公开(公告)号：US09653300B2

公开(公告)日：2017-05-16

申请号：US13864218

申请日：2013-04-16

Applicant: UNITED MICROELECTRONICS CORP.

Inventor： Nien-Ting Ho ,  Chien-Hao Chen ,  Hsin-Fu Huang ,  Chi-Yuan Sun ,  Wei-Yu Chen ,  Min-Chuan Tsai ,  Tsun-Min Cheng ,  Chi-Mao Hsu

IPC: H01L27/148 ,  H01L21/28 ,  H01L29/49 ,  H01L21/8238 ,  H01L29/51 ,  H01L29/66 ,  H01L29/78 ,  H01L29/165

CPC classification number: H01L21/28088 ,  H01L21/823842 ,  H01L29/165 ,  H01L29/4966 ,  H01L29/513 ,  H01L29/517 ,  H01L29/665 ,  H01L29/66545 ,  H01L29/6659 ,  H01L29/7843 ,  H01L29/7848

Abstract: A manufacturing method of a metal gate structure is provided. First, a substrate covered by an interlayer dielectric is provided. A gate trench is formed in the interlayer dielectric, wherein a gate dielectric layer is formed in the gate trench. A silicon-containing work function layer is formed on the gate dielectric layer in the gate trench. Finally, the gate trench is filled up with a conductive metal layer.

公开(公告)号：US20140374909A1

公开(公告)日：2014-12-25

申请号：US14480648

申请日：2014-09-09

Applicant: UNITED MICROELECTRONICS CORP.

Inventor： Chi-Mao Hsu ,  Hsin-Fu Huang ,  Min-Chuan Tsai ,  Chien-Hao Chen ,  Wei-Yu Chen ,  Chin-Fu Lin ,  JING-GANG LI ,  Min-Hsien Chen ,  JIAN-HONG SU

IPC: H01L21/768 ,  H01L23/532 ,  H01L23/522

CPC classification number: H01L21/76846 ,  H01L21/28079 ,  H01L21/28088 ,  H01L21/2855 ,  H01L21/76877 ,  H01L21/76879 ,  H01L23/5226 ,  H01L23/53223 ,  H01L29/513 ,  H01L29/517 ,  H01L29/518 ,  H01L29/66545 ,  H01L2924/0002 ,  H01L2924/00

Abstract: A method for filling a trench with a metal layer is disclosed. A deposition apparatus having a plurality of supporting pins is provided. A substrate and a dielectric layer disposed thereon are provided. The dielectric layer has a trench. A first deposition process is performed immediately after the substrate is placed on the supporting pins to form a metal layer in the trench, wherein during the first deposition process a temperature of the substrate is gradually increased to reach a predetermined temperature. When the temperature of the substrate reaches the predetermined temperature, a second deposition process is performed to completely fill the trench with the metal layer. The present invention further provides a semiconductor device having an aluminum layer with a reflectivity greater than 1, wherein the semiconductor device is formed by using the method.

Abstract translation: 公开了一种用金属层填充沟槽的方法。 提供具有多个支撑销的沉积装置。 设置有基板和介电层。 电介质层具有沟槽。 在将衬底放置在支撑销上以在沟槽中形成金属层之后立即执行第一沉积工艺，其中在第一沉积工艺期间，衬底的温度逐渐增加以达到预定温度。 当基板的温度达到预定温度时，执行第二沉积工艺以用金属层完全填充沟槽。 本发明还提供了具有大于1的反射率的铝层的半导体器件，其中通过使用该方法形成半导体器件。

公开(公告)号：US08735269B1

公开(公告)日：2014-05-27

申请号：US13741402

申请日：2013-01-15

Applicant: United Microelectronics Corp.

Inventor： Chi-Yuan Sun ,  Chien-Hao Chen ,  Hsin-Fu Huang ,  Min-Chuan Tsai ,  Wei-Yu Chen ,  Chi-Mao Hsu ,  Tsun-Min Cheng ,  Chin-Fu Lin

IPC: H01L21/28

CPC classification number: H01L29/66545 ,  H01L21/28088 ,  H01L29/4966 ,  H01L29/517 ,  H01L29/6659

Abstract: The method for forming a semiconductor structure includes first providing a substrate. Then, a TiN layer is formed on the substrate at a rate between 0.3 and 0.8 angstrom/second. Finally, a poly-silicon layer is formed directly on the TiN layer. Since the TiN in the barrier layer is formed at a low rate so as to obtain a good quality, the defects in the TiN layer or the defects on the above layer, such as gate dummy layer or gate cap layer, can be avoided.

Abstract translation: 形成半导体结构的方法包括首先提供衬底。 然后，以0.3〜0.8埃的速度在基板上形成TiN层。 最后，直接在TiN层上形成多晶硅层。 由于阻挡层中的TiN以低的速率形成以获得良好的质量，因此可以避免TiN层中的缺陷或上层的缺陷，例如栅极虚设层或栅极盖层。

公开(公告)号：US20140346616A1

公开(公告)日：2014-11-27

申请号：US14454727

申请日：2014-08-08

Applicant: UNITED MICROELECTRONICS CORP.

Inventor： Min-Chuan Tsai ,  Hsin-Fu Huang ,  Chi-Mao Hsu ,  Chin-Fu Lin ,  Chien-Hao Chen ,  Wei-Yu Chen ,  Chi-Yuan Sun ,  Ya-Hsueh Hsieh ,  Tsun-Min Cheng

IPC: H01L29/49 ,  H01L29/78 ,  H01L29/51

CPC classification number: H01L29/4966 ,  H01L21/28088 ,  H01L21/823842 ,  H01L21/823857 ,  H01L29/4958 ,  H01L29/512 ,  H01L29/517 ,  H01L29/66545 ,  H01L29/78 ,  H01L2924/0002 ,  H01L2924/00

Abstract: A semiconductor structure includes a work function metal layer, a (work function) metal oxide layer and a main electrode. The work function metal layer is located on a substrate. The (work function) metal oxide layer is located on the work function metal layer. The main electrode is located on the (work function) metal oxide layer. A semiconductor process forming said semiconductor structure is also provided.

Abstract translation: 半导体结构包括功函数金属层，（功函数）金属氧化物层和主电极。 功函数金属层位于基板上。 （功函数）金属氧化物层位于功函数金属层上。 主电极位于（功函数）金属氧化物层上。 还提供了形成所述半导体结构的半导体工艺。

公开(公告)号：US20140239419A1

公开(公告)日：2014-08-28

申请号：US13778227

申请日：2013-02-27

Applicant: UNITED MICROELECTRONICS CORP.

Inventor： Chien-Hao Chen ,  Hsin-Fu Huang ,  Chi-Yuan Sun ,  Min-Chuan Tsai ,  Wei-Yu Chen ,  Nien-Ting Ho ,  Tsun-Min Cheng ,  Chi-Mao Hsu

IPC: H01L29/423 ,  H01L29/40

CPC classification number: H01L29/401 ,  H01L21/28044 ,  H01L21/28185 ,  H01L29/4925 ,  H01L29/51

Abstract: A method of manufacturing a semiconductor device is provided. A silicon substrate is provided, and a gate insulating layer is formed on the silicon substrate. Then, a silicon barrier layer is formed on the gate insulating layer by the physical vapor deposition (PVD) process. Next, a silicon-containing layer is formed on the silicon barrier layer. The silicon barrier layer of the embodiment is a hydrogen-substantial-zero silicon layer, which has a hydrogen concentration of zero substantially.

Abstract translation: 提供一种制造半导体器件的方法。 提供硅衬底，并且在硅衬底上形成栅极绝缘层。 然后，通过物理气相沉积（PVD）工艺在栅极绝缘层上形成硅阻挡层。 接着，在硅阻隔层上形成含硅层。 本实施方式的硅阻隔层是基本上为氢的氢浓度为零的氢 - 实际为零的硅层。

公开(公告)号：US20170207093A1

公开(公告)日：2017-07-20

申请号：US15479292

申请日：2017-04-05

Applicant: UNITED MICROELECTRONICS CORP.

Inventor： Nien-Ting Ho ,  Chien-Hao Chen ,  Hsin-Fu Huang ,  Chi-Yuan Sun ,  Wei-Yu Chen ,  Min-Chuan Tsai ,  Tsun-Min Cheng ,  Chi-Mao Hsu

IPC: H01L21/28 ,  H01L29/49 ,  H01L21/8238

CPC classification number: H01L21/28088 ,  H01L21/823842 ,  H01L29/165 ,  H01L29/4966 ,  H01L29/513 ,  H01L29/517 ,  H01L29/665 ,  H01L29/66545 ,  H01L29/6659 ,  H01L29/7843 ,  H01L29/7848

Abstract: A manufacturing method of a metal gate structure includes the following steps. First, a substrate covered by an interlayer dielectric is provided. A gate trench is formed in the interlayer dielectric, wherein a gate dielectric layer is formed in the gate trench. A silicon-containing work function layer is formed on the gate dielectric layer in the gate trench. The silicon-containing work function layer includes a vertical portion and a horizontal portion. Finally, the gate trench is filled up with a conductive metal layer.

公开(公告)号：US09076784B2

公开(公告)日：2015-07-07

申请号：US14454727

申请日：2014-08-08

Applicant: UNITED MICROELECTRONICS CORP.

Inventor： Min-Chuan Tsai ,  Hsin-Fu Huang ,  Chi-Mao Hsu ,  Chin-Fu Lin ,  Chien-Hao Chen ,  Wei-Yu Chen ,  Chi-Yuan Sun ,  Ya-Hsueh Hsieh ,  Tsun-Min Cheng

IPC: H01L29/78 ,  H01L29/49 ,  H01L21/28 ,  H01L29/51 ,  H01L29/66 ,  H01L21/8238

CPC classification number: H01L29/4966 ,  H01L21/28088 ,  H01L21/823842 ,  H01L21/823857 ,  H01L29/4958 ,  H01L29/512 ,  H01L29/517 ,  H01L29/66545 ,  H01L29/78 ,  H01L2924/0002 ,  H01L2924/00

Abstract: A semiconductor structure includes a work function metal layer, a (work function) metal oxide layer and a main electrode. The work function metal layer is located on a substrate. The (work function) metal oxide layer is located on the work function metal layer. The main electrode is located on the (work function) metal oxide layer. A semiconductor process forming said semiconductor structure is also provided.

Abstract translation: 半导体结构包括功函数金属层，（功函数）金属氧化物层和主电极。 功函数金属层位于基板上。 （功函数）金属氧化物层位于功函数金属层上。 主电极位于（功函数）金属氧化物层上。 还提供了形成所述半导体结构的半导体工艺。

公开(公告)号：US20140306273A1

公开(公告)日：2014-10-16

申请号：US13864218

申请日：2013-04-16

Applicant: UNITED MICROELECTRONICS CORP.

Inventor： Nien-Ting Ho ,  Chien-Hao Chen ,  Hsin-Fu Huang ,  Chi-Yuan Sun ,  Wei-Yu Chen ,  Min-Chuan Tsai ,  Tsun-Min Cheng ,  Chi-Mao Hsu

IPC: H01L21/28 ,  H01L29/423

CPC classification number: H01L21/28088 ,  H01L21/823842 ,  H01L29/165 ,  H01L29/4966 ,  H01L29/513 ,  H01L29/517 ,  H01L29/665 ,  H01L29/66545 ,  H01L29/6659 ,  H01L29/7843 ,  H01L29/7848

Abstract: A manufacturing method of a metal gate structure is provided. First, a substrate covered by an interlayer dielectric is provided. A gate trench is formed in the interlayer dielectric, wherein a gate dielectric layer is formed in the gate trench. A silicon-containing work function layer is formed on the gate dielectric layer in the gate trench. Finally, the gate trench is filled up with a conductive metal layer.

Abstract translation: 提供了金属栅极结构的制造方法。 首先，提供由层间电介质覆盖的基板。 在层间电介质中形成栅极沟槽，其中在栅极沟槽中形成栅极电介质层。 在栅极沟槽中的栅极电介质层上形成含硅功函数层。 最后，栅极沟槽填充有导电金属层。

公开(公告)号：US20140120711A1

公开(公告)日：2014-05-01

申请号：US13661998

申请日：2012-10-26

Applicant: UNITED MICROELECTRONICS CORP.

Inventor： Min-Chuan Tsai ,  Hsin-Fu Huang ,  Chi-Mao Hsu ,  Tsun-Min Cheng ,  Chien-Hao Chen ,  Wei-Yu Chen ,  Chi-Yuan Sun

IPC: H01L21/283

CPC classification number: H01L21/823842 ,  H01L21/28088 ,  H01L29/66545

Abstract: Provided is a method of forming a metal gate including the following steps. A dielectric layer is formed on a substrate, wherein a gate trench is formed in the dielectric layer and a gate dielectric layer is formed in the gate trench. A first metal layer is formed in the gate trench by applying a AC bias between a target and the substrate during physical vapor deposition. A second metal layer is formed in the gate trench by applying a DC bias between the target and the substrate during physical vapor deposition.

Abstract translation: 提供一种形成金属栅极的方法，包括以下步骤。 在衬底上形成介电层，其中在电介质层中形成栅极沟槽，并且在栅极沟槽中形成栅极电介质层。 通过在物理气相沉积期间在靶和衬底之间施加AC偏压，在栅极沟槽中形成第一金属层。 通过在物理气相沉积期间在靶和衬底之间施加DC偏压，在栅极沟槽中形成第二金属层。

公开(公告)号：US20140097507A1

公开(公告)日：2014-04-10

申请号：US14105198

申请日：2013-12-13

Applicant: UNITED MICROELECTRONICS CORP.

Inventor： Chi-Mao Hsu ,  Hsin-Fu Huang ,  Chin-Fu Lin ,  Min-Chuan Tsai ,  Wei-Yu Chen ,  Chien-Hao Chen

IPC: H01L29/49 ,  H01L21/28

CPC classification number: H01L21/28026 ,  H01L21/28079 ,  H01L21/28088 ,  H01L21/823842 ,  H01L29/401 ,  H01L29/49 ,  H01L29/66545 ,  H01L29/7833 ,  H01L29/7843

Abstract: The present invention provides a method of forming a semiconductor device having a metal gate. A substrate is provided and a gate dielectric and a work function metal layer are formed thereon, wherein the work function metal layer is on the gate dielectric layer. Then, a top barrier layer is formed on the work function metal layer. The step of forming the top barrier layer includes increasing a concentration of a boundary protection material in the top barrier layer. Lastly, a metal layer is formed on the top barrier layer. The present invention further provides a semiconductor device having a metal gate.

Abstract translation: 本发明提供一种形成具有金属栅极的半导体器件的方法。 提供基板，并且在其上形成栅极电介质和功函数金属层，其中功函数金属层在栅极电介质层上。 然后，在功函数金属层上形成顶部阻挡层。 形成顶部阻挡层的步骤包括增加顶部阻挡层中边界保护材料的浓度。 最后，在顶部阻挡层上形成金属层。 本发明还提供一种具有金属栅极的半导体器件。