Abstract:
A quad-polymer composition includes monomers of (a) acrylonitrile, (a) vinylimidazole, (c) methyl acrylate and (d) either acrylic acid or itaconic acid. Such quad- polymer compositions may be used to form fibers (such as by melt spinning) that may then be annealed, stabilized, and/or carbonized to produce carbon fibers. The quad-polymer composition may be used for supercapacitors, lithium battery electrodes once carbonized, and as synthesized, it may be used for wound healing fibers, fabrics, coatings, and films, and anti-bacterial/anti-microbial fibers, fabrics, coatings and films. The carbon fibers formed from the quad-polymer composition may be used for the fiber composites for automobile, aerospace structures, marine structures, military equipment/parts, sporting goods, robotics, furniture, and electronic parts.
Abstract:
The present invention provides a method for preparing a polyion thin film (in particular a polyion thin film with different surface morphologies) and the polyion thin film prepared by the method. The method comprises: providing a substrate, and coating a first lubricant on a surface of the substrate or on a surface of a tinfoil covered on the surface of the substrate; covering a film-forming liquid of the polyion thin film on the surface of the substrate with the first lubricant, and after coating uniformly, covering a cover plate coated with a second lubricant on the film-forming liquid; performing a polymerization reaction of ionic liquid monomers in the film-forming liquid to form a polyion thin film; and separating the polyion thin film and cleaning it to obtain the polyion thin film. The polyion thin films with different surface morphology can be prepared. The present invention further provides a detection kit.
Abstract:
Heat-expandable microspheres with high encapsulation efficiency of a blowing agent and good heat-expansion performance, a process for reproducibly producing the heat-expandable microspheres and application thereof are provided. The heat-expandable microspheres comprise essentially a thermoplastic resin shell and a blowing agent encapsulated therein, and contain not more than 500 ppm of silicon, not more than 350 ppm of aluminum and not more than 600 ppm of the total of the silicon and aluminum. The heat-expandable microspheres retain at least 70% of the blowing agent encapsulated therein at the temperature which is the average of their expansion-initiation temperature and maximum expansion temperature.
Abstract:
Disclosed is a binder for a secondary battery electrode including a copolymer of a hydrophilic monomer and a hydrophobic monomer, wherein, when a concentration of the copolymer is 5% in a solution based upon NMP as a solvent, a viscosity of the solution including the copolymer is 800 cP to 10000 cP. By using the binder, stability of an electrode is fundamentally improved from an electrode preparation process and, as such, a secondary battery having excellent lifespan characteristics is provided.
Abstract:
Heat-expandable microspheres with high encapsulation efficiency of a blowing agent and good heat-expansion performance, a process for reproducibly producing the heat-expandable microspheres and application thereof are provided. The heat-expandable microspheres comprise essentially a thermoplastic resin shell and a blowing agent encapsulated therein, and contain not more than 500 ppm of silicon, not more than 350 ppm of aluminum and not more than 600 ppm of the total of the silicon and aluminum. The heat-expandable microspheres retain at least 70% of the blowing agent encapsulated therein at the temperature which is the average of their expansion-initiation temperature and maximum expansion temperature.
Abstract:
Disclosed are a maleimide-a-alkylstyrene-based, heat-resistant bulk tetrapolymer and a preparation process thereof. More specifically, disclosed are a bulk tetrapolymer, comprising 5-60 wt % of an N-substituted maleimide monomer, 10-70 wt % of an a-alkylstyrene monomer, 5-50 wt % of an unsaturated nitrile monomer and 3-50 wt % of an aromatic vinyl monomer, as well as a continuous bulk polymerization process for preparing the same. The disclosed bulk tetrapolymer has a weight-average molecular weight (Mw) of 70,000-300,000 and a glass transition temperature of 150-200 DEG C., shows excellent high-temperature thermal stability and heat resistance and a remarkably low melt viscosity, and thus is excellent not only in processability, but also in productivity, processability, moldability and blendability, when it is blended with other resins. Also, the continuous bulk polymerization process is equipped with a devolatilizer and enables the bulk tetrapolymer to be produced at low cost and high efficiency.
Abstract:
Disclosed are a maleimide-a-alkylstyrene-based, heat-resistant bulk tetrapolymer and a preparation process thereof. More specifically, disclosed are a bulk tetrapolymer, comprising 5-60 wt % of an N-substituted maleimide monomer, 10-70 wt % of an a-alkylstyrene monomer, 5-50 wt % of an unsaturated nitrile monomer and 3-50 wt % of an aromatic vinyl monomer, as well as a continuous bulk polymerization process for preparing the same. The disclosed bulk tetrapolymer has a weight-average molecular weight (Mw) of 70,000-300,000 and a glass transition temperature of 150-200 DEG C., shows excellent high-temperature thermal stability and heat resistance and a remarkably low melt viscosity, and thus is excellent not only in processability, but also in productivity, processability, moldability and blendability, when it is blended with other resins. Also, the continuous bulk polymerization process is equipped with a devolatilizer and enables the bulk tetrapolymer to be produced at low cost and high efficiency.
Abstract:
This invention includes a polyelectrolytic gel comprising a polymer component and a nonaqueous solvent, characterized in that the polymer component is a crosslinked polymer having nitrogen-containing cationic functional group or a mixture of a non-crosslinked polymer having nitrogen-containing cationic functional group and a crosslinked polymer free of nitrogen-containing cationic functional group, the polymer component being swollen with the nonaqueous solvent containing an electrolyte dissolved therein. The electrolytic gel of the invention is excellent in heat resistance and durability and also in electroconductivity, especially ion conductivity.
Abstract:
A binder composition for the electrode of a non-aqueous lithium ion secondary battery, which is unlikely to swell with respect to an electrolyte solution and can easily increase the electrode density of the electrode for a non-aqueous lithium ion secondary battery, includes a polymer, the polymer includes an acrylonitrile unit and an α,β-ethylenically unsaturated nitrile monomer unit in which at least one or more types of hydrogen at the α position has been substituted, and the polymer has a crystallite size of 2.5 nm or more and 7.0 nm or less, which is determined from the peak within the range of 2θ=14° to 18° in X-ray structure diffraction and the half width of this peak.
Abstract:
Provided is a new technique that can sufficiently inhibit heat generation in the event of an internal short circuit of an electrochemical device while also reducing IV resistance at low temperature and improving high-temperature storage characteristics of the electrochemical device. A binder composition for an electrochemical device contains a binder and a thermally decomposable material. The thermally decomposable material includes a foaming agent. The thermally decomposable material has a thermal decomposition temperature of 150° C. to 400° C., a number-average particle diameter of 0.01 μm to 10 μm, a ratio of the number-average particle diameter relative to volume-average particle diameter of 0.05 to 1, and a circularity of 0.05 to 0.95.