摘要:
A method of using a metal organic framework (MOF) comprising a metal ion and an at least bidendate organic ligand to catalytically detoxify chemical warfare nerve agents including exposing the metal-organic-framework (MOF) to the chemical warfare nerve agent and catalytically decomposing the nerve agent with the MOF.
摘要:
A spinning fluids reactor, includes a reactor body (24) having a circular cross-section and a fluid contactor screen (26) within the reactor body (24). The fluid contactor screen (26) having a plurality of apertures and a circular cross-section concentric with the reactor body (24) for a length thus forming an inner volume (28) bound by the fluid contactor screen (26) and an outer volume (30) bound by the reactor body (24) and the fluid contactor screen (26). A primary inlet (20) can be operatively connected to the reactor body (24) and can be configured to produce flow-through first spinning flow of a first fluid within the inner volume (28). A secondary inlet (22) can similarly be operatively connected to the reactor body (24) and can be configured to produce a second flow of a second fluid within the outer volume (30) which is optionally spinning.
摘要:
A process and sensor device are disclosed that employ metal β-diketonate polymers to selectively capture gas-phase explosives and weaponized chemical agents in a sampling area or volume. The metal β-diketonate polymers can be applied to surfaces in various analytical formats for detection of: improvised explosive devices, unexploded ordinance, munitions hidden in cargo holds, explosives, and chemical weapons in public areas.
摘要:
Methods and apparatus for destroying ozone in an air stream are provided. Specific embodiments comprise passing air through a particulate filter comprising a filter media folded into a plurality pleats and a plurality of separators, where the separators and/or the filter media is coated with an ozone destruction catalyst.
摘要:
A process and sensor device are disclosed that employ metal β-diketonate polymers to selectively capture gas-phase explosives and weaponized chemical agents in a sampling area or volume. The metal β-diketonate polymers can be applied to surfaces in various analytical formats for detection of: improvised explosive devices, unexploded ordinance, munitions hidden in cargo holds, explosives, and chemical weapons in public areas.
摘要:
A shelter coating comprising a photocatalyst capable of generating singlet oxygen from ambient air. The shelter coating may optionally include a singlet oxygen scavenger.
摘要:
An air decontamination system that cleans air which has been contaminated by a terrorist attack or other means of contamination. The air is drawn into the system, cleaned through the use of filters, and exits the system into an enclosed area where people have gathered to await passage of the danger. The unit is easily turned on and off via a switch.
摘要:
A microfibrous matrix with embedded supporting particulates/fibers and chemically reactive materials is provided as a filtration system for the removal of contaminants and other harmful agents from liquid and gaseous streams. Such filter may be used for example to protect the intolerant anodes and cathodes of fuel cells from damaging H2S while simultaneously aiding the selective conversion of CO to CO2 in fuel streams predominated by hydrogen. In general, the reactive materials utilized as well as the supporting matrix of fibers may be broadly selected to remove specific contaminants at specific reaction conditions inherent to the application. Such materials may include chemically reactive materials as high surface area carbons, zeolites, silicas, aluminas, inorganic metal oxides, polymer resins, ZnO, ZnO/Carbon, Pt/γ-Al2O3, PtCo/γ-Al2O3, ZnO/SiO2 and various other catalysts, sorbents or reactants. In an alternative embodiment, entrapped sorbents and other reactants may be used to provide a highly efficient gas and/or liquid separation and purification methodology for gas masks, building filtration systems, and/or as polishing media located downstream of traditional packed bed filtration systems so as to achieve the high volume loading/capacity of the packed bed along with the overall contacting efficiency of the outlet polishing layer.
摘要:
Areas in which toxic material has been released, particularly in gaseous form but also in liquid form, are decontaminated by forming gas hydrate of the toxic agent. Smaller-molecule toxic agents form sI or sII type hydrates, whereas larger-molecule toxic agents for sH type hydrates. A “companion gas” or “companion agent” is supplied to fill the smaller voids of the sH hydrate, thereby enabling larger-molecule toxic agents to form hydrates by filling the larger voids of the sH hydrate which, but for the presence of the smaller-molecule agent in the smaller voids, would be unstable and not form. Portable as well as fixed, permanently installed apparatus for conducting hydrate-based decontamination is also disclosed.
摘要:
Airborne or aqueous organic compound collection using carbon nanotubes. Exposure of carbon nanotube-coated disks to controlled atmospheres of chemical warefare (CW)-related compounds provide superior extraction and retention efficiencies compared to commercially available airborne organic compound collectors. For example, the carbon nanotube-coated collectors were four (4) times more efficient toward concentrating dimethylmethyl-phosphonate (DMMP), a CW surrogate, than Carboxen, the optimized carbonized polymer for CW-related vapor collections. In addition to DMMP, the carbon nanotube-coated material possesses high collection efficiencies for the CW-related compounds diisopropylaminoethanol (DIEA), and diisopropylmethylphosphonate (DIMP).