请日：2008-06-11

申请人： Pauli Leskinen ,  Olli Tuominen

发明人： Pauli Leskinen ,  Olli Tuominen

IPC分类号： C08F10/06

CPC分类号： C08F210/06 ,  C08F210/16 ,  Y10S526/904 ,  C08F2500/06 ,  C08F2500/18 ,  C08F2500/24 ,  C08F2500/12

摘要： The present invention relates to a process for the production of propylene copolymers wherein in a first step an olefin polymerisation catalyst comprising a solid catalyst component is subjected to a prepolymerisation reaction in a prepolymerisation reactor, in which propylene monomers are present in an amount of 98.0 to 99.9 mol % and further alpha-olefin monomers other than propylene are present in an amount of 0.1 to 2.0 mol %, based on the combined amount of propylene and further alpha-olefin monomers, so that a prepolymer is produced on the catalyst in an amount of 10 to 1000 g per g of the solid catalyst component, and in a second, subsequent step propylene and further alpha-olefin monomers other than propylene are copolymerised in the presence of the prepolymerised catalyst produced in the first step so that a propylene copolymer is obtained which contains at least 0.1 mol % of alpha-olefin units other than propylene, to propylene copolymers obtainable by such a process and to the use of a prepolymerised catalyst in such a process.

摘要翻译： 本发明涉及一种生产丙烯共聚物的方法，其中在第一步中，将包含固体催化剂组分的烯烃聚合催化剂在预聚合反应器中进行预聚合反应，其中丙烯单体的存在量为98.0至 基于丙烯和其它α-烯烃单体的总量，99.9摩尔％和除了丙烯之外的其它α-烯烃单体的存在量为0.1-2.0摩尔％，从而在催化剂上产生一定量的预聚物 每克固体催化剂组分为10至1000g，在第二步骤中，丙烯和除丙烯之外的其它α-烯烃单体在第一步中制备的预聚合催化剂存在下共聚合，使丙烯共聚物为 包含至少0.1mol％的除丙烯以外的α-烯烃单元的丙烯共聚物可以通过这种方法得到的丙烯共聚物和t 他在这样一个过程中使用预聚合的催化剂。

公开(公告)号：US20070299229A1

公开(公告)日：2007-12-27

申请号：US11897828

申请日：2007-08-31

申请人： R. Resendes ,  Gabor Kaszas ,  Mark Drewitt ,  Stephan Glander ,  Gerhard Langstein ,  Martin Bohnenpoll

发明人： R. Resendes ,  Gabor Kaszas ,  Mark Drewitt ,  Stephan Glander ,  Gerhard Langstein ,  Martin Bohnenpoll

IPC分类号： C08F210/00 ,  C08F14/16 ,  C08F22/00 ,  C08F28/02 ,  C08F30/02 ,  C08F30/08

CPC分类号： C08F210/12 ,  C08F4/06 ,  C08F4/005 ,  C08F236/08 ,  C08F212/36 ,  C08F2500/17 ,  C08F2500/03 ,  C08F2500/06

摘要： The present invention relates to a continuous process for producing polymers at conversions ranging from 50% to 95% having a Mooney viscosity of at least 25 Mooney-units and a gel content of less than 15 wt. % containing repeating units derived from at least one isoolefm monomer, more than 4.1 mol% of repeating units derived from at least one multiolefm monomer and optionally further copolymerizable monomers in the presence of AlCl3 and a suitable proton source (e.g. water) or cationogen and at least one multiolefin cross-linking agent wherein the process is conducted in the absence of transition metal compounds and organic nitro compounds.

摘要翻译： 本发明涉及以50至95％的转化率生产聚合物的连续方法，门尼粘度至少为25门尼单元，凝胶含量小于15wt。 ％，含有衍生自至少一种异烯烃单体的重复单元，大于4.1摩尔％的衍生自至少一种多元醇单体的重复单元和任选的另外可共聚单体在AlCl 3存在下和合适的质子源 （例如水）或阳离子原子和至少一种多烯烃交联剂，其中该方法在不存在过渡金属化合物和有机硝基化合物的情况下进行。