摘要:
A hydrogen production system (X1) according to the present invention includes a reforming apparatus (Y1) having a vaporizer (1) and a reforming reactor (2), and a PSA apparatus (5). In the vaporizer (1) a mixed material (hydrocarbon-based material, water, and oxygen) is heated and vaporized. In the reforming reactor (2), steam reforming reaction and partial oxidation reaction of the hydrocarbon-based material take place at a time, so that reformed gas (containing hydrogen) is led out from the vaporized mixed material. In the PSA apparatus (5), the reformed gas is introduced into an adsorption tower loaded with an adsorbing agent, so that an unnecessary component in the gas is adsorbed by the adsorbing agent and hence hydrogen-rich gas is led out of the tower, while the unnecessary component is desorbed from the adsorbing agent, so that hydrogen-containing desorbed gas that contains the unnecessary component and hydrogen remaining in the tower is discharged out of the tower. The desorbed gas is burnt in the vaporizer (1), and combustion gas generated by burning the desorbed gas is utilized as a heat source to heat the mixed material.
摘要:
A method for treating drain in hydrogen production includes steps of gasifying in a gasifier (1), reforming in a reformer (2), gas-liquid separation in a gas-liquid separator (4), PSA gas separation in a PSA separator (5) and evaporation in a drain treatment unit (6). In the gasifying, a mixed material containing methanol is heated and gasified. In the reforming, reformed gas containing hydrogen is produced from the mixed material by reforming reaction of methanol. In the gas-liquid separation, a liquid component is separated from the reformed gas and discharged as drain. In the PSA gas separation, hydrogen-rich gas and offgas are extracted from the reformed gas by PSA separation using an adsorption tower. In the gasifying, the offgas is burned, and the mixed material is heated by using the combustion gas as heat source. In the evaporation, drain is evaporated using the combustion gas after heating the mixed material as heat source.
摘要:
A method for treating drain in hydrogen production includes steps of gasifying in a gasifier (1), reforming in a reformer (2), gas-liquid separation in a gas-liquid separator (4), PSA gas separation in a PSA separator (5) and evaporation in a drain treatment unit (6). In the gasifying, a mixed material containing methanol is heated and gasified. In the reforming, reformed gas containing hydrogen is produced from the mixed material by reforming reaction of methanol. In the gas-liquid separation, a liquid component is separated from the reformed gas and discharged as drain. In the PSA gas separation, hydrogen-rich gas and offgas are extracted from the reformed gas by PSA separation using an adsorption tower. In the gasifying, the offgas is burned, and the mixed material is heated by using the combustion gas as heat source. In the evaporation, drain is evaporated using the combustion gas after heating the mixed material as heat source.
摘要:
A hydrogen production system (X1) according to the present invention includes a reforming apparatus (Y1) having a vaporizer (1) and a reforming reactor (2), and a PSA apparatus (5). In the vaporizer (1) a mixed material (hydrocarbon-based material, water, and oxygen) is heated and vaporized. In the reforming reactor (2), steam reforming reaction and partial oxidation reaction of the hydrocarbon-based material take place at a time, so that reformed gas (containing hydrogen) is led out from the vaporized mixed material. In the PSA apparatus (5), the reformed gas is introduced into an adsorption tower loaded with an adsorbing agent, so that an unnecessary component in the gas is adsorbed by the adsorbing agent and hence hydrogen-rich gas is led out of the tower, while the unnecessary component is desorbed from the adsorbing agent, so that hydrogen-containing desorbed gas that contains the unnecessary component and hydrogen remaining in the tower is discharged out of the tower. The desorbed gas is burnt in the vaporizer (1), and combustion gas generated by burning the desorbed gas is utilized as a heat source to heat the mixed material.
摘要:
Stable hemoglobin A.sub.lc (s-A.sub.lc) can be separated from other hemoglobin components and quantitated in a short time by means of a liquid-chromatographic apparatus comprising a separation column packed with a packing material consisting essentially of a porous substance having a carboxyalkyl group combined thereinto, as ion exchanger, a means for injecting a sample into the separation column, a means for passing one or more eluents through the separation column, and a means for detecting hemoglobin, hemoglobin derivatives or glycosylated hemoglobin, the average particle size of the packing material in dry state being 4 .mu.m or less.
摘要:
An apparatus for electrochemically measuring clinical emergency check items of blood for a short time by flowthrough system, using a small amount of whole blood as a blood sample, which comprises a blood pH/gas component sensor unit, an electrolyte component sensor unit, and/or a biochemical component sensor unit, arranged in series in this order, a sampler and these sensor units being communicated with one another through a blood sample flow passage or channel, each of the sensor units being provided with sensor electrodes and at least one reference electrode as electrochemical sensor means.Detected values from each of the sensor units are transmitted to a computer or calculator through a current amplifier and/or a differential amplifier for a differential voltage from the voltage of the reference electrode to compute pH, pressure, or concentrations from the detected values, and numerically displayed on a display device connected to the computer.
摘要:
A gas detecting means of this invention is provided with a discharge section which radiates light by electric discharge, a detecting section which collects an ion current of a sample gas ionized by the light, and an optical path which connects the discharge and the detecting sections. The discharge is formed by a pointed cathode and an anode having a penetration hole. The tip of the pointed cathode is directed to the optical path. The diameter of the penetration hole of the anode is smaller than that of the optical path. The anode is disposed in such a manner that any peripheral part of an inlet of the penetration hole is at an equal distance from the tip of the cathode. Both the discharge section and the detecting section are shielded electrically by an outer shell of metal.
摘要:
A method for continuously treating a gas using an apparatus with a catalyst bed housed therein comprises the steps of passing a subject gas through the catalyst bed to adsorb the adsorbable substances in the subject gas thereto; and passing a regenerating gas through the catalyst bed adsorbed by the adsorbable substances in the subject gas to react and decompose them and simultaneously regenerate the catalyst bed. A particular apparatus is used with this method.By carrying out this method of the present invention using the gas treating apparatus, it is possible to continuously, efficiently and economically advantageously treat a gas containing a malodorous component, harmful component, organic solvent, hydrocarbon vapor or the like.
摘要:
A liquid chromatography system and a method of utilizing the same, comprising a plurality of separated-component vessels for collecting components eluted in a separation column, a flowing system conduit for component extraction through which the components separated in the separation column are individually delivered to the separated-component vessels. The system further comprises a flowing system conduit for sample introduction through which any of the separated components collected in the plurality of separated-component vessels is selectively drawn from its vessel and introduced to the upstream side of the separation column. The present invention allows a plurality of components in a sample of a mixture to be individual collected, and also allows any of the collected components to be re-separated selectively and automatically.
摘要:
A sample leaving a separation column of liquid chromatograph is led to an electrolytic cell to obtain an electrolytic current corresponding to the amount of an assayed sample component. The electrolytic cell is divided into two compartments by an ion exchange pipe penetrating therethrough at the center. One compartment is a cylindrical working electrode chamber in the pipe, and the other compartment is a cylindrical chamber for a counterelectrode outside the pipe. A working electrode comprising a bundle of electroconductive carbon fibers is provided in the working electrode chamber, and preferably a swellable rod is inserted as a core into the working electrode. In the chamber for the counterelectrode, a cylindrical counterelectrode made of carbon fibers is provided to surround the outside surface of the ion exchange pipe. The inner diameter of the ion exchange pipe is substantially equal to the inner diameter of a tube for introducing the sample. The sample undergoes electrolysis reaction while the sample passes through the carbon fibers of the working electrode.